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101.
Nak-Jin Seong Young-Hun Jo Myung-Hwa Jung Soon-Gil Yoon 《Journal of magnetism and magnetic materials》2006
Epitaxial Ti0.97Co0.03O2:Sb0.01(TCO:Sb) films were deposited on R-Al2O3 (1 1 0 2) substrates at 500 °C in various deposition pressures by pulsed laser deposition. The solubility of cobalt within the films increases with decreasing deposition pressure at a deposition temperature of 500 °C. The TCO:Sb films deposited at 5×10−6 Torr exhibit a p-type anomalous Hall effect having a hole concentration of 6.1×1022/cm3 at 300 K. On the other hand, films deposited at 4×10−4 Torr exhibits an n-type anomalous Hall effect having an electron concentration of about 1.1×1021/cm3. p- or n-type DMS characteristics depends on the change of the structure of TCO:Sb films and the solubility of Co is possible by controlling the deposition pressure. 相似文献
102.
Tungsten trioxide and titanium dioxide thin films were synthesised by pulsed laser deposition. We used for irradiations of oxide targets an UV KrF* (λ = 248 nm, τFWHM ≅ 20 ns, ν = 2 Hz) excimer laser source, at 2 J/cm2 incident fluence value. The experiments were performed in low oxygen pressure. The (0 0 1) SiO2 substrates were heated during the thin film deposition process at temperature values within the 300-500 °C range. The structure and crystalline status of the obtained oxide thin films were investigated by high resolution transmission electron microscopy. Our analyses show that the films are composed by nanoparticles with average diameters from a few to a few tens of nm. Moreover, the films deposited at substrate temperatures higher than 300 °C are crystalline. The tungsten trioxide films consist of a mixture of triclinic and monoclinic phases, while the titanium dioxide films structure corresponds to the tetragonal anatase phase. The oxide films average transmittance in the visible-infrared spectral range is higher than 80%, which makes them suitable for sensor applications. 相似文献
103.
《Electroanalysis》2006,18(10):947-954
In this work, for the first time a fast continuous cyclic voltammetry was used as a highly sensitive detection method for Penicillin G in a flow‐injection system. A special computer‐based numerical calculation method (using Fast Fourier Transformation) is introduced here for enhancing the analyte signal and noise reduction. During the measurements, the potential waveform (consists of potential steps for cleaning, stripping and potential ramp) was continuously applied on an Au disk microelectrode (with a radius 12.5 μm in radius). The stripping time was less than 200 ms. Effects of rest potential, sweep rate, and delay time on the sensitivity of the method were investigated. The limit of detection of the method was 1.0 × 10?11 M. The detection limit of the method is 660 times lower than the most sensitive reported method. The relative standard deviation of the method at 1.0×10?7 M of Penicillin G was 2.7% for 10 runs. 相似文献
104.
采用溶胶-凝胶方法在Si(111)上制备了LSMO(x=0.17)薄膜.研究了块体材料和不同厚度薄膜R -T曲线、红外光谱和X射线衍射.结果表明,LSMO薄膜属于正交晶体结构,薄膜取向与膜厚度 有关,当膜厚度为450nm或680nm时,主要取向〈200〉,而膜厚度为900nm时取向为〈020〉 :根据离子对相互作用能和谐振子模型,得到了红外吸收与Mn—O—Mn键长和键角关系式,6 00cm-1附近红外吸收与晶格常数b的变化有关;块体与薄膜的金属—绝缘体转变 温度(TMI)存在较大差别,薄膜转变温度显著低于块体,并与厚度有一定关系. 认为是LSMO薄膜中的应力诱导了晶格常数变化,引起键角改变及JT效应是转变温度变化的主 要原因.
关键词:
单晶硅
晶格常数
金属—绝缘体转变温度
应力诱导 相似文献
105.
JUGuo-Xing ZhaoXian-Lin 《理论物理通讯》2002,37(4):397-404
The solution transformations and properties of the R-matrices for two-component systems under these transformations are analyzed in details.Not all transformed R-matrices can be put into the Skalyanin‘s formalism.For those R-matrices with all required properties,the effects of solution transformations to the six-and eight-vertex systems with open boundary conditions are discussed.these effects can be one of the following types:the Hamiltonian is invariant or transposition-invariant or made in a similarity transformation,or its coupling coefficients are multiplied by an overall factor,or the spin of the system is rotated around the z axis or/and reflected with respect to some plane.In these cases,the transformed systems remain to be integrable. 相似文献
106.
R. Cristescu G. Dorcioman E. Axente A. Moldovan T. Kocourek M. Albulescu D. Mihaiescu D.B. Chrisey 《Applied Surface Science》2006,252(13):4647-4651
We report the first successful deposition of triacetate-pullulan polysaccharide thin films by matrix assisted pulsed laser evaporation. We used a KrF* excimer laser source (λ = 248 nm, τ ≈ 20 ns) operated at a repetition rate of 10 Hz. We demonstrated by FTIR that our thin films are composed of triacetate-pullulan maintaining its chemical structure and functionality. The dependence on incident laser fluence of the induced surface morphology is analysed. 相似文献
107.
Consider a sequenceF
1,F
2,... of i.i.d. random transformations from a countable setV toV. Such a sequence describes a discrete-time stochastic flow onV, in which the position at timen of a particle that started at sitex isM
n(x), whereM
n
=F
n
F
n–1
F
1. We give conditions on the law ofF
1 for the sequence (M
n) to be tight, and describe the possible limiting law. an example called the block charge model is introduced. The results can be formulated as a statement about the convergence in distribution of products of infinite-dimensional random stochastic matrices. In practical terms, they describe the possible equilibria for random motions of systems of particles on a countable set, without births or deaths, where each site may be occupied by any number of particles, and all particles at a particular site move together. 相似文献
108.
A. Pellegrinotti 《Journal of statistical physics》1988,53(5-6):1327-1336
A transformation on the two-dimensional torus which is related to the problem of limit distribution for the distance between the levels in the kicked-rotator model is considered. The first four moments of the r.w. which describe the numbers of visits of a point in a rectangle of measure are calculated. It is shown that when 0 they converge to the first four moments of a Poisson r.w. 相似文献
109.
The kinetics of carbon deposition over a Ni/α-Al2O3 commercial catalyst, has been studied using CH4−H2 gas mixtures in the range of 748–873 K. A Hougen-Watson type model gives good agreement with the experimental rates. 相似文献
110.
晶化温度对中孔分子筛(M41S)结构转变的影响 总被引:11,自引:6,他引:11
在低表面活性剂浓度及低表面活性剂与氧化硅比的条件下,研究了十六烷基三甲基溴化铵-硅酸钠体系中晶化温度对中孔分子筛M41S材料结构转变的影响。结果有,晶化温度提高至135℃改变了原六方晶相MCM-41的结构,晶化温度提高到150℃后,中孔结构六方MCM-41晶格转变为变不稳定的层状相, 相似文献