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101.
α’-晶型聚乳酸(PLA)膜被制备和单轴拉伸.通过凝胶渗透色谱仪(GPC)、全反射红外光谱(ATR-IR)、差示扫描量热仪(DSC),X射线衍射(XRD)及Raman光谱等测试技术研究了拉伸温度梯度变化对α’-晶型PLA膜的分子量及其分布、分子链构象、结晶度、晶型转变和取向行为的影响.在恒定拉伸速度与应变下,拉伸温度对PLA膜的应力-应变曲线,特别是屈服强度、拉伸模量产生了较大的影响,其值随拉伸温度的增加而降低.GPC测试结果表明,在不同的温度下拉伸后,PLA会发生一定程度的降解,分子量降低;ATR-IR,XRD,DSC和Raman光谱测试结果表明,在不同的温度下拉伸后α’-型PLA没有发生晶型的转变,即没有由α’-晶体转变为α-或β-晶体.结果表明PLA的结晶度、分子链取向程度强烈依赖于拉伸温度:当拉伸温度低于100℃时,α’-型PLA膜的结晶度与沿着拉伸方向的变形程度随拉伸温度的增加而增加,分子链的高度取向诱导了PLA结晶;当拉伸温度超过100℃后,PLA的分子链沿着拉伸方向上的有序度与结晶度将降低. 相似文献
102.
去氢枞酸类成核剂改性聚丙烯的非等温结晶动力学研究 总被引:7,自引:0,他引:7
对以去氢枞酸盐为成核剂的聚丙烯非等温结晶动力学进行了研究,用修正Avrami方程的Jexiorny法和莫志深法进行处理。结果表明:修正Avrami方程的Jeziorny方法和莫志深法都适用于去氢枞酸类成核剂改性的聚丙烯的非等温结晶动力学。在同样的降温速率下纯聚丙烯的t1/2比成核聚丙烯的t1/2要长,当降温速率为20K/min时,纯聚丙烯和成核聚丙烯的t1/2分别为0.78min和0.51min。同时从莫志深法得到的F(T)结果可以看出,达到相同的结晶度时纯聚丙烯所需的降温速率要大于成核聚丙烯所需的降温速率,说明成核剂的加入提高了聚丙烯的结晶速率。从Jeziorny法求出的纯聚丙烯和成核聚丙烯的Avrami指数分别为4.46和2.77,表明成核剂改变了聚丙烯的结晶成核和生长方式。 相似文献
103.
Low melting temperature thermoplastic sheets based on poly(e-caprolactone) (PCL) can be formed directly on the patient and
are used as immobilization device (mask) in the radiation therapy. The immobilization mask is allowed to harden in isometric
conditions on the body at room temperature. A new method for isometric crystallization kinetics of thermoplastic polymer sheets
is developed using a tensile-strength instrument. The isometric crystallization method allows investigating the shrinkage
force on time of crystallization of stretched samples of thermoplastic polymer sheets or immobilization medical devices. The
dependence of the shrinkage force on time is described by Avrami equation and the kinetics parameters of isometric crystallization
are calculated.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
104.
Josef-Christian Buhl Claudia Taake F. Stief M. Fechtelkord 《Reaction Kinetics and Catalysis Letters》2000,69(1):15-21
Investigations on the formation of nitrate enclathrated cancrinite were performed under low temperature hydrothermal conditions (353 K, autogeneous pressure). The alkaline transformation of kaolinite in the presence of sodium nitrate was selected as the preferred method of synthesis. All experiments were carried out at high alkalinity, using a 16 molar NaOH solution as well as at low NaOH concentrations (2 molar NaOH). Qualitative phase analysis was performed by X-ray-powder diffraction and IR-spectroscopy. Besides cancrinite formation no further intermediate phases were formed. Quantitative data of the educt conversion into cancrinite was determined by 27Al MAS NMR spectroscopy and integration of the resonance signals of four- and six-coordinated aluminium. Whereas full conversion could be found already after 24 h of reaction under highly alkaline conditions, only an insufficient progress of the reaction resulted in the case of low alkalinity. 相似文献
105.
106.
A simulation study of microstructure evolution during solidification process of liquid metal Ni 下载免费PDF全文
A molecular dynamics simulation study has been performed for the
microstructure evolution in a liquid metal Ni system during
crystallization process at two cooling rates by adopting the
embedded atom method (EAM) model potential. The bond-type index
method of Honeycutt--Andersen (HA) and a new cluster-type index
method (CTIM-2) have been used to detect and analyse the
microstructures in this system. It is demonstrated that the cooling
rate plays a critical role in the microstructure evolution: below the
crystallization temperature $T_{\rm c}$, the effects of cooling rate
are very remarkable and can be fully displayed. At different cooling
rates of $2.0\times10^{13}$\,K\,$\cdot$\,s$^{-1}$ and
$1.0\times10^{12}$\,K\,$\cdot$\,s$^{-1}$, two different kinds of
crystal structures are obtained in the system. The first one is the
coexistence of the hcp (expressed by (12 0 0 0 6 6) in CTIM-2) and
the fcc (12 0 0 0 12 0) basic clusters consisting of 1421 and 1422
bond-types, and the hcp basic cluster becomes the dominant one with
decreasing temperature, the second one is mainly the fcc (12 0 0 0 12
0) basic clusters consisting of 1421 bond-type, and their
crystallization temperatures $T_{\rm c}$ would be 1073 and 1173\,K,
respectively. 相似文献
107.
108.
John F. Nagle 《Journal of statistical physics》1985,38(3-4):531-540
It has been suggested that some lattice models of polymers, especially ones that incorporate more realistic excluded volume interactions extending to further neighbors, may be subject to gridlock. A model is defined to have the property of gridlock if it cannot melt at any temperature unless a density decrease is allowed. Classical theories of polymer melting are incompatible with the property of gridlock. This paper proves rigorously that a two-dimensional square-lattice model of polymer chains that have nearest-neighbor excluded volume interactions (called the X1S model) has the gridlock property. The proof uses elementary concepts from graph theory. Also, different interpretations of the X1S model are given in terms of real polymers. This leads to a discussion of a number of different classes of melting depending upon whether the intramolecular rotameric energies and the attractive intermolecular energies are antagonistic to or supportive of the melting transition. 相似文献
109.
110.
在等离子体增强化学气相淀积系统中,采用aSi:H层淀积和原位等离子体氧化相结合的逐层生长技术制备了aSi:H/SiO_2多层膜.在激光诱导限制结晶原理基础上,使用KrF准分子脉冲激光为辐照源,对aSi:H/SiO_2多层膜进行辐照,使纳米级厚度的aSi:H子层晶化.Raman散射谱和电子衍射谱的结果表明,经过激光辐照后纳米Si颗粒在原始的aSi:H子层内形成,晶粒尺寸可以根据aSi:H层的厚度精确控制.还研究了样品的光致发光(PL)特性以及激光辐照能量密度对PL性质的影响.
关键词:
脉冲激光
多层膜
限制结晶 相似文献