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11.
AO Sheng-Mei YAN Jia-Ren 《理论物理通讯》2007,47(1):15-18
Three types of expression in the dark-soliton perturbation theory based on squared Jost solutions are invesgigaged in ghis paper. It is shown that there are three formally different results about the effects of perturbagion on a dark soliton, and it is proved by means of a transformation between two integral variables that they are essentially equivalent. 相似文献
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We consider a composite material composed of fibres included in a resin which becomes solid when it is heated up (reaction of reticulation). The mathematical modelling of the cure process is given by a kinetic equation describing the evolution of the reaction of reticulation coupled with the heat equation. In this paper, we are interested in the computation of approximate solutions. We propose a family of discretized problems depending on two parameters (β1, β2) ε [0, 1]2 which split the linear and non‐ linear terms in implicit and explicit parts. We prove the stability and convergence of the discretization for any (β1, β2) ε [½, 1 ] × [0, 1]. We present also some numerical results. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
15.
讨论了带有背景矢量场的动力学标量场作为暗能量在闭宇宙的情形下的演化. 选取适当的标量场势函数后, 在得到的暗能量有效状态方程中, 参数w在红移z≈0.2处可以越过-1, 而且在z≈1.7处宇宙从减速膨胀的状态转变为加速膨胀状态, 这与最近的宇宙学观测相符. 相似文献
16.
F. Román S. Montserrat J. M. Hutchinson 《Journal of Thermal Analysis and Calorimetry》2007,87(1):113-118
The procedure for
the fabrication of epoxy-based polymer layered silicate nanocomposites is
important in respect of the nanostructure that is developed. To further our
understanding of this, the influence of an organically modified clay (montmorillonite,
MMT) on the curing kinetics of an epoxy resin has been studied by differential
scanning calorimetry. Clay loadings of 10 and 20 mass% are used, and isothermal
as well as dynamic cures have been investigated. For both cure schedules the
effect of the MMT is to advance the reaction. Kinetic analysis yields values
for the activation energy, but shows that the reaction cannot be described
simply by the usual autocatalytic equation. The glass transition of the cured
nanocomposites is lower than that for the cured neat resin, a result that
is attributed to homopolymerisation taking place in addition to the epoxy–amine
reaction. 相似文献
17.
C.?Korah Bina K.?G.?Kannan K.?N.?NinanEmail author 《Journal of Thermal Analysis and Calorimetry》2004,78(3):753-760
The urethane forming cure reactions of hydroxyl terminated polybutadiene (HTPB) binder with three different isocyanate curatives, viz., toluene diisocyanate (TDI), isophorone diisocyanate (IPDI) and 4,4-methylene bis(cyclohexyl isocyanate) (MCHI), were investigated by differential scanning calorimetry (DSC). The effect of two cure catalysts, viz., dibutyl tin dilaurate (DBTDL) and ferrric tris-acetylacetonate (FeAA) on the cure reactions was also studied. Cure kinetics was evaluated using the multiple heating rate Ozawa method. The reactivities of the three isocyanates and catalytic efficiencies were compared based on the DSC reaction temperatures, activation energies and rate constants. Viscosity build-up in these systems at isothermal temperature was also studied and compared with the results from DSC. 相似文献
18.
Mu-Shih Lin Kuen-Tay Jeng 《Journal of polymer science. Part A, Polymer chemistry》1992,30(9):1941-1951
Poly(ethylene glycol) diacrylate was synthesized from poly(ethylene glycol) of molecular weight 600 with acryloyl chloride in a molar ratio of 1:2. Poly(ethylene glycol) diacrylate (PEGDA) was then blended with diglycidyl ether of bisphenol A (DGEBA) in various ratios, followed by curing with 2,2′-azobisisobutyronitrile (AIBN) and isophronediamine (IPDA) simultaneously. Viscosity changes before and during IPN formation were examined with a Brookfield viscometer. Formation of H-bonding and functional group changes were investigated with FTIR. Exothermic curing thermograms were recorded with dynamic DSC. Optically clear IPNs thus obtained were characterized with rheometric dynamic spectroscopy (RDS) and scanning electron microscopy (SEM) to check possible compatibility of the two networks. Experimental results revealed that during IPN formation hydrogen bonds between PEGDA and DGEBA and interlock of networks had profound effect on viscosity change and pot-life. Complete compatibility of the IPNs was found as DGEBA content was higher than 50% by weight. The compatibility between PEGDA and DGEBA networks was evidenced from inner shift of a single damping peak in RDS. In the meantime, SEM micrographs confirmed the coincidence with the result of RDS © 1992 John Wiley &Sons, Inc. 相似文献
19.
Marta Sánchez-Cabezudo Margarita G. Prolongo Catalina Salom Rosa M. Masegosa 《Journal of Thermal Analysis and Calorimetry》2006,86(3):699-705
The cure kinetics
and morphology of diglycidyl ether of bisphenol A (DGEBA) modified with polyvinyl
acetate (PVAc) using diaminodiphenylmethane (DDM) as hardener were investigated
through differential scanning calorimetry (DSC) and environmental scanning
electron microscopy (ESEM). Isothermal curing measurements were carried out
at 150, 120 and 80°C. The kinetic parameters were obtained using the general
autocatalytic chemically controlled model. The comparison of the kinetic data
indicates that the presence of PVAc does not change the autocatalytic nature
of the cure reaction. Two T
g’s
were observed in the fully cured samples of the modified systems. ESEM micrographies
confirm the biphasic morphology. 相似文献
20.
WANG Gui-Xiu ZHU Rong-Xiu ZHANG Dong-Ju② LIU Cheng-Bu 《结构化学》2006,25(11):1402-1408
1 INTRODUCTION Ethers are a kind of organic compounds that are easily oxidized under the conditions of lacking light and any additional excitement. According to dif- ferent mechanisms, the oxidation reactions could be classified into two types: photooxidation reaction and dark oxidation reaction. The former is the reaction with excited state oxygen molecule (singlet state), while the latter is the reaction with ground state oxygen molecule (triple state) without illuminance or any exciter… 相似文献