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41.
François Loiseau Jean-Mary Simone David Carcache Pavel Bobal Reinhard Neier 《Monatshefte für Chemie / Chemical Monthly》2007,138(2):121-129
Summary. Free radical couplings from furan, as cheap starting material, were studied in view of developing a rapid strategy en route to the synthesis of derivatives of nonactin. The chain containing the alcohol function was introduced in one or two steps
in 86% yield. For the introduction of the second chain with the ester function two different coupling methods were tested.
Starting from the advanced intermediates obtained nonactin derivatives can be prepared by catalytic hydrogenation of the furan
ring. 相似文献
42.
The lantadenes fraction from Lantana camara was isolated and transformed to the medicinally important intermediate 22β-hydroxyoleanonic
acid. The compound was studied for hepatotoxicity using lantadene A as standard and found to be nontoxic.
Published in Khimiya Prirodnykh Soedinenii, No. 4, pp. 357–358, July–August, 2006. 相似文献
43.
We review the unusual structural, transport and magnetic properties of highly conducting polyaniline, doped with boron trifluoride.
Our studies establish the unique conducting state of this system, which is in distinct contrast with the conventional proton-doped
polyaniline samples. 相似文献
44.
低温太阳热能与化学链燃烧相结合控制CO2分离动力系统 总被引:3,自引:1,他引:2
本文探索并提出控制CO2分离的低温太阳热能与清洁合成燃料甲醇-三氧化二铁化学链燃烧相结合的新颖能源动力系统。基于图象(?)分析方法,明确地指出甲醇化学链燃烧能量释放过程燃烧堋损失减小和低温太阳热能品位提升的机理。从能源有效利用和环境相容出发,研究和揭示化学链燃烧与太阳能有机整合共同减小CO2分离能耗的特性规律。相比不分离常规联合循环,新系统(?)效率提高约6.2个百分点;与分离CO2的联合循环相比,新系统媚效率提高约14.2个百分点。同时,低温太阳热能热转功效率可达到22.5%。 相似文献
45.
A new probabilistic cellular automaton model is introduced to simulate cluster and interface growth in two dimensions. The dynamics of this model is an extension to higher dimensions of the compact directed percolation studied by Essam. Numerical results indicate that the two-dimensional cluster coarsening and growth can be described only approximately by the conventional cluster size scaling due to a crossover in the growth mode. The spreading of the initially flat interface follows a purely diffusional,t
1/2, law. 相似文献
46.
Marina DellaGreca 《Tetrahedron》2006,62(12):2877-2882
Examination of the hydroalcoholic extract of the leaves of Aptenia cordifolia has afforded three cinnamic acid amides and two lignanamides. Structures were established on the basis of spectroscopic data, including 2D-NMR analyses. 相似文献
47.
This paper presents detailed information on the experience gained during the attempts to model a set of transitional flows
due to boundary layer separation. These flows are developed on a flat plate with a semi-circular leading edge and they have
been coded by the ERCOFTAC Special Interest Group on Transition, as T3L flows. Different freestream velocities and turbulence
intensities configure these transitional flows and, by consequence, govern the transition mechanism, resulting in larger or
smaller transitional regions. The modeling of the T3L flows has been performed by adopting a low-Reynolds number second-moment
closure turbulence model. The results showed satisfactory agreement with the experimental measurements, although some difficulties
regarding successful convergence have been faced. The final conclusion is that turbulence modeling can present quite accurate
results for transitional flows without any additional use of ad-hoc modifications or additional equations based on various
transition models and intermittency transport modeling. 相似文献
48.
The toxicity of inorganic trivalent arsenic for living organisms is reduced by in vivo methylation of the element. In man, this biotransformation leads to the synthesis of monomethylarsonic (MMA) and dimethylarsinic (DMA) acids, which are efficiently eliminated in urine along with the unchanged form (Asi). In order to document the methylation process in humans, the kinetics of Asi, MMA and DMA elimination were studied in volunteers given a single dose of one of these three arsenicals or repeated doses of Asi. The arsenic methylation efficiency was also assessed in subjects acutely intoxicated with arsenic trioxide (As2O3) and in patients with liver diseases. Several observations in humans can be explained by the properties of the enzymic systems involved in the methylation process which we have characterized in vitro and in vivo in rats as follows: (1) production of Asi metabolites is catalyzed by an enzymic system whose activity is highest in liver cytosol; (2) different enzymic activities, using the same methyl group donor (S-adenosylmethionine), lead to the production of mono- and di-methylated derivatives which are excreted in urine as MMA and DMA; (3) dimethylating activity is highly sensitive to inhibition by excess of inorganic arsenic; (4) reduced glutathione concentration in liver moderates the arsenic methylation process through several mechanisms, e.g. stimulation of the first methylation reaction leading to MMA, facilitation of Asi uptake by hepatocytes, stimulation of the biliary excretion of the element, reduction of pentavalent forms before methylation, and protection of a reducing environment in the cells necessary to maintain the activity of the enzymic systems. 相似文献
49.
V. I. Saloutin I. T. Bazyl' Z. E. Skryabina P. N. Kondrat'ev O. N. Chupakhin 《Russian Chemical Bulletin》1994,43(2):279-282
Reactions of pentafluorobenzoylpyruvic acid with amines afford the respective enamines. The intramolecular cyclization of the latter results inN-substituted 4-quinolone-2-carboxylic acids. Ammonia and triethylamine favor the cyclization of pentafluorobenzoylpyruvic acid to 2-carboxychromone.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 299–302, February, 1994. 相似文献
50.
Electrolysis of dimethyl malonate or methyl cyanoacetate in methanol in the presence of LiCl in an undivided cell leads to formation of 1,1,2,2-cyclopropanetetracarboxylic derivatives.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1835–1836, October, 1994.This work was supported by the International Science Foundation (Grant No MHY 000). 相似文献