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11.
George R. Newkome Gregory R. Baker James K. Young James G. Traynham 《Journal of polymer science. Part A, Polymer chemistry》1993,31(3):641-651
Cascade (dendritic) polymers are discrete, highly branched, monodisperse polymers that possess branching patterns described by a mathematical progression. A systematic nomenclature that accurately represents these molecules is described. © 1993 John Wiley & Sons, Inc. 相似文献
12.
Ioanna Chalari Nikos Hadjichristidis 《Journal of polymer science. Part A, Polymer chemistry》2002,40(10):1519-1526
The synthesis of second‐generation (G‐2) dendritic polymers of isoprene (I) and styrene (S) was achieved with anionic polymerization high‐vacuum techniques and by performing the following steps: (1) selective reaction of a living chain with the chlorosilane group of 4‐(chlorodimethylsilyl)styrene (a dual‐functionality compound) to produce a macromonomer, (2) addition of a second living chain (same or different) to the double bond of the macromonomer, (3) polymerization of I with the anionic sites, and (4) reaction of the produced off‐center living species with trichloromethyl silane or tetrachlorosilane (CH3SiCl3 or SiCl4). The combined characterization results showed that the G‐2 dendritic macromolecules synthesized—(S2I)3, (SI′I)3, (I″I′I)3, (I′2I)4—have a high molecular and compositional homogeneity. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 1519–1526, 2002 相似文献
13.
L. Montrucchio 《Journal of Optimization Theory and Applications》1994,80(3):385-406
We study the relationship between the dynamical complexity of optimal paths and the discount factor in general infinite-horizon discrete-time concave problems. Given a dynamic systemx
t+1=h(x
t
), defined on the state space, we find two discount factors 0 < * ** < 1 having the following properties. For any fixed discount factor 0 < < *, the dynamic system is the solution to some concave problem. For any discount factor ** < < 1, the dynamic system is not the solution to any strongly concave problem. We prove that the upper bound ** is a decreasing function of the topological entropy of the dynamic system. Different upper bounds are also discussed.This research was partially supported by MURST, National Group on Nonlinear dynamics in Economics and Social Sciences. The author would like to thank two anonymous referees for helpful comments and suggestions. 相似文献
14.
O. Naselli 《Journal of Optimization Theory and Applications》1996,91(1):81-90
In this paper, we present a class of functions:f:X such that inf
xX
f(x)=
, whereX is a nonempty, finitely compact and convex set in a vector space andB
x
={xX: y aff(X){x:[x, y]X={x}. Our main tool is a recent minimax theorem by Ricceri (Ref. 1). 相似文献
15.
16.
Multiparticle fractal aggregation 总被引:1,自引:0,他引:1
Richard F. Voss 《Journal of statistical physics》1984,36(5-6):861-872
Kinetic fractal aggregation in a particle bath where a fractionf of the sites are initially occupied is studied withd=2 computer simulations. Independent particles diffusing to a fixed cluster produce an aggregate with fractal dimensionD 1.7 up to a correlation length(f). At larger lengthsD2.(f) asf 0. When the particles remain fixed but the cluster undergoes a rigid random walkD appears constant at larger scales but varies withf. D 1.95 at largef andD 1.7 asf 0. In both cases, the aggregate sizeN(t) grows with timet
(f)
. Aggregation on a surface by independently diffusing particles produces shapes reminiscent of electrochemical dendritic growth. The dependence of growth rate and geometry is studied as a function of particle concentration and sticking probability. 相似文献
17.
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19.
Alternating copolymers of vinyl acetate (VAc) and maleic anhydride (MA) are produced preferentially when VAc and MA are copolymerized at moderate temperatures while random copolymers are produced at temperatures above 90°C. A charge-transfer complex (CTC) of VAc/MA exists at moderate temperatures but does not exist at temperatures above 90°C. 相似文献