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951.
《Electroanalysis》2003,15(3):225-229
The interaction between avidin and biotin was evaluated electrochemically by monitoring the change in the electrode response of redox markers. Biotin was immobilized on the electrode surface by means of the electrochemical polymerization of biotinylated pyrrole and pyrrole. When avidin was introduced onto the biotinylated polypyrrole electrode surface, the large change in the electrode response of the redox marker was detected. The fact that the change in the electrode response of a marker ion could be attributed to the electrostatic interaction between avidin on the electrode surface and the redox marker ion present in a solution was verified by replacing avidin with NutrAvidin. At a pH lower than the isoelectric point of avidin, the electrode response of ferrocyanide as an anionic marker ion increased linearly within the range of 5.0×10?9 ?3.0×10?8 M avidin. The relative standard deviation at 1.5×10?8 M avidin was about 5.4% (n=5). The detection of biotin was also performed using a competitive reaction between biotin in solution and biotin that had been immobilized on the electrode surface in the form of the biotinylated polypyrrole. 相似文献
952.
Guey‐Sheng Liou Sheng‐Huei Hsiao 《Journal of polymer science. Part A, Polymer chemistry》2002,40(15):2564-2574
A new N‐phenylated amide (N‐phenylamide) unit containing aromatic diamine, N,N′‐bis(3‐aminobenzoyl)‐N,N′‐diphenyl‐1,4‐phenylenediamine, was prepared by the condensation of N,N′‐diphenyl‐1,4‐phenylenediamine with 3‐nitrobenzoyl chloride, followed by catalytic reduction. Two series of organosoluble aromatic poly(N‐phenylamide‐imide)s and poly(N‐phenylamide‐amide)s with inherent viscosities of 0.58–0.82 and 0.56–1.21 dL/g were prepared by a conventional two‐stage method and the direct phosphorylation polycondensation, respectively, from the diamine with various aromatic dianhydrides and aromatic dicarboxylic acids. All polyimides and polyamides are amorphous and readily soluble in many organic solvents such as N,N‐dimethylacetamide and N‐methyl‐2‐pyrrolidone. These polymers could be solution cast into transparent, tough, and flexible films with high tensile strengths. These polyimides and polyamides had glass‐transition temperatures in the ranges of 230–258 and 196–229 °C, respectively. Decomposition temperatures of the polyimides for 10% weight loss all occurred above 500 °C in both nitrogen and air atmospheres. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 2564–2574, 2002 相似文献
953.
Yoichiro Iwase Koichi Kondo Kenji Kamada Koji Ohta 《Journal of polymer science. Part A, Polymer chemistry》2002,40(20):3534-3541
1,4‐Bis(4‐benzylpyridinium)butadiyne triflate was aggregated in dimethylformamide and spontaneously converted into the 1,4‐addition type of polydiacetylene. The polymerization took place in a dipolar aprotic solvent with a large dielectric constant that could enhance the aggregation of the ionic diacetylene salt through the electrostatic interaction. The molecular weight of the diacetylene was leveled off after 30 h at 80 °C to reach 1.5 × 104 (number‐average molecular weight) that consisted of the 1,4‐addition type of polydiacetylene similar to polydiacetylenes obtained in the conventional solid‐state polymerization. Electron spin resonance spectra revealed that diradicals were generated at the earlier state aggregation to give rise to a solution polymerization. The UV spectra also suggested the presence of the activated aggregation associated with the polymerization as well as the eximer emission spectra. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 3534–3541, 2002 相似文献
954.
Synthesis and characterization of block copolymers from 2‐vinylnaphthalene by anionic polymerization
Faquan Zeng Mu Yang Jianxin Zhang Sunil K. Varshney 《Journal of polymer science. Part A, Polymer chemistry》2002,40(24):4387-4397
The anionic polymerization of 2‐vinylnaphthalene (2VN) has been studied in tetrahydrofuran (THF) at ?78 °C and in toluene at 40 °C. 2VN polymerization in THF, toluene, or toluene/THF (99:1 v/v) initiated by sec‐butyllithium (sBuLi) indicates living characteristics, affording polymers with predefined molecular weights and narrow molecular weight distributions. Block copolymers of 2VN with methyl methacrylate (MMA) and tert‐butyl acrylate (tBA) have been synthesized successfully by sequential monomer addition in THF at ?78 °C initiated by an adduct of sBuLi–LiCl. The crossover propagation from poly(2‐vinylnaphthyllithium) (P2VN) macroanions to MMA and tBA appears to be living, the molecular weight and composition can be predicted, and the molecular weight distribution of the resulting block copolymer is narrow (weight‐average molecular/number‐average molecular weight < 1.3). Block copolymers with different chain lengths for the P2VN segment can easily be prepared by variations in the monomer ratios. The block copolymerization of 2VN with hexamethylcyclotrisiloxane also results in a block copolymer of P2VN and poly(dimethylsiloxane) (PDMS) contaminated with a significant amount of homo‐PDMS. Poly(2VN‐b‐nBA) (where nBA is n‐butyl acrylate) has also been prepared by the transesterification reaction of the poly(2VN‐b‐tBA) block copolymer. Size exclusion chromatography, Fourier transform infrared, and 1H NMR measurements indicate that the resulting polymers have the required architecture. The corresponding amphiphilic block copolymer of poly(2VN‐b‐AA) (where AA is acrylic acid) has been synthesized by acidic hydrolysis of the ester group of tert‐butyl from the poly(2VN‐b‐tBA) copolymer. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4387–4397, 2002 相似文献
955.
《Electroanalysis》2006,18(1):70-76
A lead‐copper film electrode was proposed for Co(II) determination by catalytic adsorptive stripping voltammetry. The electrode was plated in situ and hence the exchange of a solution after plating step was not required. At optimized conditions the calibration graph for Co(II) was linear from 5×10?10 to 2×10?8 mol L?1 for accumulation time of 15 s. The relative standard deviation for Co(II) determination at concentration 5×10?9 mol L?1 was 4.1%. The detection limits for Co(II) were 1.2×10?10 and 1.0×10?11 mol L?1 for an accumulation time of 15 and 180 s, respectively. The method was applied to Co(II) determination in certified reference material and other water samples. 相似文献
956.
Bao‐Shiang Lee Sangeeth Krishnanchettiar Syed Salman Lateef Nabila Salman Lateef Shalini Gupta 《中国化学会会志》2006,53(3):745-750
Avidin functional affinity electrophoresis (AFAEP) is substituted for an avidin affinity column (AAC) to capture biotinylated peptides in the Isotope‐Coded Affinity Tagging (ICAT) technique which is a valuable tool in quantitative proteomics. In this new technique, the AFAEP‐captured ICAT‐labeled biotinylated peptides are extracted with the biotin tag intact from the polyacrylamide gel piece with aqueous 95% formamide (pH 8.2) at 65 °C for 20 min, and then detected by a matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometer. Bovine serum albumin (BSA) and the 12C‐ and 13C‐ICAT reagents are used to test this AFAEP‐ICAT technique. The results show that both AFAEP and AAC methods provide quantitative information of the relative amounts of 12C‐ and 13C‐ICAT‐labeled biotinylated tryptic peptides of BSA in a sample. Compared with AAC, the AFAEP is cheaper to perform, more stringent in capturing the biotinylated peptides, and capable of simultaneously processing multiple samples. 相似文献
957.
A new blue emitting 2‐allyl‐6‐(2‐dimethylaminoethyloxy)‐benzo[de]isoquinoline‐1,3‐dione, bearing an allylic group has been designed and synthesized. Bulk radical copolymerization has been carried out in order to prepare a fluorescent copolymer, based on styrene. The main photophysical characteristics of the monomeric and polymeric fluorophores have been investigated both in the absence and presence of metal cations and protons. It has been found that the monomeric naphthalimide can be used as a sensor for protons and Zn2+, Ni2+, Ce3+, Cu2+, Co2+, Ag+ cations. The polymeric fluorophore has been shown to be a selective chemosensor for Cu2+ cations. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
958.
Turbiez M Frère P Allain M Videlot C Ackermann J Roncali J 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(12):3742-3752
Hybrid oligothiophenes based on a various combinations of thiophene and 3,4-ethylenedioxythiophene (EDOT) groups have been synthesized. UV/Vis absorption spectra show that the number and relative positions of the EDOT groups considerably affect the width of the HOMO-LUMO gap and the rigidity of the conjugated system. Analysis of the crystallographic structure of two hybrid quaterthiophenes confirms that insertion of two adjacent EDOT units in the middle of the molecule leads to a self-rigidification of the conjugated systems by intramolecular SO interactions. Cyclic voltammetry data shows that the first oxidation potential of the oligomers decreases with increasing chain length and increasing number of EDOT groups for a given chain length. Electrochemical studies and theoretical calculations show that the positions of the EDOT units in the conjugated chain control the potential difference (DeltaE(p)) between the first and second oxidation steps. Moving the EDOT groups from the outer to the inner positions of the conjugated system increases DeltaE(p). Theoretical calculations confirm that this phenomenon reflects an increase of the intramolecular coulombic repulsion between positive charges in the dication. A thin-film field-effect transistor was fabricated by vacuum sublimation of a pentamer with alternating thiophene-EDOT structure, and the hole mobility was determined. 相似文献
959.
Xiao‐Yan Chen Peng Cheng Shi‐Ping Yan Dai‐Zheng Liao Zong‐Hui Jiang 《无机化学与普通化学杂志》2005,631(15):3104-3107
A novel two‐dimensional cobalt complex, [Co(btrm)2(dca)]ClO4 ( 1 , btrm = 1,2‐bis(1,2,4‐triazole‐1‐yl)methane, dca = dicyanamide), was synthesized and characterized. X‐ray diffraction analyses reveal that the title complex crystallizes in the monoclinic space group C2/m with a = 29.507(13)Å, b = 17.804(8) Å, c = 14.709(7) Å, β = 119.916(7)°, Z = 12, and R1 = 0.0784, wR2 = 0.2041. The cobalt atom involves a six‐coordinated CoN6 environment, with a distorted octahedral coordination. Two btrm ligands connect the CoII atoms with the exodentate nitrogen atoms on the 4‐position of triazole rings to form a sixteen‐membered rhombic grid. The unprecedented double btrm bridges and μ1,5‐dca bridge connect the cobalt atoms to form a two‐dimensional grid‐like layered structure. The spectroscopic and magnetic properties have also been investigated. 相似文献
960.
《Chemphyschem》2004,5(2):202-208
We have designed and synthesized a series of Schiff base derivatives, and studied their structural features in two‐dimensional (2D) and three‐dimensional (3D) states by combining scanning tunneling microscopy (STM) and X‐ray diffraction experiments. The Schiff‐base derivatives with short alkyl chains crystallize easily, which allows a detailed structural analysis by X‐ray diffraction. Due to the strong adsorbate–substrate interactions, those bases with long alkyl chains easily form 2D assemblies on highly oriented pyrolytic graphite (HOPG). The STM images indicate also that the introduction of two methoxy groups into the molecule can change the structure of these 2D assemblies as a result of the increased steric hindrances, for example: the Schiff‐base derivative, bearing both methoxy groups and C16H33 tails, forms 2D Moiré patterns, and an alignment of pairing Schiff‐base molecules may be easily resolved. Conversely, the Schiff base derivative, bearing solely C16H33 tails, forms 2D non‐Moiré patterns. It is demonstrated that the 3D structural features result from the compromise of intermolecular interactions of different molecular moieties. However, there is one more factor, which also governs the 2D structure: the adsorbate‐substrate interaction. The 3D crystal structure may thus help to understand many factors involved in the formation of 2D structures, and would be helpful for designing new molecular assemblies with tailoring functions. 相似文献