Synthesis and Characterization of Amphiphilic Biodegradable Copolymer,Poly(aspartic acid‐co‐lactic acid)

An amphiphilic biodegradable polymer, poly(aspartic acid‐co‐lactic acid) (PAL), was synthesized by simply heating a mixture of aspartic acid (Asp) and L ‐lactide without additional catalysts or solvents. The unique branched architecture comprising succinimide units and lactic acid units was confirmed by IR and NMR spectroscopy. A copolymer of sodium aspartate and lactic acid (PALNa) was prepared by reacting PAL with an aqueous sodium hydroxide solution. The PAL was soluble in many organic solvents, while the PALNa was soluble in methanol and water. The hydrolytic degradation behavior of PAL varied with the copolymer composition. A higher Asp content resulted in a faster molecular weight decrease, and introducing glycolic acid units accelerated the degradation rate.

Microphotograph of microsphere of PAL‐1/5.     

二氧化碳与环氧化合物直接制备聚碳酸酯

综述了近几年来发展的用于二氧化碳与环氧化合物直接催化合成聚碳酸酯的各类催化剂,并详细讨论了其催化反应机理.利用二氧化碳与环氧化合物来合成聚碳酸酯,对于高分子合成化学、碳资源利用和环境保护都具有重大意义.它是发展聚碳酸酯生产的一个具有很大潜力的方面.     

Plasma Copolymerization of Pyrrole with Si-Compounds

The plasma copolymerization of pyrrole with hexamethyldisiloxane, hexamethyldisilane and hexamethyldisilazane was investigated with regard to the polymer deposition characteristics and the properties of the product films. Deposition rates were evaluated by monitoring the weight increase of the deposits over time, and the effect of varying the experimental set up parameters was determined. The results of deposition rates and quantitative IR analysis suggested that the increasing amounts of Si-components were incorporated into the polymer matrix as the supply ratio of the Si-monomer was increased. The Si-component in the copolymer brought some dramatic effects on the physical properties of the films and changed the hydrophobicity of the surfaces, as reflected in the advancing and receding contact angle measurements. The experimental results obtained are discussed in terms of the contribution of the polar and dispersion components of surface energy.     

Struktur und Koordinationsverhalten des sterisch anspruchsvollen Phenylcycloarsoxans

Structure and Coordination Chemistry of Sterically Demanding Phenylcycloarsoxane Tetrameric phenylcycloarsoxane (C₆H₅AsO)₄ 1 exhibits a boat‐chair‐conformation in the solid state. Its reaction with CuI in benzonitrile leads to the formation of coordination polymers. [(CuI · C₆H₅CN){cyclo‐(C₆H₅AsO)₄}] ( 2 ) underlines the structure‐directing steric requirements of the phenyl side chains. Treatment of 1 with M(CO)₆ (M = Cr, Mo) confirms its capability to undergo metal‐mediated ring expansion. In [{M(CO)₃}₂{cyclo‐(C₆H₅AsO)₆}] with M = Cr ( 3 ) and M = Mo ( 4 ), twelve membered As–O‐rings are stabilised by the participation of alternating As atoms in the coordination spheres of opposite facial transition metal carbonyl fragments M(CO)₃.     

Insights on the Synthesis of N-Heterocycles Containing Macrocycles and Their Complexion and Biological Properties

Macrocyclic chemistry has been extensively developed over the past several decades. In fact, the architecture of new macrocyclic models has undergone exponential growth to offer molecules with specific properties. In this context, an attempt is made in this study to provide an overview of some synthetic methods allowing the elaboration of N-heterocycles containing macrocycles (imidazole, triazole, tetrazole, and pyrazole), as well as their applications in the complexation of metal cations or as pharmacological agents.     

城市基层党建与社区社会资本生成—基层社区党建的延展效应

与强调纵向协调有损社区社会资本的观点不同,基层社区党建的延展效应和居民有分寸的自律协调概念,可用以解释中国城市居民住宅小区、尤其是新建商品房住宅小区中社会资本得以生成的现象。居民社区党组织在发挥纵向协调职能时,具有一种作为潜在社会过程的延展效应,导致了居民住宅小区里“有分寸的自律协调机制”的出现,进而生成了居民间的横向社会网络和社区社会资本。对2016年“上海社区研究”（SCS）资料的分析发现,建有活跃党组织的居民住宅小区,会拥有相对较多的居民社团,包括自发型居民社团;在商品房住宅小区里,拥有活跃党组织,同样更有可能形成自发型居民社团。这些发现支持了基于上述论辩的研究假设,表明所提出的中国城市基层党建的延展效应和有分寸的自律协调机制,是能够解释在纵向协调起主导作用的制度环境下社区社会资得以生成的现象的。     

新型氮杂大环化合物的研究2: 四吡唑类卟啉大环化合物的合成 及配位性能

报道了几种四吡唑类卟啉大环化合物的合成及其对Ru^2^+离子的配位性能。结果表明,配体环中4个sp^2杂化N原子均参与对Ru^2^+配位,形成一个近似配位平面,另有两个相同或不同的轴向配体位于平面上下,形成稳定的八面体配位结构。根据轴向配体的配位稳定性可方便地将其进行交换。     

苯乙烯,丙烯腈在炭黑表面的阴离子接枝聚合

反应型炭黑;苯乙烯;丙烯腈在炭黑表面的阴离子接枝聚合     

Protein environmental effects on iron‐sulfur clusters: A set of rules for constructing computational models for inner and outer coordination spheres

The structural properties and reactivity of iron‐sulfur proteins are greatly affected by interactions between the prosthetic groups and the surrounding amino acid residues. Thus, quantum chemical investigations of the structure and properties of protein‐bound iron‐sulfur clusters can be severely limited by truncation of computational models. The aim of this study was to identify, a priori, significant interactions that must be included in a quantum chemical model. Using the [2Fe‐2S] accessory cluster of the FeFe‐hydrogenase as a demonstrative example with rich electronic structural features, the electrostatic and covalent effects of the surrounding side chains, charged groups, and backbone moieties were systematically mapped through density functional theoretical calculations. Electron affinities, spin density differences, and delocalization indexes from the quantum theory of atoms in molecules were used to evaluate the importance of each interaction. Case studies for hydrogen bonding and charged side‐chain interactions were used to develop selection rules regarding the significance of a given protein environmental effect. A set of general rules is proposed for constructing quantum chemical models for iron‐sulfur active sites that capture all significant interactions from the protein environment. This methodology was applied to our previously used models in galactose oxidase and the 6Fe‐cluster of FeFe‐hydrogenase. © 2016 Wiley Periodicals, Inc.