中子与63,65Cu反应的理论计算

根据中子与天然Cu及其同位素反应的总截面, 去弹截面和弹性散射角分布的实验数据, 得到中子的光学模型势参数; 应用得到的光学模型势参数, 光学模型, 统一的Hauser-Feshbach和激子模型理论, 以及扭曲波玻恩近似理论, 系统计算和分析了中子与^63,65Cu反应的非弹散射角分布和双微分截面, 理论结果与实验很好的一致.     

Crystal Structure of a Novel Phosphorane (C30H27N3O12P4)with Three P-P Bonds

1　INTRODUCTIONInrecentyears,therehasbeenmuchinterestinphosphoranescontainingonlyonephosphorus-phosphorusbondandthestructuresofmostofthesecompoundshavebeenidentifiedbyX-raycrystallography[1～6].In1990,anewtypeofphosphoraneinvolvingtwoP-Pbondswassuccessfullysynthesized[7],butthecrystalstructurewasnotdetermined.Wehavesuccessfullysynthesizedthenovelphosphorane3bear-ingthreeP-Pbonds.Hereitscrystalstructureisreported.2　EXPERIMENTAL2.1　PreparationAllprocedureswereperformedunderN2atmos…     

一类Burgers方程的孤立波解

Burgers方程在工程上有着重要的应用,它可以用来描述湍流、车队的交通流、氏族的随机迁移、化学工程中的分离等现象,对Burgers方程求解方法的研究有着重要的现实意义.对Burgers方程求解主要是应用差分和微分两方面的方法来展开求解的,1/G展开法是近年来发展起来的求解非线性偏微分方程的一种较为有效的微分解法.采用微分方程方面的方法,利用1/G展开法对一类Burgers方程进行求解,得到了此方程的一类孤立波解和扭曲波解,同时描绘出解的图像并分析解的结构和变化趋势.     

Electron impact ionization cross sections for Li-like Al ion in ground and excited states

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Oxidative coupling of radicals in reactions of compounds of tervalent iodine with trimethylsilyl(phenyl) acetylene

Reactions of trimethylsily](phenyl)acetyleiie with aryl and alkyl difluoroiodides give coupling products of substituents in high yields.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 1022–1023, April, 1996.     

基于主成分分析的图像匹配方法

将主成分分析引入图像匹配过程，提出了一个基于主成分分析的图像匹配算法，将根据基准图来制备畸变图集，并用这些畸变图来作为训练样本，由这些畸形变像确定新的主成分空间，把畸变图变换到主成分这间中，在变换过程中尽量存原始图像的整体特征，在新空间做匹配，并以处理人脸图像匹配为应实例来检验匹配结果，该算法有一定的抗畸变能力。     

Orientational disorder in crystal structures of (NH<Subscript>4</Subscript>)<Subscript>3</Subscript>ZrF<Subscript>7</Subscript> and (NH<Subscript>4</Subscript>)<Subscript>3</Subscript>NbOF<Subscript>6</Subscript>

Crystal structures of (NH₄)₃ZrF₇ (I) and (NH₄)₃NbOF₆ (II) are refined by X-ray diffraction at room temperature. The compounds are isostructural and belong to the structural type of elpasolite: space group F23; a(I) = 9.4185(3) Å, a(II) = 9.3371(5) Å; V(I) = 835.50(5) ų, V(II) = 814.02(8) ų; Z = 4; R(I) = 0.0145, and R(II) = 0.0138. The refinement of the structures in the space group Fm3m yields abnormally short X-X distances in the pentagonal bipyramid MX₇ (X = F, O). The oxygen atom in II is identified by Nb-X distances and occupies one of the axial vertices of the bipyramid. The Nb atom in II is statistically distributed over the position 24f, while Zr in I resides in the symmetry center. The pentagonal bipyramid MX₇ has six independent orientations in I and twelve in II. One of three crystallographically independent ammonium groups of the structures is disordered over six or twelve equivalent orientations.     

DNA三角双锥结构的放射性标记

分别采用点击化学方法对DNA三角双锥结构进行氟-18标记研究,采用二氯亚锡还原法对DNA三角双锥结构进行锝-99m标记研究.结果表明,点击化学方法不适用于DNA三角双锥结构的氟-18标记;而采用二氯亚锡还原法则制得了以DNA三角双锥结构为载体的分子影像探针99mTc-DBNs.     

用于大景深三维纳米分辨多分子追踪的衍射光学元件的设计制备和实验研究

发展能实时检测完整细胞内多个生物分子随时空变化的单分子探测和追踪技术, 对于研究生命过程的分子机理具有重要意义. 在变形光栅多阶成像和双螺旋点扩散函数成像方法的基础上, 基于波前编码的原理, 提出将二者优化结合, 获得全新的衍射光学元件, 该器件同时具有多重平面成像和双螺旋点扩散函数成像的功能, 旨在解决活细胞内单分子探测和追踪技术中的大景深探测难题. 设计和制备了该器件, 并基于该器件搭建了显微成像系统, 实验模拟证明该衍射光学元件同时可实现轴向12 μ的探测范围, 与理论设计结果相符合, 从而有效扩大了显微镜系统的景深, 证明了设计的可行性. 关键词： 多分子追踪 衍射光学元件 变形光栅 双螺旋点扩散函数     

Solid state synthesis and characterization of a triple chain calcium(II) coordination polymer showing two different bridging 4-nitrobenzoate coordination modes

The solid state reaction of [Ca(H₂O)₄(η¹-4-nba)(η²-4-nba)] 1 (4-nba = 4-nitrobenzoate) with 2-methylimidazole (L²) at 100 °C results in the formation of a Ca(II) coordination polymer [Ca(H₂O)(L²)(4-nba)₂]_n2. Compound 2 was characterized by elemental analysis, spectral and thermal methods, and its structure determined. The coordination polymer 2 crystallizes in the centrosymmetric monoclinic space group P2₁/n with all atoms situated in general positions and its structure consists of a central Ca(II), a monodentate 2-methylimidazole, a bridging water ligand (μ₂-H₂O), a bidentate bridging (μ₂-η¹:η¹) 4-nba ligand and a monoatomic bridging (μ₂-η²) 4-nba ligand. Each seven-fold coordinated Ca(II) in the title compound is bonded to a nitrogen atom of a terminal 2-methylimidazole (L²) ligand, two symmetry related water molecules and four symmetry related 4-nba ligands, resulting in a distorted pentagonal bipyramidal {CaO₆N} polyhedron. Due to the bridging nature of the aqua and 4-nba ligands [(2-methylimidazole)calcium(II)] units in 2 are linked into a one-dimensional coordination polymer consisting of three chains, all of which propagate along b-axis. In the triple chain coordination polymer a Ca···Ca separation of 3.8432(3) Å is observed between neighbouring Ca(II) ions. The oxygen atoms of the carboxylate and nitro functionalities of the 4-nba ligand and the coordinated water are involved in O–H···O, N–H···O and C–H···O interactions. A comparative study of nine alkaline-earth 4-nitrobenzoate compounds is described.