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141.
142.
Peter A. Markowich Gerhard Rein Gershon Wolansky 《Journal of statistical physics》2002,106(5-6):1221-1239
We consider the Schrödinger–Poisson system in the repulsive (plasma physics) Coulomb case. Given a stationary state from a certain class we prove its nonlinear stability, using an appropriately defined energy-Casimir functional as Lyapunov function. To obtain such states we start with a given Casimir functional and construct a new functional which is in some sense dual to the corresponding energy-Casimir functional. This dual functional has a unique maximizer which is a stationary state of the Schrödinger–Poisson system and lies in the stability class. The stationary states are parameterized by the equation of state, giving the occupation probabilities of the quantum states as a strictly decreasing function of their energy levels. 相似文献
143.
The constants of binding dye molecules with the micelles of sodium dodecyl sulfate are determined using quenching of delayed fluorescence of acridine dyes by sodium iodide in aqueous–micellar solutions. Kinetic equations have been composed that describe the processes of deactivation of the excited states of dyes. By solving these equations at the concentration of the quencher sodium iodide corresponding to the minimum lifetime of triplet states and at the concentration of micelles corresponding to the least value of the delayed fluorescence quenching rate constants, we obtained the constants of binding dyes with micelles equal to 1.3·107, 2.9·107, and 3.1·107 M–1 for trypaflavine, acridine orange, and acridine yellow, respectively. We calculated the rate constants of quenching of the triplet states of the molecules of dyes by iodide ions (I
–) that decreased in transition from trypaflavine to acridine orange and acridine yellow. 相似文献
144.
We examine asymptotically periodic density evolution in one-dimensional maps perturbed by noise, associating the macroscopic state of these dynamical systems with a phase space density. For asymptotically periodic systems density evolution becomes periodic in time, as do some macroscopic properties calculated from them. The general formalism of asymptotic periodicity is examined and used to calculate time correlations along trajectories of these maps as well as their limiting conditional entropy. The time correlation is shown to naturally decouple into periodic and stochastic components. Finally, asymptotic periodicity is studied in a noise-perturbed piecewise linear map, focusing on how the variation of noise amplitude can cause a transition from asymptotic periodicity to asymptotic stability in the density evolution of this system. 相似文献
145.
146.
Rajesh H. Somani Igors Sics Benjamin S. Hsiao 《Journal of polymer science. Part A, Polymer chemistry》2006,44(24):3553-3570
Combined in situ rheo-SAXS (small-angle X-ray scattering) and -WAXD (wide-angle X-ray diffraction) studies using couette flow geometry were carried out to probe thermal stabilty of shear-induced oriented precursor structure in isotactic polypropylene (iPP) at around its normal melting point (162 °C). Although SAXS results corroborated the emerging consensus about the formation of “long-living” metastable mesomorphic precursor structures in sheared iPP melts, these are the first quantitative measures of the limiting temperature at which no oriented structures survive. At the applied shear, rate = 60 s−1 and duration ts = 5 s, the oriented iPP structures survived a temperature of 185 °C for 1 h after shear, while no stable structures were detected at and above 195 °C. Following Keller's concepts of chain orientation in flow, it is proposed that the chains with highly oriented high molecular weight fraction are primarily responsible for their stability at high temperatures. Furthermore, the effects of flow condition, specifically the shear temperature, on the distributions of oriented and unoriented crystals were determined from rheo-WAXD results. As expected, at a constant flow intensity (i.e., rate = 30 s−1 and duration, ts = 5 s), the oriented crystal fraction decreased with the increase in temperature above 155 °C, below which the oriented fraction decreased with the decrease in temperature. As a result, a crystallinty “phase” diagram, i.e., temperature versus crystal fraction ratio, exhibited a peculiar “hourglass” shape, similar to that found in many two-phase polymer–polymer blends. This can be explained by the competition between the oriented and unoriented crystals in the available crystallizable species. Below the shear temperature (155 °C), the unoriented crystals crystallized so rapidly that they overwhelmed the crystallization of the oriented crystals, thus depleting a major portion of the crystallizable species and increasing their contribution in the final total crystalline phase. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3553–3570, 2006 相似文献
147.
Yan Yin Otoo Yamada Shunsuke Hayashi Kazuhiro Tanaka Hidetoshi Kita Ken‐Ichi Okamoto 《Journal of polymer science. Part A, Polymer chemistry》2006,44(12):3751-3762
A series of branched/crosslinked sulfonated polyimide (B/C‐SPI) membranes were prepared and evaluated as proton‐conducting ionomers based on the new concept of in situ crosslinking from sulfonated polyimide (SPI) oligomers and triamine monomers. Chemical branching and crosslinking in SPI oligomers with 1,3,5‐tris(4‐aminophenoxy)benzene as a crosslinker gave the polymer membranes very good water stability and mechanical properties under an accelerated aging treatment in water at 130 °C, despite their high ion‐exchange capacity (2.2–2.6 mequiv g?1). The resulting polymer electrolytes displayed high proton conductivities of 0.2–0.3 S cm?1 at 120 °C in water and reasonably high conductivities of 0.02–0.03 S cm?1 at 50% relative humidity. In a single H2/O2 fuel‐cell system at 90 °C, they exhibited high fuel‐cell performances comparable to those of Nafion 112. The B/C‐SPI membranes also displayed good performances in a direct methanol fuel cell with methanol concentrations as high as 50 wt % that were superior to those of Nafion 112. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3751–3762, 2006 相似文献
148.
Katsuya Sakayori Yuji Shibasaki Mitsuru Ueda 《Journal of polymer science. Part A, Polymer chemistry》2006,44(21):6385-6393
Poly(amic acid)s (PAAs) having the high solution stability and transmittance at 365 nm for photosensitive polyimides have been developed. PAAs with a twisted conformation in the main chains were prepared from 2,2′,6,6′‐biphenyltetracarboxylic dianhydride (2,2′,6,6′‐BPDA) and aromatic diamines. Imidization of PAAs was achieved by chemical treatment using trifluoroacetic anhydride. Among them, the PAA derived from 2,2′,6,6′‐BPDA and 4,4′‐(1,3‐phenylenedioxy)dianiline was converted to the polyimide by thermal treatment. The heating at 300 °C under nitrogen did not complete thermal imidization of PAAs having glass‐transition temperatures (Tg)s higher than 300 °C to the corresponding PIs. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6385–6393, 2006 相似文献
149.
Discrete-time GI/Geo/1 queue with multiple working vacations 总被引:2,自引:0,他引:2
Consider the discrete time GI/Geo/1 queue with working vacations under EAS and LAS schemes. The server takes the original
work at the lower rate rather than completely stopping during the vacation period. Using the matrix-geometric solution method,
we obtain the steady-state distribution of the number of customers in the system and present the stochastic decomposition
property of the queue length. Furthermore, we find and verify the closed property of conditional probability for negative
binomial distributions. Using such property, we obtain the specific expression for the steady-state distribution of the waiting
time and explain its two conditional stochastic decomposition structures. Finally, two special models are presented.
相似文献
150.
P. Kh. Atanasova T. L. Bojadjiev S. N. Dimova 《Computational Mathematics and Mathematical Physics》2006,46(4):666-679
Partial critical dependences of the form current-magnetic field in a two-layered symmetric Josephson junction are modeled. A numerical experiment shows that, for the zero interaction coefficient between the layers of the junction, jumps of the critical currents corresponding to different distributions of the magnetic fluxes in the layers may appear on the critical curves. This fact allows a mathematical interpretation of the results of some recent experimental results for two-layered junctions as a consequence of discontinuities of partial critical curves. 相似文献