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21.
The complex [Ru(II)(dcbpyH2)(bdmpp)NCS](PF6) (1) (where dcbpyH2 is 2,2′-bipyridine-4,4′-dicarboxylic acid, bdmpp is 2,6-bis(3,5-dimethyl-N-pyrazoyl)pyridine,) is synthesized and characterized extensively by 1H NMR and 13C NMR 1D and 2D, mass spectroscopy, cyclic voltammetry, electronic absorption spectroscopy and IR. The half-wave potential of the Ru(II)/Ru(III) redox couple was measured at E1/2=+0.795 V versus Ag/AgCl in CH3CN. The complex presents three intense metal-to-ligand charge transfer (MLCT) (dM→πL*) absorption bands centered at 383 (=21 300 M−1 cm−1), 432 (=22 400 M−1 cm−1) and 475 nm (=23 400 M−1 cm−1), respectively. The absorbance is extremely strong between 400 and 500 nm and even at 620 nm, the extinction coefficient is still high (=3768 M−1 cm−1). The strong π-acceptor property of the trans-isothiocyanate ligand compared with the Cl− ligand is probably the cause of the blue-shift observed in complex 1. These properties make the complex potentially promising for the photosensitization process. The incorporation of TiO2 photoelectrodes derivatized with this complex into a solar cell using a composite polymer/inorganic oxide solid-state electrolyte confirmed its sensitizing ability. Incident monochromatic photon-to-current conversion efficiency (IPCE) values of about 30% and overall energy conversion efficiency (η) of 1.7% were obtained. 相似文献
22.
Peter Bakó László Fenichel László Tôke 《Journal of inclusion phenomena and macrocyclic chemistry》1993,16(1):17-23
The complexing (in CHCl3) and extracting abilities of 18-crown-6 type compounds (1–15) were measured with Li, Na, K and NH4 cations. The substituents on the sugar part affected these properties significantly (K
a=103–107). Some substituents, like acetyloxy groups (3) decreased whereas others, like tosyloxy groups (10, 11) significantly increased the complexing ability and thus changed the selectivity. The compound with four tosyloxy groups (11) shows an excellent picrate salt extracting ability in a CH2Cl2-water system. 相似文献
23.
Norio Yoshino Munetoshi Morita Atsushi Ito Masahiko Abe 《Journal of fluorine chemistry》1995,70(2):187-191
Anionic surfactants having two polyfluoroalkyl chains per molecule, i.e. the sodium salt of bis(1H, 1H, 2H,2H-heptadeca-fluorodecyl)-2-sulfosuccinate, CF3(CF2)7(CH2)2OCOCH2CH(SO3Na)COO(CH2)2(CF2)7CF3, the sodium salt of bis(1H, 1H, 2H, 2H-tridecafluoro-octyl)-2-sulfosuccinate, CF3(CF2)5(CH2)2OCOCH2CH(SO3Na)COO(CH2)2(CF2)5CF3, and the sodium salt of bis(1H, 1H, 2H, 2H-nonafluorohexyl)-2-sulfosuccinate, CF3(CF2)3(CH2)2OCOCH2CH(SO3Na)COO(CH2)2(CF2)3CF3, have been prepared from maleic anhydride, the corresponding alcohols possessing a polyfluoroalkyl chain and sodium hydrogen sulfite. The flocculation and redispersion abilities of these surfactants for dispersed magnetic particles in water have been examined to investigate the effect of the chain length. It was found that this ability was enhanced by an increase in the chain length. The contact angles for water for pelleted surface-modified magnetite have been measured. In order to compare this ability and the contact angles, data for other fluorinated surfactant have been obtained. The Kraff point, the surface tension and the pNa of the aqueous surfactant solutions have also been measured. 相似文献
24.
25.
Dr. Ngoc-Anh Tran Nhan Do Van Thanh Prof. My Loan Phung Le 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(36):9198-9217
Magnesium batteries, like lithium-ion batteries, with higher abundance and similar efficiency, have drawn great interest for large-scale applications such as electric vehicles, grid energy storage and many more. On the other hand, the use of organic electrode materials allows high energy-performance, metal-free, environmentally friendly, versatile, lightweight, and economically efficient magnesium storage devices. In particular, the structural diversity and the simple activity of organic molecules make redox properties, and hence battery efficiency, easy to monitor. While organic magnesium batteries still in their infancy, this field becomes more and more promising because significant results were reported. To summarize the achievements in studies on organic cathodes for magnesium systems, their synthesis is discussed, combined with electrode design to provide the basis for controlling the electrochemical properties. Moreover, the techniques to synthesize organic materials with high-yield are mentioned. Finally, potential problems and prospects are explored to further improve organic cathodes. 相似文献
26.
Low-field nuclear magnetic resonance techniques are employed to extract information about the effects introduced by the interaction with the surface on the rotational and translational dynamics of molecules confined inside a mesoporous carbon xerogel. The molecules under study were water, cyclohexane, and hexane. They were chosen due to their different interaction strength with the carbonaceous matrix. Frequency dependent longitudinal relaxation measurements, using the fast field cycling technique, allowed extraction of the fractal dimension of the carbon xerogel surface. It was observed that the measured value is influenced by the molecule affinity to the surface. Diffusion measurements, using the pulse field gradient technique, have revealed that the stronger interaction with the surface of cyclohexane and hexane molecules leads to an increased diffusive tortuosity, as compared with water. 相似文献
27.
基于应用型本科院校创新型人才的培养目标,对本科生开展科研训练,将科研训练纳入教学过程,从课程体系、教学环节、教学手段、考核评价等方面进行了探索,构建了以科研训练为主线的研究型教学模式。 相似文献
28.
Role of compositional changes on thermal,magnetic,and mechanical properties of Fe-P-C-based amorphous alloys
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Indah Raya Supat Chupradit Mustafa M Kadhim Mustafa Z Mahmoud Abduladheem Turki Jalil Aravindhan Surendar Sukaina Tuama Ghafel Yasser Fakri Mustafa Alexander N Bochvar 《中国物理 B》2022,31(1):16401-016401
This work aimed to tune the comprehensive properties of Fe-P-C-based amorphous system through investigating the role of microalloying process on the crystallization behavior,glass forming ability(GFA),soft magnetic features,and mechanical properties.Considering minor addition of elements into the system,it was found that the simultaneous microalloying of Ni and Co leads to the highest GFA,which was due to the optimization of compositional heterogeneity and creation of near-eutectic composition.Moreover,the FeCoNiCuPC amorphous alloy exhibited the best anelastic/viscoplastic behavior under the nanoindentation test,which was owing to the intensified structural fluctuations in the system.However,the improved plasticity by the extra Cu addition comes at the expense of magnetic properties,so that the saturation magnetization of this alloying system is significantly decreased compared to the FeCoPC amorphous alloy with the highest soft magnetic properties.In total,the results indicated that a combination of added elemental constitutes,i.e.,Fe69Co5Ni5Cu1P13C7 composition,provides an optimized state for the comprehensive properties in the alloying system. 相似文献
29.
Prof. Santiago Alvarez 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(19):4350-4377
After briefly reviewing the applications of the coordination ability indices proposed earlier for anions and solvents toward transition metals and lanthanides, a new analysis of crystal structures is applied now to a much larger number of coordinating species: anions (including those that are present in ionic solvents), solvents, amino acids, gases, and a sample of neutral ligands. The coordinating ability towards s-block elements is now also considered. The effect of several factors on the coordinating ability will be discussed: (a) the charge of an anion, (b) the chelating nature of anions and solvents, (c) the degree of protonation of oxo-anions, carboxylates and amino carboxylates, and (d) the substitution of hydrogen atoms by methyl groups in NH3, ethylenediamine, benzene, ethylene, pyridine and aldehydes. Hit parades of solvents and anions most commonly used in the areas of transition metal, s-block and lanthanide chemistry are deduced from the statistics of their presence in crystal structures. 相似文献
30.
应用简单的高温固相烧结法合成了Ti掺杂改性的Li2MnO3材料。电子扫描显微镜、X射线衍射以及X射线光电子能谱分析表明Ti元素取代Mn离子掺入到Li2MnO3晶格中,且掺杂能有效地抑制一次颗粒的团聚。电化学阻抗和恒流充放电测试结果表明,在2.0~4.6 V的电压窗口下,掺杂改性的样品Li2Mn0.9Ti0.03O3的首圈放电比容量达到209 mAh·g-1,库仑效率为99.5%,循环40圈后容量保持率为94%;当电流密度增大到400 mA·g-1时,掺杂改性的样品仍然可以放出120 mAh·g-1比容量,远高于同等电流密度下未掺杂的Li2MnO3原粉的比容量(52 mAh·g-1)。Ti掺杂可有效地改善Li2MnO3的循环稳定性和倍率性能,有利于促进该材料的商业化应用。 相似文献