Finite deformation swelling of a temperature-sensitive hydrogel cylinder under combined extension-torsion

The swelling behavior of a temperature-sensitive poly-N-isopropylacrylamide(PNIPAM) hydrogel circular cylinder is studied subjected to combined extension-torsion and varied temperature. In this regard, a semi-analytical solution is proposed for general combined loading. A finite element(FE) analysis is conducted, subjecting a hydrogel cylinder to the combined extension-torsion and the varied temperature to evaluate the validity and accuracy of the solution. A user-defined UHYPER subroutine is de...     

HL-2M偏滤器结构动力学分析

用有限元软件分析了动载荷作用下的偏滤器结构动力学响应。通过对动力学和静力学计算结果的对比,确定载荷的动态放大因子。计算结果表明,所设计的偏滤器结构在瞬态电磁力载荷作用下能满足设计准则的要求。     

离散梯度法在基于图像的计算生物力学中的应用1)

介绍一种可用于计算生物力学的离散梯度方法,此方法可利用离散的点云模型直接进行数值模拟分析而不需要传统的几何模型。将离散梯度法应用于点云模型需要首先确定模型中点之间的相邻关系和每个点所分配的材料体积,然后通过用广义的有限差分的形式定义了梯度插值向量,并以此向量来近似函数在每个离散点上的梯度。从弱形式出发,推导建立了适用于弹性固体大变形问题的求解器,并具有和有限元法中双线性四边形单元一致的准确性和收敛性。着重描述了一种可以从医学图像中快速提取材料点并建立点云模型的方法,以及利用三角划分和重心划分确定材料点之间的相邻关系和每个材料点体积的具体过程。通过腹主动脉瘤膨胀的静力学模拟分析,展示了离散梯度法的实用性和准确性。该算法实现了基于医学图像进行生物力学分析的过程自动化,为病体特异性的研究和治疗提供便利和实用的工具。     

岩土工程下沉贯入数值模拟方法研究进展

岩土工程下沉贯入领域的数值分析,由于结构物贯入时网格变形过大而产生扭曲畸变等问题,常会造成收敛困难甚至计算结果失真. 采用合适的数值方法分析此类问题颇具挑战性. 本文系统介绍了近年来对于岩土下沉贯入数值模拟的研究现状和发展动态,对各种数值模拟方法的相关原理、主要特征以及优缺点进行简要的探讨. 并简要介绍耦合的欧拉-拉格朗日(coupled Eulerian-Lagrangian, CEL) 有限元法的基本原理,通过不排水条件下的条形基础贯入问题和砂土中桩的静压下沉示例分析,表明CEL 有限元法在模拟岩土贯入问题时计算结果的准确性和较其他模拟方法的优势. 文中所阐述的岩土贯入分析数值模拟方法可供从事岩土贯入分析的相关学者借鉴参考.     

基于改进匹配追踪算法的化爆地震波信号时频特征提取

通过化爆地震波信号的时频分析可以获取丰富的地下岩层信息,为进一步的化爆地震波特性研究提供支撑。本文中利用爆炸地震波信号的非平稳随机特性,提出一种改进的匹配追踪算法(matching pursuits),该方法能更有效地获取化爆地震波信号的时频信息。该算法首先对地震波信号进行Hibert变换,将其转换成复数信号,获得爆炸地震波信号瞬时频率相位参数,再进行子波分解,从而显著提高了匹配追踪算法的运算速率;用分解后的信号计算其魏格纳威利分布(Wigner Ville distribution),有效地消除了交叉干扰项的影响。将该方法用于实测地震波信号的时频分析,获得了分辨率较高的时频分布图,且运算速率大大提高。

     

全长锚固锚杆锚固单元力学性能实验研究

锚固单元的传力特性是影响全长锚固锚杆支护能力的重要因素。由于锚固单元界面构成复杂,本文主要考虑锚杆与粘结材料及其界面的力学特性,开展锚固单元界面剪切力学实验研究。实验结果表明,砂浆强度直接影响界面的峰值强度和剪切刚度;采用相同强度砂浆,界面的峰值强度、剪切刚度和残余剪切强度都与法向应力成正比;在相同法向应力作用下,剪切速率增加引起峰值剪切强度增大,但对残余剪切强度影响较小。依据实验剪切应力–位移曲线将锚固单元与岩石间界面的解耦过程分为“峰前–软化–滑移”三阶段,非连续变形分析方法数值模拟结果表明,加载初期的损伤主要受粘结材料抗拉强度的影响,临近峰值阶段与粘结材料张剪混合破裂相关;软化阶段和滑移阶段主要受粘结材料剪切特性和颗粒形状的影响;引入实验所获得的三线滑移模型曲线到全长锚固锚杆模型,模拟拔出数值实验结果表明较快拔出速率将影响锚杆变形能力。

     

斜圈弹簧力学性能的有限元分析

斜圈弹簧在医疗器械、高压开关、汽车工业等领域应用广泛. 但其结构特殊, 受力复杂, 目前尚无有效的理论计算方法得出其载荷位移曲线, 只能通过数值仿真的方法研究其力学性能. 利用有限元软件ANSYS参数化建立环形斜圈弹簧有限元模型, 通过对模型的分析求解, 得出了其主要参数线径、节距、倾斜角与斜圈弹簧力学性能之间的关系. 研究了斜圈弹簧工作状态下的受力变形情况, 计算分析结果为斜圈弹簧的优化设计和合理应用提供了理论依据.     

Chemometric Assisted UV-Spectrophotometric Methods Using Multivariate Curve Resolution Alternating Least Squares and Partial Least Squares Regression for Determination of Beta-Antagonists in Formulated Products: Evaluation of the Ecological Impact

In this study, UV-spectrophotometry coupled with chemometrics has been utilized to enhance the sustainability of quality control analysis of beta antagonists. First, we developed and optimized two eco-friendly chemometric-assisted methods without preliminary separation utilizing (1) multivariate curve resolution alternating least squares (MCR-ALS) and (2) well-established partial least squares regression (PLSR) multivariate calibration for the resolution and quantification of the most commonly prescribed beta antagonists in active pharmaceutical ingredients or commercial pharmaceutical products. The performance of the two proposed chemometric methods was computed and compared. Second, a comprehensive qualitative and quantitative evaluation of the eco-friendliness of the developed methods was performed utilizing the following greenness assessment tools: Green Analytical Procedure Index (GAPI), Analytical Eco-scale assessment (AES) tool, Raynie and Driver’s assessment tool and Analytical GREEnness Metric (AGREE). The models showed satisfactory recovery with a range from 99.83% to 101.12% for MCR-ALS and from 99.66% to 101.54% for PLSR. The optimized models were employed for green analysis of the investigated beta-blockers in single or co-formulated formulations without prior separation. The predictivity of the proposed MCR-ALS and the well-established PLSR method were very comparable. Nevertheless, the MCR-ALS method has the ability to recover the pure spectra of the studied analytes and the interferences as well. The proposed chemometric methods are fast, precise and do not need any sample pretreatment. In addition, they can be used as a benign substitute for the traditional methods used for the analysis of the investigated drugs in pharmaceutical products without harmful impacts on human health and the environment. They also provide advantages in terms of low solvent usage, reduced energy consumption and short analysis time, making them a safe and sustainable approach for quality control analysis.     

Dihydrogen Bonding—Seen through the Eyes of Vibrational Spectroscopy

In this work, we analyzed five groups of different dihydrogen bonding interactions and hydrogen clusters with an H3+ kernel utilizing the local vibrational mode theory, developed by our group, complemented with the Quantum Theory of Atoms–in–Molecules analysis to assess the strength and nature of the dihydrogen bonds in these systems. We could show that the intrinsic strength of the dihydrogen bonds investigated is primarily related to the protonic bond as opposed to the hydridic bond; thus, this should be the region of focus when designing dihydrogen bonded complexes with a particular strength. We could also show that the popular discussion of the blue/red shifts of dihydrogen bonding based on the normal mode frequencies is hampered from mode–mode coupling and that a blue/red shift discussion based on local mode frequencies is more meaningful. Based on the bond analysis of the H3+(H2)n systems, we conclude that the bond strength in these crystal–like structures makes them interesting for potential hydrogen storage applications.     

邻菲啰啉计算光度法同时测定生物浸出样品中Fe（Ⅱ）和Fe（Ⅲ）

邻菲啰啉光度法常用于Fe（Ⅱ）测定,但受到试样中Fe（Ⅲ） 对测定的影响,因此不能直接用于生物浸出样品中Fe（Ⅱ）和Fe（Ⅲ） 的同时测定. 为此,基于Fe（Ⅱ）邻菲啰啉特征吸收曲线以及混合铁中Fe（Ⅲ） 对Fe（Ⅱ）测定的线性影响关系,建立了基于Fe（Ⅱ）和全铁同时测定Fe（Ⅱ）和Fe（Ⅲ）的计算光度法,并研究了生物浸出样品中典型金属离子（Cu²⁺、Ni²⁺、Cd²⁺、Co²⁺）以及试样溶解与储放对测定的影响.方法可准确地测定含铁次生矿物和生物浸出液中铁价态组成,应用于生物浸出矿渣、细胞表面中常量或微量的Fe（Ⅱ）和Fe（Ⅲ） 组成分析,具有简便快速的特点.