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81.
Ionic elastomers based on carboxylated nitrile rubber (XNBR) crosslinked with magnesium oxide (OMg) and filled with layered nanoclays have been prepared. Two types of nanofillers were employed: a commercial one (Cloisite 15 A) and the other prepared in our laboratory (BCA-ODA). The properties of raw and vulcanized compounds have been studied in order to elucidate the effect of layered nanoclays. X-ray diffraction analysis shows that during compounding and crosslinking the macromolecular chains of rubber were intercalated in a commercial nanofiller, whilst our nanoclay was exfoliated. However, this fact does not affect the properties of compounds homogeneously. Vulcanization parameters, Mooney viscosity and decay and rheological properties were affected depending on the filler type. Mechanical properties were not significantly varied, but glass transition temperature and ionic transition temperature were shifted in comparison with those of the unfilled compound. 相似文献
82.
A room temperature method for the encapsulation of pyrene in SiO2 nanoparticles is described. The relation between alkoxysilane surfactant chain length, reactant molar ratios and the uptake of dye, sample morphology, photophysical properties, and the ability of the silicate matrix to protect the encapsulated dye was examined. The synthesis can easily be adapted for the encapsulation of other hydrophobic and thermolabile substances, and used in the development of nanostructured optically active coatings, films and monoliths. 相似文献
83.
针对重力输水管道设计中存在的问题,文章以管道造价最小为目标,应用动态规划,提出了一种新的重力输水管道优化设计方法,对输水管的当量管径、流量分配、连接管设置与可靠性校核计算等问题作了探讨。该方法可用于沿线有节点流量流出的并联输水管道优化设计,能明显节省投资,有良好的实用性 相似文献
84.
T.R. Saitoh N. Hashimoto G. Sletten R.A. Bark S. Törmänen M. Bergström K. Furuno K. Furutaka G.B. Hagemann T. Hayakawa T. Komatsubara A. Maj S. Mitarai M. Oshima J. Sampson T. Shizuma P.G. Varmette 《The European Physical Journal A - Hadrons and Nuclei》1998,3(3):197-199
High-spin states in 181Ta have been studied via the 176Yb(11B,α2n) reaction at 52 MeV using the PEX array and at 57 MeV using the NORDBALL array, with α-particle detection. The previously
known, Kπ=(7/2)+ ground state band and Kπ=(9/2)− band have been extended to spins (29/2)+ and (31/2)−, respectively. Two new one-quasiparticle bands, the Kπ=(5/2)+ band built on the known (5/2)+ isomer and a Kπ=((1/2)−) band have been observed. Two other rotational bands with three-quasiparticle structure, Kπ=(15/2)− and ((19/2)+ with π(7/2)[404]ν2(1/2)[510](9/2)[624] and π(9/2)[514]ν2(1/2)[510](9/2)[624] configurations, respectively, have been newly observed. The half-life of the Kπ=((19/2)+) bandhead which decays to the head of the (15/2)− band has been measured to be 140(36) ns. However, transitions from the ((19/2)+) state to the (15/2)− band have not been observed.
Received: 26 August 1998 相似文献
85.
R. Cressely V. Hartmann 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,6(1):57-62
In this experimental work we carefully investigate the rheological behaviour and in particular the shear thickening exhibited
by aqueous micellar solutions of CTAB with NaSal as added counterion. We are particularly interested in the evolution of the
critical shear rate (at which shear thickening occurs) versus
C
D
, the surfactant concentration. We show that , at fixed salt concentration C
S
, increases with C
D
following a power law evolution with a positive exponent of + 5.8. On the other hand we show that if the ratio C
D
/ C
S
is fixed, decreases with C
D
with a negative exponent of -2.0. Nevertheless investigations of the zero shear viscosity indicate that in all situations (implying variation of the surfactant concentration C
D
, or the salt concentration C
S
or the temperature) is a decreasing function of the length of the micelles. All these evolutions are compatible with a gelation mechanism which
could possibly be associated with entanglement effects of large interacting flowing structures.
Received: 3 March 1998 / Revised: 16 June 1998 / Accepted: 3 July 1998 相似文献
86.
C. Andreoiu D. Rudolph I. Ragnarsson C. Fahlander R.A.E. Austin M.P. Carpenter R.M. Clark J. Ekman R.V.F. Janssens T.L. Khoo F.G. Kondev T. Lauritsen T. Rodinger D.G. Sarantites D. Seweryniak T. Steinhardt C.E. Svensson O. Thelen J.C. Waddington 《The European Physical Journal A - Hadrons and Nuclei》2002,14(3):317-348
High-spin states in 59Cu were populated using the fusion-evaporation reaction 28Si + 40Ca at a beam energy of 122 MeV. The Gammasphere Ge-detector array in conjunction with the 4π charged-particle detector array
Microball allowed for the detection of γ-rays in coincidence with evaporated light particles. The resulting extensive high-spin
decay scheme of 59Cu is presented, which comprises more than 320 γ-ray transitions connecting about 150 excited states. Their spins and parities
have been assigned via directional correlations of γ-rays emitted from oriented states. Average quadrupole moments of rotational
bands have been determined from the analysis of residual Doppler shifts. Shell model calculations in the fp shell are invoked to study some of the low-spin states, while the experimental characteristics of the rotational bands are
analyzed in the configuration-dependent cranked Nilsson-Strutinsky (CNS) approach.
Received: 15 February 2002 / Accepted: 23 April 2002 相似文献
87.
基于专家动态权重的群组AHP交互式决策方法 总被引:2,自引:0,他引:2
为了能在群组决策中得到更为客观和准确的决策结果,在把专家权重划分为静态权重和动态权重的基础上,研究了在交互式决策中专家动态权重的确定方法,给出了共识度的一个定义.在此基础上,研究了群组AHP交互式决策方法中的一致性和相容性检验,给出了基于专家动态权重的群组AHP交互式决策方法流程,最后用一个示例说明了该方法的应用步骤. 相似文献
88.
N. B. Brusnikina A. V. Lotov 《Computational Mathematics and Mathematical Physics》2007,47(11):1779-1787
A method is proposed for approximating the reachable set of a dynamic system with a state space dimension no higher than six-eight considered on a finite time interval. The system is governed by linear differential equations with piecewise constant coefficients and impulse actions specified at prescribed times. The method is based on guaranteed-accuracy polyhedral approximations of reachable sets at researcher-specified times. Every approximation is constructed using the preceding one. A procedure is described for choosing parameters of the method that ensure the required accuracy with close-to-minimal time costs. 相似文献
89.
航空公司在给定的运力和机队配置条件下,如何适应航线需求的不断变化而合理地分配运力,使航空公司的经营效益最大化是我国航空经营管理的一个重大课题.根据航班效益分析,在一定的经营时间,航行班次的条件下,建立一个航线贡献最大化的含有随机变量的动态规划模型.求解方法是先用M ON TE C ARLO方法计算机仿真把模型转化为非线性的整数规划.再用动态规划中资源分配算法求出模型的最优解,编排最优各航线规划. 相似文献
90.
Hiroshi Aoki Ken Hosoya Tomohisa Norisuye Nobuo Tanaka Daisuke Tokuda Norio Ishizuka Kazuki Nakanishi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(2):949-958
An investigation was made of the gelation of dimethacrylate‐type crosslinking agents in view of an application for separation media. The study mainly centered on a crosslinking agent, glycerol dimethacrylate (GDMA), which is relatively hydrophilic because of a hydroxyl group in the middle of its structure. The gelation of GDMA was compared with that of other hydrophobic crosslinking agents such as ethylene glycol dimethacrylate and 1,6‐hexanediol dimethacrylate. The diluents used in the study were toluene, toluene with methanol, and cyclohexanol. The gelation was observed in real time with a charge coupled device camera and dynamic light scattering (DLS). Also, the separated dry gels were extensively characterized with scanning electron microscopy, BET (N2 absorption and desorption isotherm), and Fourier transform infrared. DLS analysis showed a stronger molecular interaction of GDMA gelation in toluene, whereas this interaction was much weaker in an alcoholic solvent such as toluene with methanol or cyclohexanol. This indicated that GDMA gelation might proceed through hydrogen bonding as well as a crosslinking reaction of vinyl groups. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 949–958, 2006 相似文献