Synthesis and fluorescence properties of dysprosium‐coordinated with high‐Tg polyaryletherketones containing carboxyl side groups

A series of novel dysprosium coordination polymers were synthesized using new high‐T_g carboxyl‐containing polyaryletherketones (PEKs) as macromolecular ligands and a small molecule, 1,10‐phenanthroline, as co‐ligand. The FTIR, WAXD, and UV–Vis results indicated that the dysprosium ions were coordinated simultaneously with carboxyl group of PEKs and 1,10‐phenanthroline, and homogeneously distributed along the polymer backbone. These obtained dysprosium coordination polymers showed excellent film‐formation properties. Moreover, all the dysprosium coordination polymers could exhibit the intense characteristic emission of dysprosium ions under UV excitation. Meanwhile, the emission intensity increased with increasing dysprosium ion content, and no obvious fluorescence quenching happened at the Dy³⁺ ion content up to 10.71 wt%, which was attributed to the very rigid structure of PEK and synergistic coordination effect of PEK and 1,10‐phenanthroline. Copyright © 2009 John Wiley & Sons, Ltd.     

矢量分析在反射和折射中的应用

利用反射定律和折射定律的矢量公式计算出平面转镜和道威棱镜的转像规律.     

采用双石英棱镜对的掺钛蓝宝石自锁模激光器

给出了双棱镜对二、三阶色散的解析式。报道了采用双石英棱镜对的掺钛蓝宝石自锁模激光器的实验结果，获得与理论分析一致的结论。     

三轴稳像棱镜组的三种运动方式

三轴稳像棱镜组是具有三自由度全视场稳定作用,同时还可起扫描、正像作用的多功能棱镜组。本文对该棱镜组的三种运动方式进行了讨论,并运用反射棱镜的基本稳像原理,推导出了三种运动方式的稳像公式和稳像工作公式。     

光学补偿LD侧向非均匀泵浦全固化激光器

采用定向棱镜谐振腔、半圆柱面LD阵列交错侧向泵浦两根串接NdYAG激光棒、热传导冷却结构,研制出了一台工程实用的全固化激光器.定向棱镜腔内振荡光线平行于光轴的对称位置交换穿行,匀化了增益,降低了模序数;同时,定向棱镜准相位共轭特性和自准直作用在一定程度上修正波前畸变、热光楔以及热致双折射,保证了大的动态范围内热稳定性,改善了光束质量.激光器采用Cr4+YAG被动调Q,在室温条件下,工作电流为53 A、频率10 Hz时,1.06 μm单脉冲激光能量高于150 mJ、脉宽9 ns、输出稳定度±3%、束散度2.5 mrad且光轴指向稳定,远场分布近似相干平顶高斯光束.     

单层介质膜保偏全反射直角三棱镜镀膜材料的选择及其微分相位特性研究

入射角、基底玻璃折射率、膜介质折射率、膜厚等因素会影响单层介质膜保偏全反射直角三棱镜的保偏特性，且各因素的影响程度并不相同。本文分析了上述各因素的微小变化对保偏特性的影响，并提出了选择膜介质的方法     

旋转光楔多重全息术

本文提出一种新颖的多重全息术,它是利用旋转光楔调制平面参考波的传播方向,实现编码参考光记录获得多重全息图.该全息图经球面波再现,获得位于同一平面内的再现多重象.文中给出了这种方法的理论分析和实验结果,两者是吻合的.     

Variable Wavelengths Fiber Bragg Gratings Written with A Phase Mask and Four Prisms

Using only one diffractive element, the Talbot interferometer provides a robust and inherently stable method for reproducing fiber Bragg gratings with variable wavelengths, and reduces the complexity of the fiber grating fabrication system. However, the usable length of the grating is limited by the practical length of the mirrors. This paper presents a phase mask with two fixed prisms and two rotational prisms to inscribe fiber Bragg gratings with variable Bragg wavelengths. In this system, the fiber Bragg grating is inscribed by UV interference stripes of 193 nm derived from two rotational prisms and two fixed prisms, where phase mask is used as a beam splitter of ±1 order diffraction light. It is noteworthy that the tunable phase mask interferometer decreases the demand of the length of prism evidently.