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101.
A simple and efficient preparation of a number of hybrid linear‐branched PEG esters are described. The polymers are generated by direct coupling of PEG–carboxylic acids and a variety of pentaerythritol ethoxylates using carbon tetrabromide catalyst.  相似文献   
102.
《合成通讯》2013,43(9):1203-1208
Abstract

A new and efficient solid‐state method for the preparation of thiohydantoins is reported. With this method, twelve thiohydantoin compounds have been synthesized in good to excellent yields (81–92%). In addition, this method has the advantages of high yields, a cleaner reaction, simple methodology, and short reaction times.  相似文献   
103.
In this paper the affine connection approach will be used to calculate the elastic constants of nematic liquid crystals. Following this approach, which was originally conceived to compute the nematic viscosity coefficients, an expression for the elastic constants, without adjustable free parameters, will be formulated in terms of a temperature dependent metric, whose non‐isotropic part is proportional to the tensorial order parameter of the nematic phase. The dependence of the elastic constants on the scalar order parameter, in the geometry of the nematic molecules, and in the anisotropic part of the molecular interaction, will be determined.  相似文献   
104.
Thermotropic ionic liquid crystals (LCs) are useful for a number of applications such as anisotropic ion transport and as organised reaction media/solvents because of their ordered fluid properties and intrinsic charge units. A large number of different ionic LC architectures are known, but only a handful of examples of gemini (i.e. paired or dimeric) ionic LCs have been prepared and studied. In this work, a series of 20 new symmetric, imidazolium-based, gemini cationic LCs containing two bridged imidazolium cations and two pendant alkyl chains was synthesised, and the thermotropic LC behaviours were characterised. The imidazolium unit provides a highly tunable and modular platform for the design and synthesis of gemini cationic LCs which offers excellent structure control. As expected, the thermotropic LC properties of these new amphilphilic, gemini ionic LCs were found to be strongly influenced by the length of the spacer between the imidazolium units, the length of the pendant alkyl tails, and the nature of the anion. Smectic A (SmA) thermotropic LC phases were observed in more than half of the gemini imidazolium LC systems studied.  相似文献   
105.
Per- and poly-substituted oligosaccharide derivatives, with trehalose cores, have been prepared and assessed for their potential for use as excipients in controlled-release formulations. The synthesized compounds, generally with acyl and amido substituents, included 6,6′-N,N′ -diamido-6,6′ -dideoxy-α,α -trehalose derivatives, 6,6′ -bis(1,2,3,4-tetra-O-acetyl-β -D-glucopyranuronyl)-α, α -trehalose derivatives, 2,2′,3,3′ -tetra-O-acetyl-6,6′ -bis-(1,2,3,4-tetra-O-acetyl-β-D-glucopyranuronyl)-4,4′ -di-O-acyl-α,α-trehalose, 2, 2′, 3, 3′ -tetra-O-acetyl-6-(1,2,3,4-tetra-O-acetyl-β-D-glucopyranuronyl)-4,4′,6′ -tri-O-acyl-α,α-trehalose, and 2,2′,3,3′,4,4′ -hexa-O-acetyl-6,6′ -bis-(1,2,3,4-tetra-O-acetyl-6-O-succinyl-β-D-glucopyranuronyl)-α,α-trehalose. Compounds were characterized by NMR, IR, MS and optical rotations; elemental analyses; or HRMS. The compounds formed amorphous materials either on fast quenching of melts or on spray drying. Properties, used in the initial assessment of the potential as controlled-release excipients, were log10 P and glass transition, Tg, values.  相似文献   
106.

New retinoyl sugar derivatives of 13‐cis‐retinoic acid were synthesized in three ways in this paper in order to enhance pharmacal effects, especially antiproliferative activities of 13‐cis‐retinoic acid. Their structures were confirmed by IR, 1H‐NMR, 13C‐NMR, and MS spectra and their antiproliferative activities were determined in vitro using human cancer lines. Results showed that some compounds possessed potential antitumor activities.  相似文献   
107.
The research provides a novel approach for producing diarylmethane derivatives using CB[7]–NaCl–PdCl2 catalyzed Suzuki cross-coupling reaction of benzyl chloride derivatives and arylboronic acids in ethanol aqueous solution.  相似文献   
108.
Herein a simple one-pot metal-free synthesis of alkyl-, aryl-, heteroaryl- and alkoxycarbonyl substituted 1,3-bis(dimethylamino)benzene derivatives is described. The products were prepared from the corresponding methyl ketones or compounds with an α-methylene group in regard to the carbonyl group, using N,N-dimethylacetamide dimethyl acetal (DMADMA) as the reagent.  相似文献   
109.
Transition-metal free direct C–H arylation of benzene with aryl halides was achieved by meso-aryl-substituted [14]triphyrins(2.1.1) catalysts in an air atmosphere. Various aryl halides underwent successful direct C–H arylation of benzene to give moderate to high yields of biaryls. A radical mechanism is proposed for this triphyrin catalyzed C–H arylation reaction.  相似文献   
110.
《Comptes Rendus Chimie》2014,17(4):301-304
2-Amino-5-oxo-4,5-dihydropyrano[3,2-c]chromene-3-carbonitrile derivatives are obtained in excellent yields by a simple, mild and efficient procedure by an electrocatalytic multicomponent chain transformation of aryl aldehydes, 4-hydroxycoumarin and malononitrile under neutral and mild conditions by electrolysis in an undivided cell in the presence of sodium bromide as an electrolyte.  相似文献   
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