Hierarchical ferromagnetic vector spin model possessing the Lee-Yang property. Thermodynamic limit at the critical point and above

The hierarchical ferromagneticN-dimensional vector spin model as a sequence of probability measures onR ^N is considered. The starting element of this sequence is chosen to belong to the Lee-Yang class of measures that is defined in the paper and includes most known examples (⁴ measures, Gaussian measures, and so on). For this model, we probe two thermodynamic limit theorems. One of them is just the classical central limit theorem for weakly dependent random vectors. It describes the convergence of classically normed sums of spins when temperature is sufficiently high. The other theorem describes the convergence of more than normally normed sums that holds for some fixed temperature. It corresponds to the strong dependence of spins, which appears at the critical point of the model.     

Relaxation time for a dimer covering with height representation

This paper considers the Monte Carlo dynamics of random dimer coverings of the square lattice, which can be mapped to a rough interface model. Two kinds of slow modes are identified, associated respectively with long-wavelength fluctuations of the interface height, and with slow drift (in time) of the system-wide mean height. Within a continuum theory, the longest relaxation time for either kind of mode scales as the system sizeN. For the real, discrete model, an exactlower bound ofO(N) is placed on the relaxation time, using variational eigenfunctions corresponding to the two kinds of continuum modes     

细长竖直管路内自然对流沸腾临界热通量研究

l引言管内或窄小流路内的自然对流沸腾CHF的研究比较少。文献［1～41对水及氟里昂系等液体进行了实验，在Kutataladze【’］的池内沸腾无量式基础上，提出如下经验公式当L／De－－＋0时上式退化为池内沸腾公式。式中qm。x是临界热通量；Hi。是蒸发潜热；。是汽液界面张力；尸l和p。分别是液体和蒸汽的密度；9是重力加速度；c是实验常数；不同研究者之间相差很大。当L／De较大时各经验公式的计算值会相差l～2倍。式（1）没有任何物理机理的支持，仅以J和L／De之间的无量纲关系对实验值进行统计整理，对物性的实际影响、De独立于L／De的…     

新的适用于整个热力面的1,1,1,2-四氟乙烷(R134a)跨接状态方程

1前言作者建立了一个新型的符合临界重整化群理论的跨接状态方程，能够描述物质的整个区域热力性质山。鉴于R134a是R12的新的主要替代制冷剂，为了计算其整个区域的热力性质，本文将新跨接状态方程应用于R134a，以便提供一个能在整个区域计算R134a热力性质的状态方程。2新跨接状态方程作者建立了以下型式的新跨接状态方程l‘］：上式中，西方一r一IDZ户一p巾c；，一DI—TD；T—To／T；产为密度；pc为临界密度；T为温度；To为临界温度；矿对比过余Helmholtz自由能；A是Helmholtz自由能。新函数中，a。一30，a，一10；0—0．325和西一…     

Critical Slowing Down in One-Dimensional Maps and Beyond

This is a brief review on critical slowing down near the Feigenbaum period-doubling bifurcation points and its consequences. The slowing down of numerical convergence leads to an “operational” fractal dimension D=2/3 at a finite order bifurcation point. There is a cross-over to D ₀=0.538... when the order goes to infinity, i.e., to the Feigenbaum accumulation point. The problem of whether there exists a “super-scaling” for the dimension spectrum D _q ^W that does not depend on the primitive word W underlying the period-n-tupling sequence seems to remain open     

Surface energies of metals in both liquid and solid states

Although during the last years one has seen a number of systematic studies of the surface energies of metals, the aim and the scientific meaning of this research is to establish a simple and a straightforward theoretical model to calculate accurately the mechanical and the thermodynamic properties of metal surfaces due to their important application in materials processes and in the understanding of a wide range of surface phenomena. Through extensive theoretical calculations of the surface tension of most of the liquid metals, we found that the fraction of broken bonds in liquid metals (f) is constant which is equal to 0.287. Using our estimated f value, the surface tension (γ_m), surface energy (γ_SV), surface excess entropy (−dγ/dT), surface excess enthalpy (H_s), coefficient of thermal expansion (α_m and α_b), sound velocity (c_m) and its temperature coefficient (−dc/dT) have been calculated for more than sixty metals. The results of the calculated quantities agree well with available experimental data.     

A Mixed-Transfer-Matrix Method for Simulating Normal Conductor/Perfect Insulator/Perfect Conductor Random Networks

We develop a mixed-transfer-matrix approach for computing the macroscopic conductivity of a three-constituent normal conductor/perfect insulator/perfect conductor random network. This is applied to two-dimensional and three-dimensional samples at a percolation threshold. Such networks are simulated in order to test whether a diluted percolating network of normal conducting bonds remains in the same universality class of critical behavior when a finite fraction of those bonds have been replaced by perfectly conducting bonds. Also tested by such simulations is whether a percolating mixture of normal and perfectly conducting bonds remains in the same universality class of critical behavior when a finite fraction of the normal bonds are replaced by perfectly insulating bonds. These questions are crucial for some recently published exact results which connect the macroscopic electrical and elastic responses of percolating networks.     

Criterion of homogeneous boiling-up of superheated liquids

It is difficult to eliminate the effect of vessel walls and impurities in practical studies of boiling-up of strongly superheated liquids. Therefore, some doubts are always cast upon validity of experiments and their agreement with the classical theory of homogeneous stationary nucleation, impairing the verification of theoretical considerations. This paper reports main results of the theory of homogeneous nucleation and presents formulas for calculating the work of formation of a critical nucleus by an incline of the accessible superheating boundary on isobars and isotherms. Matching of experimental and theoretical values of the work of formation was considered as the homogeneous boiling-up criterion. Calculations by isobars and isotherms were made for some liquids. The theoretical values of the work of formation of a critical nucleus were 1.23–4.5 times higher than the corresponding empirical values for all the liquids, i.e., they were much higher than the calculation error. Thus, boiling-up of the studied liquids was not homogeneous and, hence, it did not correspond to the classical theory of nucleation. The work was financially supported by the President of the Russian Federation (No. NSh-4429.2006.8) and the Russian Foundation for Basic Research (Grant No. 07-08-00575-a).     

Stretched exponential relaxation in the Coulomb glass

The relaxation of the specific heat and the entropy to their equilibrium values is investigated numerically for the three-dimensional Coulomb glass at very low temperatures. The long time relaxation follows a stretched exponential function, f (t) = f ₀exp - (t/τ)^β , with the exponent β increasing with the temperature. The relaxation time diverges as an Arrhenius law when T→ 0. Received 24 May 2001 and Received in final form 12 September 2001     

Use of Crustacean Shells for Uptake and Removal of Metal Ions in Solution

Abstract

The use of crustacean shells, in particular crab shells, for the removal of metal ions in solution is described. Research studies found in the literature on the ability of the shells, effect of particle size, pH, competitive studies in mixtures of metals, application to real samples such as acid mine drainage, and use of the shells in a column are presented. The major component of the shells that allows uptake to occur is chitin. Several mechanisms are proposed for uptake. There are conflicting accounts in the literature on such areas as the effect of pH, flow rate, and particle size.