A Survey of Complementary Methods for the Characterization of Dense Colloidal Silica

The aim of this study is to enhance existing knowledge of different techniques developed for the characterization of stability and particle sizing of nanoparticles in dense dispersions subjected to interparticulate and hydrodynamic forces. Silica suspension, commercially known as Klebosol^® 30R50 and consisting of a particle size of 80 nm on average, was investigated in the study over a wide range of concentrations. The investigations were carried out using different optical and acoustic techniques such as laser diffraction, multiple light scattering, photon correlation spectroscopy and acoustic spectroscopy. The study details the capabilities and limitations of these modern techniques based on the different physical principles behind the characterization of the size distribution of particles in suspensions. The results are presented in terms of particle size ranges, solid concentration and technological aspects such as online and offline analysis. An important finding is that many of these modern techniques need to be improved for applications at higher concentrations since the standard models become practically invalid because of the complex interaction of acoustic and optical waves with particles in suspensions of silica.     

多级全通均衡器对介质薄膜滤波器进行色散补偿的探讨

讨论了介质薄膜滤波器的色散特点,并推导了单级全通滤波器的理论色散。比较理论色散曲线与实际测量色散曲线,两者吻合较好。但由于单级全通滤波器的色散带宽及斜率不能满足实际所需的色散补偿曲线,因此提出了多级全通滤波器,通过控制级连的单级全通滤波器的谐振波长及反射率,可以增大色散带宽,改善色散斜率,使之满足实用的要求。文中给出了四级全通滤波器的理论色散曲线。     

骨架密实型低噪声路面降噪机理的实验研究

配制了传统的沥青混凝土(AC)、碎石沥青玛蹄脂(SMA)、不同橡胶粉掺量的骨架密实型低噪声路面等3类共5个配比的沥青路面,采用驻波法测量了各类沥青路面的吸声系数。并且分析了橡胶粉掺量对密实型低噪声路面动态模量的影响,得出了结论,即在这些路面中,橡胶粉含量为3%的密实型路面的减振降噪效果最好。     

稠密颗粒射流倾斜撞击颗粒膜特征

采用高速摄像仪对稠密颗粒射流倾斜撞击形成的类液体颗粒膜特征进行实验研究,考察了颗粒粒径、射流速度以及射流含固率等因素对颗粒膜形态及动态特征的影响.结果表明:随着颗粒粒径增大,稠密颗粒倾斜撞击流由颗粒膜向散射模式转变;随着射流速度增加,气固不稳定增强,射流流量出现脉动,正面与侧面分别表现为颗粒膜的非轴对称振荡和表面波纹结构;颗粒膜非轴对称振荡的振荡频率和振荡幅度随射流速度的增大而增大;表面波纹速度和波长沿传播方向增大,波纹间存在叠加现象.颗粒膜出现非轴对称振荡主要是因为喷嘴出口由气固不稳定性引起的射流流量脉动,射流流量脉动频率与撞击面振荡频率基本相当.     

Design of bicontinuous polymeric microemulsions

Recent experiments suggest that thermodynamically stable, bicontinuous microemulsions can be achieved in symmetric ternary blends of two homopolymers and a diblock copolymer by formulating alloys with compositions near mean-field isotropic Lifshitz points. We argue that practical application of this design criterion may require use of homopolymers of unequal molecular weights and block copolymers of different architecture. We demonstrate the existence of, and explicitly locate, mean-field isotropic Lifshitz points in ternary blends with homopolymer molecular weight asymmetry and either AB diblock or ABA triblock copolymer architectures. These calculations considerably expand the parameter space for observing bicontinuous microemulsions and allow for more flexibility in tailoring melt rheological properties and solid-state mechanical properties. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 2775–2786, 1997     

稠密共振介质中近偶极-偶极相互作用的局域场效应

 为研究存在由近偶极-偶极相互作用诱导的局域场效应时超短强激光脉冲与稠密共振介质相互作用的特性,采用光与物质相互作用的半经典理论,建立了稠密二能级体系中考虑原子间近偶极-偶极相互作用的修正光学Bloch方程,并用四阶Runge-Kutta法数值求解了该方程。研究结果表明:局域场效应对稠密二能级体系中Bloch矢量的瞬态相干过程和稳态性质都具有强烈的调制作用。并由此提出了调控稳态粒子数布居的两种方案。     

量子通信研究进展与应用

量子通信利用量子信道进行信息的编码、传输和处理,具有安全性高和信道容量高等特点。量子保密通信以信息安全为主要目的,包括量子密钥分发、量子安全直接通信和量子秘密共享等模式。利用量子纠缠,量子隐形传态根据事先已经分发的纠缠粒子对实现不传输实物粒子而传输未知粒子的状态,量子密集编码通过传输一个粒子而实现两个粒子信息的传输,这些是经典通信无法实现的任务。文章简单介绍量子通信的内容和进展情况。     

Equation of state of hydrogen,helium, and solar plasmas

The equation of state (EOS) for plasmas of the two lightest elements H and He, and mixtures as typical for the plasmas in the sun are calculated. The contributions of deep bound states are included by using inverted fugacity expansions. The inversion of fugacities to densities is reduced to solvable algebraic problems and expressed by rational polynomials. The calculation of relative pressures is carried out separately for low and high densities. Near the crossing point, in between, the separate solutions are connected to each other by smooth concatenation. Applications to hydrogen–helium plasmas in the sun including estimates for the isentropic EOS are discussed.