Angle-resolved desorption and removal of surface nitrogen in deNOx

This paper reports on recent progress on angle-resolved desorption leading to structure-sensitive desorption dynamics. The sensitivity is exemplified in NO and N₂O reduction on Pd and Rh surfaces. The energy partitioning in the repulsive desorption of hyper-thermal products into their rotational and translational modes is an indispensable concept to examine the structure of a reaction site from desorbing molecules because it connects the structure of a transition state with each energy of desorbed products. The extent of the energy partitioning will be derived from the desorption-angle dependences of both the rotational and translational energies at each vibrational state. Such energy analysis has never been completed for any thermal reactive desorption. A new type of measurement is thus proposed. Additionally, we discuss the inadequate use of the detailed balance principle in desorption dynamics, which has prevented desorption dynamics from being sensitive to surface structures.     

Refinements of the Weyl Pure Geometrical Thick Branes From Information‐Entropic Measure

This work aims to analyse the so‐called configurational entropy in the Weyl pure geometrical thick brane model. The Weyl structure plays a prominent role in the brane thickness of this model. We find a set of parameters associated to the brane width where the configurational entropy exhibits critical points. The information‐theoretical measure sets bounds into parameter of Weyl pure geometrical brane model. In addition, we also argue that a similar approach can be useful to analyze the corrections to Newtonian and Coulombian potentials in Weyl scenarios.     

基于LabPQR降维的多色打印机光谱特征化模型研究

研究多色打印机的光谱特征化,提出了一种基于降维的光谱特征化模型,保证了多色打印机颜色转换的精度,同时也提高了特征化的运行效率。该模型结合颜色分区理论和LabPQR非线性降维方法,首先将高维光谱数据降低至LabPQR六维空间中,然后通过胞元搜索算法查找目标颜色所属的胞元空间,最后利用反向四面体插值算法对目标的LabPQR值进行计算,得到打印机最终的通道信号输出值。检测颜色样本的实验数据表明,正向模型和反向模型的平均色差达到0.714和1.016 NBS,模型的运行时间为2.03和9.05 s。新算法能够实现多色打印机光谱数据与通道信号值间的准确转换。     

Symmetry Reduction of the (2+1)-Dimensional Modified Dispersive Water-Wave System

Using the standard truncated Painlevé expansion, the residual symmetry of the (2+1)-dimensional modified dispersive water-wave system is localized in the properly prolonged system with the Lie point symmetry vector. Some different transformation invariances are derived by utilizing the obtained symmetries. The symmetries of the system are also derived through the Clarkson-Kruskal direct method, and several types of explicit reduction solutions relate to the trigonometric or the hyperbolic functions are obtained. Finally, some special solitons are depicted from one of the solutions.     

Magnetic phase diagram of anisotropic layered superconductors via magnetization measurements forH‖c in Bi2212

The Bi₂Sr₂CaCu₂O₈ system is viewed as an archetypal of superconductors modelled as Josephson coupled CuO₂ bilayers. The isothermal and temperature dependent DC and AC magnetization measurements forH‖c in a single crystal of Bi2212 have been performed. Qualitative changes are observed to occur over a narrow range of temperature values before reaching the superconducting-normal transition. The observed behaviour can be ascribed to the rapid variation in the strength of the coupling between the superconducting CuO₂ planes (i.e., bilayers in the case of Bi2212). Strongly coupled planes behave like a 3D superconductor, whereas weakly coupled planes have a two component response attributable to 2D planes and interplanar couplings. We believe that this paper is a plethora of new findings. Our observations imply that resistivity across the planes becomes zero earlier than that within the planes. A new line (designated asH _2D(T)) above which the change in the electromagnetic response is dominated by quasi 2D-planes has been determined for the first time. This paper also contains the first observation of Differential Diamagnetic Effect (DDE) in the In-phase AC susceptibility data which signals the onset (atT _2D(H)) of dominance of response from 2D-planes. In addition to a host of interesting thermomagnetic history effects which are a consequence of interplay between the diamagnetic responses from the two components, a comparison of irreversibility lines (of the 3D state) determined by different methods on the same specimen of a HTSC is also being presented for the first time. We have come across Paramagnetic Meissner Effect (PME), first recognized in ceramic samples of Bi2212, in the temperature region of dimensional crossover in our single crystal sample, whichinter-alia confirms our labelling of the two component behaviour. A schematic phase diagram summarizing the various transformations that can occur nearT _c in the electromagnetic response of an anisotropic layered system has been drawn.     

非线性光学效应与光速减慢

激光技术的发展为极限光速的测量和应用提供了有效工具。本主要介绍了与光速减慢有关的非线性光学知识和光速减慢的实验原理及方法。光速减慢实验中用到的低温Na原子气在探测激光和耦合激光的共同作用下处于量子相干态－－一种非线性极化状态,由于电磁感应透明效应（EIT）,探测光可以使介质的折射率改变并能透过Na原子气,使极限光速的测量和应用变为实现。     

有限维希尔伯特空间非简谐振子广义相干态

在有限维希尔伯特空间中构造了非简谐振子的广义相干态,并研究了其量子统计特性。详细地讨论了该量子态的压缩效应和反聚束效应,得到了出现压缩的条件并给陋了反聚束效应与有限维希尔伯特空间维数关系的数值计算结果。理论计算表明该量子态存在压缩效应和反聚束效应,这与通常的无限维空间中的广义相干态是完全不同的。     

Characterization of NOx species in dehydrated and hydrated Na- and Ba-Y, FAU zeolites formed in NO2 adsorption

Adsorbed ionic NO_x species formed upon the interaction of NO₂ with dehydrated or hydrated Na- and Ba-Y, FAU zeolites were characterized using FT-IR/TPD, solid state NMR, and XANES techniques. NO₂ disproportionates on both dehydrated catalyst materials forming NO⁺ and NO₃⁻ species. These ionic species are stabilized by their interactions with the negatively charged zeolite framework and the charge compensating cations (Na⁺ and Ba²⁺), respectively. Although the nature of the adsorbed NO_x species formed on the two catalysts is similar, their thermal stabilities are strongly dependent on the charge compensating cations. In the presence of water in the channels of these zeolite materials new paths open for reactions between NO⁺ and H₂O, and NO₂ and H₂O, resulting in significant changes in the adsorbed ionic species observed. These combined spectroscopic investigations afforded the understanding of the interactions between water and NO₂ on these zeolite catalysts.     

Reduction of Vaisman structures in complex and quaternionic geometry

We consider locally conformal Kähler geometry as an equivariant (homothetic) Kähler geometry: a locally conformal Kähler manifold is, up to equivalence, a pair $(K,\Gamma )$, where $K$ is a Kähler manifold and $\Gamma$ is a discrete Lie group of biholomorphic homotheties acting freely and properly discontinuously. We define a new invariant of a locally conformal Kähler manifold $(K,\Gamma )$ as the rank of a natural quotient of $\Gamma$, and prove its invariance under reduction. This equivariant point of view leads to a proof that locally conformal Kähler reduction of compact Vaisman manifolds produces Vaisman manifolds and is equivalent to a Sasakian reduction. Moreover, we define locally conformal hyperKähler reduction as an equivariant version of hyperKähler reduction and in the compact case we show its equivalence with 3-Sasakian reduction. Finally, we show that locally conformal hyperKähler reduction induces hyperKähler with torsion (HKT) reduction of the associated HKT structure and the two reductions are compatible, even though not every HKT reduction comes from a locally conformal hyperKähler reduction.     

Noise reduction by dynamic signal preemphasis

In this work we propose an approach to reduce the digitization noise for a given dynamic range, i.e., the number of bits, of an analog to digital converter used in an NMR receiver. In this approach, the receiver gain is dynamically increased so that the free induction decay is recorded in such an emphasized way that the decaying signal is digitized using as many number of bits as possible, and at the stage of data processing, the original signal profile is restored by applying the apodization that compensates the effect of the preemphasis. This approach, which we call APodization after Receiver gain InCrement during Ongoing sequence with Time (APRICOT), is performed in a solid-state system containing a pair of (13)C spins, one of which is fully isotopically labeled and the other is naturally abundant. It is demonstrated that the exceedingly smaller peak buried in the digitization noise in the conventional approach can be revealed by employing APRICOT.