液晶光谱成像技术研究进展

液晶光谱成像技术是基于液晶可调滤光片的新型光谱成像技术.利用向列相液晶材料的电控双折射效应,液晶可调滤光片可在工作谱段内进行连续光谱调谐,实现光谱成像系统的小型化、多用途、实时控制.获取高空间分辫率和高光谱分辫率的光谱图像,是今后航天航空遥感的一个重要发展方向.结合液晶光谱成像技术的国内外研究进展,分析了其目前存在的主...     

基于透明质酸构筑的药物递送载体及其应用

传统纳米药物控释载体主要通过细胞胞吞作用实现药物递送,其主要过程为被动靶向机制,因此会影响纳米载体在肿瘤组织的富集和治疗效果.近年来生物大分子透明质酸因其优异的水溶性、生物相容性、可降解性和肿瘤靶向性备受科研工作者青睐,已被广泛用于药物控释载体的构筑中,并成为靶向肿瘤治疗纳米载体领域的研究热点.本文根据透明质酸基纳米载...     

数控抛光技术中抛光盘的去除函数

抛光盘去除函数的确定是数控抛光技术的应用基础,以Ｐｒｅｓｔｏｎ 方程为基础,应用运动学原理推导了抛光盘在行星运动及平转动两种运动方式下的材料去除函数,并通过计算机模拟出相应的工作特性曲线。结果表明,两种运动方式下工作特性曲线均在不同程度上趋近于高斯曲线。因而行星运动及平转动都可作为抛光盘的运动方式应用在ＣＣＯＰ技术中,使加工中的面形误差得到收敛。     

极坐标系统下进行直角坐标扫描的离子束抛光

在离子束抛光设备研制过程中,离子源扫描运动方式的选择是很关键的,一般分为直角坐标方式扫描和极坐标方式扫描两种。根据两种扫描方式的特点,在极坐标系统下进行直角坐标扫描方式加工。该种方法采用直角坐标扫描方式下的驻留时间计算,算法相对简单。该种方法在极坐标系统下进行加工,同等情况下可加工圆形镜面的口径比直角坐标系统下更大些;而且离子源的可移动区域是一条直线,其余地方可以摆放其他设备,空间利用率较高。对这种新思路进行仿真分析,证实了其具有可行性。     

Controlled Release of the Dithiocarbamate Ligand From A Polypyrrole Polymer. A Basis For On-Line Electrochemicalycontrolled Derivatisation

Abstract

The development of a novel on-line derivatisation scheme is described. the scheme involves use of a conducting polymeric material into which the derivatising agent is incorporated. the properties of the polymer enable electrochemical controlled release of the reagent into flowing solutions.     

A di‐tert‐butyl acrylate monomer for controlled radical photopolymerization

A new di‐tert‐butyl acrylate (diTBA) monomer for controlled radical polymerization is reported. This monomer complements the classical use of tert‐butyl acrylate (TBA) for synthesis of poly(acrylic acid) by increasing the density of carboxylic acids per repeat unit, while also increasing the flexibility of the carboxylic acid side‐chains. The monomer is well behaved under Cu(II)‐mediated photoinduced controlled radical polymerization and delivers polymers with excellent chain‐end fidelity at high monomer conversions. Importantly, this new diTBA monomer readily copolymerizes with TBA to further the potential for applications in areas such as dispersing agents and adsorbents. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 801–807     

Structural rearrangement and stiffening of hydrophobically modified supramolecular hydrogels during thermal annealing

Dynamic crosslinks formed by thermoreversible associations provide an energy dissipation mechanism to toughen hydrogels. However, the details of the organization of these crosslinks impact the hydrogel properties through constraints on the network chain conformation. The physical crosslinks generated by hydrophobic association of the 2‐(N‐ethylperfluorooctane‐sulfonamido)ethyl methacrylate (FOSM) groups in a random copolymer of N,N‐dimethylacrylamide (DMA) and FOSM provide a simple system to investigate how the hydrogel structure (as determined from small angle neutron scattering impacts the mechanical properties of the hydrogel. The initial hydration of the copolymer at 25 °C leads to a kinetically trapped structure with large‐scale heterogeneities. Heating the hydrogel at 60 °C, which is above the glass transition temperature for the FOSM domains, allows the hydrogel structure to rearrange to reduce the density of network defects and the structural heterogeneities. That effectively increases the crosslink density of the network, which stiffens the hydrogel and decreases the swelling at equilibrium at 25 °C. The processing history determines how the hydrophobes aggregate to form the physically crosslinked network, whose structure defines the mechanical properties of these hydrogels. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 1036–1044     

Synthesis of SnO_2 nanorods from aqueous solution:The effect of preparation conditions on the formed patterns

<正>SnO_2 nanorods were deposited on the Si substrates in an aqueous solution containing both SnCl_4 and CO(NH_2)_2.It is found that different self-assembled patterns of SnO_2 nanorods can be obtained by changing the deposition conditions such as the molar ratio of CO(NH_2)_2 to SnCl_4 and the pretreatment of the substrate.Scattered SnO_2 nanorods,for example,can be changed into flower-like patterns when the molar ratio of CO(NH_2)_2 to SnCl_4 is raised,and well-aligned nanorod arrays can be formed when the pretreatment of the substrate is changed.In addition,some interesting patterns,e.g.tree-like patterns,can also be observed.     

Teleportation Capability of Six-Qubit Cluster State

Recently Wei-Bo Gao et al. [Phys. Rev. Lett. 104 （2010） 020501]; reported on the creation of a 4-photon 6-qubit cluster state. It is shown this states can be utilized for perfect teleportation of arbitrary three qubit systems and controlled teleportation of an arbitrary two-qubit state. Therefore, the six-qubit cluster state as quantum channels is equivalent to that of maximally six-qubit entangled state.     

同轴电喷法制备PCL-蛋清体系复合微胶囊

以鸡蛋的卵清蛋白作为蛋白质药物模板、生物可降解材料聚己内酯(PCL)为药物载体模板,采用同轴电喷法制备PCL-蛋清体系的复合微球.研究了电导率、黏度对于电喷微球成型的影响.核壳溶液推进速率比、电压、溶液质量分数和接收距离等对于所得微球表面形态和结构的影响.利用扫描电子显微镜(SEM)研究了微球的表面形态,用荧光显微镜表征了微球的包覆模式.结果表明:同轴电喷法可以制备PCL-蛋清体系的复合结构微胶囊,其中推进速率比对微球形貌、粒径及其分布的影响比较明显,当PCL与蛋清溶液推进速率比大于10时,将出现具有包覆结构的微球.