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221.
H. Sakuma T. Taniyama K. Ishii Y. Kitamoto Y. Yamazaki 《Journal of magnetism and magnetic materials》2006,300(2):284-292
The order parameter S of Fe–Pt nanoparticles is estimated from X-ray diffraction (XRD) patterns. The total intensity of a diffraction peak is obtained by Rietveld analysis as well as simply integrating the intensity. The Rietveld analysis is found to provide a plausible value of S even for a sample showing an XRD pattern with broad and overlapped peaks. Another order parameter Q, which is obtained from Mössbauer spectra, is introduced, and it is confirmed that Q is equivalent to the probability of Fe atoms being in the L10-type atomic arrangement. The coercivity of Fe–Pt nanoparticles is directly proportional to Q, while it vanishes at S=0.4, indicating that the magnetic property of Fe–Pt nanoparticles has a closer relationship to Q than S. 相似文献
222.
Scaling analysis of the magnitude series (volatile series) has been proposed recently to identify possible non-linear/multifractal signatures in the given data [Y. Ashkenazy, et al. Phys. Rev. Lett. 86 (2001) 1900; Y. Ashkenazy, et al. Physica A 323 (2003) 19; T. Kalisky, Y. Ashkenazy, S. Havlin. Phys. Rev. E 72 (2005) 011913]. In this article, correlations of volatile series generated from stationary first-order linear feedback process with Gaussian and non-Gaussian innovations are investigated. While volatile correlations corresponding to Gaussian innovations exhibited uncorrelated behavior across all time scales, those of non-Gaussian innovations showed significant deviation from uncorrelated behavior even at large time scales. The results presented raise the intriguing question whether non-Gaussian innovations can be sufficient to realize long-range volatile correlations. 相似文献
223.
In this note we study constant mean curvature surfaces in asymptotically flat 3-manifolds. We prove that, outside a given compact subset in an asymptotically flat 3-manifold with positive mass, stable spheres of given constant mean curvature are unique. Therefore we are able to conclude that the foliation of stable spheres of constant mean curvature in an asymptotically flat 3-manifold with positive mass outside a given compact subset is unique.
224.
225.
Hong Ming ZHANG Xian Hong WANG Xiao Jiang ZHAO Ji LI Fo Song WANG 《中国化学快报》2006,17(4):437-440
A novel method for the preparation of oligothiophene molecular wires is described via a bi-directional solid-phase synthesis. Using an alternating sequence of bromination and Stille coupling reactions, oligomers were obtained up to the heptamer in excellent yield and purity. 相似文献
226.
本文研究了一维模型分子离子(初态为基态和一个激发束缚态叠加的相干态)在超强超短激光脉冲作用下的谐波发射谱.我们发现在高次谐波谱平台区域出现了周期性的结构变化.我们利用小波变换对谐波谱进行了暂态时间频率分析,结果表明该谐波结构产生的原因是由电离电子返回母离子时与不同束缚态复合而产生的谐波光脉冲之间相干叠加.同时采用半经典计算,对所得到的计算结果进行了分析,验证了我们的结论. 相似文献
227.
Dimensional analysis is presented as a powerful tool in the study of the paste boriding process. In particular, a dimensional method is used to study the growth kinetics of the boride layers FeB and Fe2B. Experiments were performed in AISI 1045 steel and AISI M2 steel, to test the suggested model. Samples of 1045 steel were prepared and treated using boron paste thickness of 3-5 mm, at temperatures of 1193, 1223 and 1273 K, with 2, 4 and 6 h of treatment time. The M2 specimens had boron paste thickness of 3 and 4 mm and temperatures of 1223, 1253 and 1273 K for 2 and 6 h. Results indicate that the growth of boron layers obeys power laws of the form y = αxβ, where α and β constants are a function of the material and the interface of interest. Validation of the model was carried out using experimental data with an average error percentage of 7.6% for Fe2B in 1045 steel, 15.8% for FeB and 3.4% for Fe2B in M2 steel. 相似文献
228.
Effects of Nb2O5 on thermal stability and optical properties of Er3+-doped tellurite glasses 下载免费PDF全文
Er3+-doped tellurite glasses with molar compositions of
xNb2O5-(14.7-x)Na2O--10ZnO--5K2O--10GeO2--
60TeO2--0.3Er2O3
(x=0, 3, 5, 7 and 9) have been investigated for developing 1.5~μm
fibre and planar amplifiers. The effects of Nb2O5 on the thermal stability
and optical properties of Er3+-doped tellurite glasses have been discussed.
It is noted that the incorporation of Nb2O5 (x=5) increases the thermal
stability of tellurite glasses significantly. Er3+-doped niobium tellurite
glasses exhibit a large stimulated emission cross-section (7.2\times 10-21-
10.7×10-21~cm2 and the gain bandwidth, FWHM×\sigmae^{\rm peak} (274\times 10-28 - 480×10-28~cm3), which are
significantly higher than that of silicate and phosphate glasses. In addition, the
intensity of upconversion luminescence of the Er3+-doped niobium tellurite
glasses decreases rapidly with increasing Nb2O5 content. As a result,
Er3+-doped niobium tellurite glasses might be a potential candidate for
developing laser or optical amplifier devices. 相似文献
229.
230.
ZnO naorods on ZnO-coated seed substrates were fabricated by solution chemical method from Zn(NO3)2/NaOH under assisted electrical field. The working mechanism of electrical field was analyzed and the factors affecting the rod growth such as potential, precursor concentration and growth temperature were elucidated. The structural and optical properties are characterized by SEM, TEM, XRD, HRTEM and UV-vis. The results indicated that the nanorods have wurtzite structure without electrical field and are primarily of zincite structure under electrical field; when the electrical field is 1.1-1.3 V, not only the elevation of ion diffusion and adsorption lower the crystallite/solution interfacial energy and then the crystal nucleation barrier by increasing charge intensity, but also the production of H+ through oxidation of OH− increases properly the degree of solution supersaturation near the substrate, and thus lowers the activation energy. Both the two processes do favor to rod growth. With increasing precursor concentration in this system, the average diameter and length of ZnO nanorods increase, leading to decreasing of optical transmittance. The maximum rod growth rate at given concentration of Zn2+ occurs at a specific temperature. 相似文献