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991.
建立了用于住宅建设污染土壤中1,8-二硝基蒽醌、1,5-二硝基蒽醌、1-氨基蒽醌、蒽醌、萘、1,4,5,8-四氯蒽醌等6种蒽醌类化合物含量的高效液相色谱分析方法。利用Ultimate双三元液相色谱仪的特点,设计了一套并联式双系统,采用2根相同的色谱柱(Dikma Diamonsil C18)交叉分析,节省了41.46%的分析时间。以50 mL N,N-二甲基甲酰胺-1,4-二氧六环-甲醇(5:20:25, v/v/v)为萃取剂,采用超声波辅助方法提取样品中的6种目标物。6种目标物的平均加标回收率为82.7%~101%,相对标准偏差为1.8%~3.2%,检出限(以信噪比为3计)为0.007~0.054 mg/kg,可满足北京地方标准DB11/T 811-2011的限量要求。该方法简便、准确,并能节省检测时间,有良好的重现性,可用于土壤中蒽醌类化合物的检测。 相似文献
992.
993.
Mohamed Ahmed Mohamady Hussein Oguzhan Gunduz Ali Sahin Mariusz Grinholc Ibrahim Mohamed El-Sherbiny Mosaad Megahed 《Molecules (Basel, Switzerland)》2022,27(7)
In this study, a dual spinneret electrospinning technique was applied to fabricate a series of polyurethane (PU) and polyvinyl alcohol–gelatin (PVA/Gel) nanofibrous scaffolds. The study aims to enhance the properties of PU/PVA-Gel NFs loaded with a low dose of nanoceria through the incorporation of cinnamon essential oil (CEO). The as-prepared nCeO2 were embedded into the PVA/Gel nanofibrous layer, where the cinnamon essential oil (CEO) was incorporated into the PU nanofibrous layer. The morphology, thermal stability, mechanical properties, and chemical composition of the produced NF mats were investigated by STEM, DSC, and FTIR. The obtained results showed improvement in the mechanical, and thermal stability of the dual-fiber scaffolds by adding CEO along with nanoceria. The cytotoxicity evaluation revealed that the incorporation of CEO to PU/PVA-Gel loaded with a low dose of nanoceria could enhance the cell population compared to using pure PU/PVA-Gel NFs. Moreover, the presence of CEO could inhibit the growth rate of S. aureus more than E. coli. To our knowledge, this is the first time such nanofibrous membranes composed of PU and PVA-Gel have been produced. The first time was to load the nanofibrous membranes with both CEO and nCeO2. The obtained results indicate that the proposed PU/PVA-Gel NFs represent promising platforms with CEO and nCeO2 for effectively managing diabetic wounds. 相似文献
994.
995.
Creation of a superhydrophobic surface from an amphiphilic polymer 总被引:12,自引:0,他引:12
996.
氮氧化物(简称NOx,包括NO和NO2等)是形成二次有机气溶胶的重要前体物,其存在会严重影响空气质量并危害人类健康.目前用于NOx的去除的方法主要有过滤、物理吸附、热催化等.然而,这些技术存在高能耗及产生二次污染等缺点,严重制约其实际应用.近年来,光催化技术作为一种有效处理NOx的环保技术,因其具备在常温下高效处理低浓度NOx(大气污染浓度水平)的优点而获得广泛关注.最近,Bi2WO6光催化剂因其独特的层状结构以及特有的催化性质,表现出良好的可见光催化性能.Bi2WO6光催化性能与催化剂的形貌及尺寸大小密切相关,目前报道的Bi2WO6的形貌有片状、颗粒状、花状、中空微球等.其中,由小纳米颗粒堆积成的中空Bi2WO6微球因其大的比表面积和高的荷质传输速率,表现出显著优于其它形貌的光催化性能.目前已有少量关于中空结构Bi2WO6微球的制备方法的报道,这些方法均需引入纳米球状的"核"作为模板,并在其上生长Bi2WO6胶体颗粒,然后去除"核",从而得到中空结构.譬如,Shang等采用碳纳米球作为"核"制备出Bi2WO6微球,再通过煅烧手段去除碳"核".Thillai与合作者用硅球作为"核",为了得到中空结构Bi2WO6微球,用NaOH将硅"核"刻蚀.然而这类方法均涉及到复杂的制备过程和高昂的运行成本.超生喷雾热分解法是一种常见的制备尺寸可控的纳米球的方法.在之前的工作中,本研究组成功使用超声喷雾热解法制备出具有优良光催化活性的Bi2WO6实心微球.我们首次加入NaCl盐为模板,使用简单的超声喷雾热分解方法制备出具有中空结构的Bi2WO6微球光催化剂,合成过程无需采用复杂的除"核"手段.一系列表征表明:该微球由直径为41?148 nm的纳米片自组装而成,并在表面形成了不均匀分布的孔结构;并对Bi2WO6中空微球的生长机制做了详细的研究,考察了所制备Bi2WO6催化剂去除NO的效率.生长机制研究结果表明,NaCl盐在中空Bi2WO6微球的形成过程中发挥着关键性作用:(1)NaCl盐溶液在超生喷雾热分解法的高温过程中形成NaCl单晶并作为"核"模板,参与中空Bi2WO6微球的形成;(2)Na+离子有助于Bi2WO6微球的微结构-纳米片的生长;(3)Cl?离子有利于Bi2WO6微球表面微孔的形成;(4)NaCl模板水洗后留下中空结构的Bi2WO6微球;(5)NaCl盐也充当着多孔诱发剂,其水洗溢出过程会造成Bi2WO6微球表面的孔结构.性能测试表明,以NaCl盐为模板所制备的中空Bi2WO6微球表现出优异的光催化性能,其在模拟太阳光下去除NO的效率是未添加模板的1.7倍、以KCl为模板的1.5倍、以Na2SO4为模板的1.2倍.BET和DRS分析表明,中空结构Bi2WO6微球具有大的比表面积和高的可见光吸收,对提高催化性能起到重要作用.ESR测试结果表明,?OH和?O2?是中空Bi2WO6微球的光催化反应过程的主要活性物种,?O2?的产生有助于提高光催化剂降解NO的耐受性. 相似文献
997.
This paper describes a central difference scheme for the prediction of flows with an interface. The interface is captured rather than tracked and the key to the current approach is a correction to the hydrostatic pressure. The correction enables the scheme to evaluate pressures at cell faces in a consistent manner so that the source term in the equations is correctly balanced at the interface and on non‐equispaced meshes. This prevents the development of large errors in the solution, which can lead to the divergence of the numerical scheme. The current approach allows interface flows to be calculated by a simple modification of existing central difference codes. Results for a number of test cases are presented, with comparisons made with both experimental data and other numerical solutions. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
998.
Marek Galewski 《Proceedings Mathematical Sciences》2008,118(4):627-635
We provide existence and stability results for semilinear Dirichlet problems with nonlinearity satisfying general growth conditions.
We consider the case when both the coefficients of the differential operator and the nonlinear term depend on the numerical
parameter. We show applications for the fourth order semilinear Dirichlet problem. 相似文献
999.
B. Farkas 《Acta Mathematica Hungarica》2003,98(1-2):71-77
Given a measure space < Ω,m,μ >, a locally bounded, Hausdorff topological linear space < X, τ > and a real number 0<p<1, one can define the space Lp(Ω,m,μ,X), which is, under certain assumptions, a Fréchet space if endowed with a suitable topology. M.M. Day [1] has given a necessary
and sufficient condition, in terms of the properties of the measure space < Ω,m,μ >, for the dual of Lp(Ω,m,μ,C) to be trivial. In this paper a different proof along with a slight generalization is given for this result, using standard
and elementary measure theoretic arguments.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
1000.
A. G. U. Perera 《Opto-Electronics Review》2006,14(2):99-108
The work describes multiband photon detectors based on semiconductor micro-and nano-structures. The devices considered include
quantum dot, homojunction, and heterojunction structures. In the quantum dot structures, transitions are from one state to
another, while free carrier absorption and internal photoemission play the dominant role in homo or heterojunction detectors.
Quantum dots-in-a-well (DWELL) detectors can tailor the response wavelength by varying the size of the well. A tunnelling
quantum dot infrared photodetector (T-QDIP) could operate at room temperature by blocking the dark current except in the case
of resonance. Photoexcited carriers are selectively collected from InGaAs quantum dots by resonant tunnelling, while the dark
current is blocked by AlGaAs/InGaAs tunnelling barriers placed in the structure. A two-colour infrared detector with photoresponse
peaks at ∼6 and ∼17 μm at room temperature will be discussed. A homojunction or heterojunction interfacial workfunction internal
photoemission (HIWIP or HEIWIP) infrared detector, formed by a doped emitter layer, and an intrinsic layer acting as the barrier
followed by another highly doped contact layer, can detect near infrared (NIR) photons due to interband transitions and mid/far
infrared (MIR/FIR) radiation due to intraband transitions. The threshold wavelength of the interband response depends on the
band gap of the barrier material, and the MIR/FIR response due to intraband transitions can be tailored by adjusting the band
offset between the emitter and the barrier. GaAs/AlGaAs will provide NIR and MIR/FIR dual band response, and with GaN/AlGaN
structures the detection capability can be extended into the ultraviolet region. These detectors are useful in numerous applications
such as environmental monitoring, medical diagnosis, battlefield-imaging, space astronomy applications, mine detection, and
remote-sensing.
The paper presented there appears in Infrared Photoelectronics, edited by Antoni Rogalski, Eustace L. Dereniak, Fiodor F. Sizov, Proc. SPIE Vol. 5957, 59570W (2005). 相似文献