Role of Activator and Vacancy Centers in the Decay of the Gamma Scintillators of CsI–Na Crystals

The influence of the concentration of an activator (C _NaI) and of plastic deformation on a change in the contribution of a slow component to the decay of the -scintillations of CsI–Na crystals was investigated, as well as the influence of C _NaI on a change in the shape of the luminescence excitation spectrum in the region of absorption of activator centers (AC) and of vacancy-related centers (VRC) and also on a change in the intercenter time of deexcitation of the centers indicated. It is shown that AC and VRC participate in the photoluminescence and -scintillations of CsI–Na crystals. In the -scintillations, AC are responsible for the component ₁ = 370 nsec, whereas the components ₁ = 460 nsec and ₂ 2 sec are associated with VRC. The reduction of ₁ from 770 to 560 nsec with an increase in C _NaI from 2·10^–3 to 3·10^–2 mole% and from 570 to 470 nsec after plastic deformation of the crystals ( = 5%) along the 111 axis is caused by a decrease in the number of VRC. The mechanisms underlying the -scintillations of the CaI–Na crystals containing AC and VRC and also the decrease in the number of VRC are discussed.     

Modeling of Structures in the Mechanics of Composites

One possible general statement of a quasi-static problem in the mechanics of composites is considered. It is assumed that a composite is characterized not only by the heterogeneity of a regular structure, but also by the presence of imperfections, impurities, cracks, and the roughness of surfaces, which are partly taken into account by introducing appropriate couple stresses. Two statements, in displacements and in stresses, are considered together with the statement of the same problems in the case where the constitutive relations are linear integral operators. The boundary-value problem remains nonlinear due to the nonlinearity of a scattering function which enters into the heat equation. The theory of effective moduli for a nonpolar medium is discussed in more detail. The equilibrium equations for a homogeneous medium with reduced characteristics and the equation of heat inflow, introduced in nonlinear (in an explicit form) and linear variants, are examined. For a simple laminated composite, all effective mechanical and thermophysical characteristics are found in an explicit form. The effective material functions for a transversely isotropic medium are constructed on the basis of a unique dimensionless relaxation kernel with the use of several Il'ushin kernels. Based on the known solution of the boundary-value problem for the reduced medium, the stress and strain concentration tensors, at any point of a simple laminated composite, are also constructed in an explicit form. In this case, the changes in the structure are taken into account.     

Recoverable creep deformation and transient local stress concentration due to heterogeneous grain-boundary diffusion and sliding in polycrystalline solids

Numerical simulations are used to investigate the influence of heterogeneity in grain-boundary diffusivity and sliding resistance on the creep response of a polycrystal. We model a polycrystal as a two-dimensional assembly of elastic grains, separated by sharp grain boundaries. The crystal deforms plastically by stress driven mass transport along the grain boundaries, together with grain-boundary sliding. Heterogeneity is idealized by assigning each grain boundary one of two possible values of diffusivity and sliding viscosity. We compute steady state and transient creep rates as functions of the diffusivity mismatch and relative fractions of grain boundaries with fast and slow diffusion. In addition, our results show that under transient conditions, flux divergences develop at the intersection between grain boundaries with fast and slow diffusivity, which generate high local stress concentrations. The stress concentrations develop at a rate determined by the fast diffusion coefficient, and subsequently relax at a rate determined by the slow diffusion coefficient. The influence of the mismatch in diffusion coefficient, loading conditions, and material properties on the magnitude of this stress concentration is investigated in detail using a simple model problem with a planar grain boundary. The strain energy associated with these stress concentrations also makes a small fraction of the plastic strain due to diffusion and sliding recoverable on unloading. We discuss the implications of these results for conventional polycrystalline solids at high temperatures and for nanostructured materials where grain-boundary diffusion becomes one of the primary inelastic deformation mechanisms even at room temperature.     

疏水表面上吸附态溶菌酶的DSC和FTIR研究

联合差示扫描量热 (DSC)和傅里叶变换红外吸收光谱(FTIR)分别研究了鸡蛋白溶菌酶(Lyz)在适度疏水吸附剂(PEG-600)表面上吸附和折叠时,不同盐(硫酸铵)浓度、表面覆盖度和变性剂(盐酸胍)浓度对无水环境的吸附态天然和变性溶菌酶构象变化及热稳定性的影响。研究发现：随着硫酸铵浓度和溶菌酶表面覆盖度的增加,吸附态天然和变性溶菌酶的吸热峰温度都逐渐降低,同时在较高温度下的微扰也增多。吸附发生后,α-螺旋结构减少,β-折叠和β-转角结构增多。在FTIR图谱中,吸附态变性溶菌酶在1 400～1 425 cm-1处的C—C拉伸振动峰和1 650～1 670 cm-1处的酰胺Ⅰ带特征峰都能明显观测到。但是,与之相比,相同条件下吸附态天然溶菌酶在1 650～1 670 cm-1处特征峰却几乎看不到。吸附态天然溶菌酶发生了结构丢失,表现得更加不稳定。     

含多椭圆孔(核)复合材料加筋层板的应力集中研究

基于各向异性体平面弹性理论中的复势方法,应用杂交变分原理建立了一种与常规有限元相协调的含任意椭圆核各向异性板杂交应力有限元,采用该杂交应力有限元来描述层板的椭圆核区域,采用杆单元来描述加强筋(杆单元的刚度取为层板沿筋条方向的刚度),其余区域采用常规8节点等参单元进行模拟,建立起分析含多椭圆核复合材料加筋壁板问题的力学分析方法,详细讨论了椭圆核大小、位置、筋条尺寸、相对位置、铺层比例等诸参数的影响规律,得到了一些有益的结论。     

I-II复合型裂缝断裂角的分层剪滞模型与分析

采用修正的剪滞理论建立了岩石、混凝土等准脆性材料的I-II复合型裂缝在单向拉伸荷载作用下的计算模型,得到了与实验相吻合且优于传统S判据的断裂角。通过对远场应力、斜裂缝区应力以及子层位移的合理简化,得到了求解剪滞分析模型的边界条件,进而得到了含斜裂缝的各子层位移分布函数。引入最大应力集中因子,对I-II复合型裂缝前缘应力场进行简化;基于斜裂缝沿最大应力集中因子方向扩展,得到裂缝的断裂角。根据斜裂缝的应力分布,设置不同的子层分区,得到了更为细化的位移分布模式。通过对计算数据的分析,针对单向拉伸荷载作用下的I-II复合型裂缝,建立了按应力场分区设置子层的分层剪滞模型,得到更为精确的斜裂缝断裂角。     

The interaction of isomeric hexanediols with sodium dodecyl sulfate and dodecyltrimethylammonium bromide micelles

The micelle formation process for a typical anionic surfactant, sodium dodecyl sulfate, and a typical cationic surfactant, dodecyltrimethylammonium bromide, has been investigated in a series of mixed solvents consisting of different concentrations of isomeric hexanediols (1,2-hexanediol and 1,6-hexanediol) in water. The critical micelle concentrations and the degrees of counterion dissociation of the mixed micelles were obtained from conductance experiments. Luminescence probing experiments have been used to determine the concentration of micelles in solution and, hence, the micellar aggregation numbers of the surfactants in the mixed solvent systems. The alcohol aggregation numbers were determined by combining the partition coefficients (obtained using NMR paramagnetic relaxation enhancement experiments) with the micellar concentrations from the luminescence probing experiments. All these results are interpreted in terms of the difference in the interaction of the isomeric hexanediols with the surfactant as a function of the position of the hydroxyl groups on the six-carbon chain of the alcohol. Received: 28 June 2000/Accepted: 5 July 2000     

Interaction of cetyltrimethylammonium bromide and poly(2-(acrylamido)-2-methylpropanesulfonic acid) in aqueous solutions determined by excimer fluorescence

 The binding interaction of the cationic surfactant cetyltrimethylammonium bromide (CTAB) and anionic poly(2-(acrylamido)-2-methylpropanesulfonic acid) (PAMPS) in dilute aqueous solutions was studied using the excimer fluorescent emission of the cationic probe 1-pyrenemethylamine hydrochloride (PyMeA·HCl). In the absence of CTAB, the saturation binding of PyMeAH⁺ on PAMPS is about 2.4 AMPS repeat units for one probe cation as determined by the relative emission intensity, I _E/I _M, of the excimer to monomer. With increasing CTAB concentration, I _E/I _M firstly increases, reaches a maximum, then decreases to zero. The I _E/I _M maximum indicates a critical aggregation concentration (cac) of 10⁻⁵ mol/l for CTAB in PAMPS solutions. The CTAB concentration at which I _E/I _M is zero is exactly equal to the PAMPS concentration, indicating that the probe cation is thoroughly excluded from the binding site of PAMPS by the CTAB cation and the equivalent stoichiometric aggregation is formed between CTAB and PAMPS. The blueshift of the excimer emission and the excitation spectra shows that the decrease of I _E/I _M with increasing CTAB concentration above the cac is caused mainly by the decrease of the static excimer. Received: 26 July 2000 Accepted: 23 November 2000     

Effect of Nd concentration on the laser performance of a new laser crystal: Nd : NaY(WO4)2

We have measured the transmission and emission spectra of a new crystal, Nd : NaY(WO₄)₂ (Nd : NYW). Using a Ti : sapphire laser as the pump source, the laser performances of Nd : NYW crystals with different concentrations are compared for the first time. The Nd³⁺ concentrations used are 1, 2, 4 and 5 at%. Our investigation shows that 2 at% is the optimum concentration. When the incident pump power is 575 mW, the 1.06 μm output can reach 184 mW, corresponding to an optical-to-optical efficiency of 32%. We believe that our work is significant for the further research and actual application of this promising laser crystal.