胶体金修饰电极测定鱼样中组胺的方法研究

基于胶体金修饰的玻碳电极,利用电流～时间曲线法建立了一种简便、灵敏的组胺检测方法。优化了底液的pH值和组胺的电化学测试方法及条件,考察了修饰电极的电化学性能。结果表明,组胺在胶体金修饰电极上的响应电流(-I,μA)与其浓度(c,μmol/L)在0. 1～64μmol/L范围内呈良好的线性关系,检出限为0. 033μmol/L,在带鱼和黄花鱼样品中的加标回收率分别为94. 4%～106%、91. 8%～106%,相对标准偏差分别为3. 2%、2. 5%。该法操作简单、检测速度快、成本低,适用于带鱼和黄花鱼等鱼样中组胺的测定。     

基于甲基苯丙胺和吗啡的胶体金免疫层析试剂盒检测法的可靠性评价

通过固相萃取-液相色谱-多级质谱(SPE-LC-MS/MS)联用技术和毒品胶体金免疫层析试剂盒检测法对13种中药及调味品样品中甲基苯丙胺及吗啡分别进行定量分析,依据LC-MS/MS检测结果,对毒品胶体金免疫层析试剂盒检测法进行可靠性评价。实验结果表明:型号1试剂盒对甲基苯丙胺和吗啡的特异性均不高,检测准确率分别为57.7%与78.8%;型号2试剂盒对甲基苯丙胺的特异性不足,准确率为73.1%,但对吗啡的检测准确率达到100%。在利用毒品胶体金免疫层析试剂盒进行毒品快速筛查时,应注重排除干扰因素以提高免疫胶体金层析试剂盒的检测准确度。     

INVERSE OPALINE STRUCTURE TITANIA PHOTONIC CRYSTALS BY FUNCTIONALLY MODIFIED COLLOIDAL CRYSTALS TEMPLATING

Ordered macroporous titania photonic crystals （PCs） and photonic balls were fabricated by functional modified polymer colloidal crystals. The TiO2 PCs and balls formed through this method exhibit no cracks and lacunae in large areas on their surface and their inner structures.     

胶体二硫化钼的高压拉曼散射研究

 测量了平均直径为4 μm的胶体二硫化钼粉剂的高压拉曼光谱。实验结果表明,高压下胶体二硫化钼拉曼峰位随压力增大向高波数方向移动,而峰强随压力增大而减小且峰宽展宽。通过对拉曼峰位移随压力变化的曲线分析,得到了胶体二硫化钼的两个振动模式E¹_2g和A_1g的模式格林爱森常数值。     

Incorporation of smooth spherical bodies in the Lattice Boltzmann method

A method to simulate bodies suspended in a Lattice Boltzmann solvent is proposed. It is based on a generalized reaction force that enforces no-slip boundary conditions at the fluid–body interface as the limiting case of an iterative procedure. A smooth version of the Heaviside function allows to treat spherical particles of arbitrary size and produces smooth hydrodynamic forces as particles move in the continuum. Numerical tests demonstrate the accuracy of the method in reproducing the hydrodynamic field around a single particle and the fluid-mediated forces between pairs of particles. The drag force experienced by a particle moving in a straight channel and at various Reynolds numbers is studied as a non-trivial testcase.     

Charge transport and contact resistance in coplanar devices based on colloidal polyaniline dispersion

The charge transport properties of thin films prepared from colloidal dispersion of polyaniline stabilized by poly(N‐vinylpyrrolidone) (PANI/PVP) have been investigated. The electrical characterization of coplanar device comprising of gold electrodes and PANI/PVP film deposited by spin coating served to gain insights into the contact and bulk resistance. The films prepared from PANI/PVP colloidal dispersion show high stability over a large temperature range. Temperature dependent measurements in the range from 90 to 350 K reveal that the charge transport can be described by a three‐dimensional variable‐range hopping mechanism as the dominant mode in the films. The stability of the films cast from dispersion within a large temperature range opens the possibility of the application as a polymer semiconductor layer in sensors and charge‐transport interlayer in organic solar cells. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1710–1716     

Fast Legendre spectral method for computing the perturbation of a gradient temperature field in an unbounded region due to the presence of two spheres

The temperature distribution around two spheres is considered when the main field has a constant gradient at infinity. Bispherical coordinates are used, together with a transformation of the dependent variable that leads to separation of variables. Then the solution can be sought in Legendre series with respect to one of the bispherical coordinates. An important element of the proposed work is the effective way to reduce an essentially 3D problem to a set of three 2D problems. The Legendre spectral method is shown to have an exponential convergence which is confirmed by the computations. The efficiency is so high that even for the hard cases of two closely situated spheres, an accuracy of 10^?10 is achieved with as few as 20 terms in the expansion. Solutions with both longitudinal and transverse gradients at infinity are obtained, and the contour lines of the temperature field are presented graphically. © 2009 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 2010     

Steady light diffusion application to rheology: a new tool for the characterization of concentrated suspensions

We present new developments of steady light diffusion applied to rheology. Though many techniques allow the structural investigation of diluted or transparent media, very few give direct information on optically dense systems. The technique proposed here is based on the diffusion approximation and is thus valid for sheared, time-dependent flows.After recalling important theoretical results, we show the techniques ability to determine typical sizes and orientation of structures in shear flows for various concentrated suspensions (emulsions, and an industrial softener). In particular, it is able to demonstrate the effect of shear on the orientation of anisotropic objects. Moreover, the use of simple structural models incorporating the measured anisotropy allows good predictions of experimental rheological measurements. This new technique, applicable to a wide range of colloidal systems, is very helpful to characterize the shear induced structural organization of optically dense materials.This paper was presented at the first Annual European Rheology Conference (AERC) held in Guimarães, Portugal, September 11-13, 2003.     

Application of inertia-induced excitation theory for nonlinear acoustic modes in colloidal plasma equilibrium flow

Application of inertia-induced acoustic excitation theory offers a new resonant excitation source channel of acoustic turbulence in the transonic domain of plasma flow. In bi-ion plasmas like colloidal plasma, two well-defined transonic points exist corresponding to the parent ion and the dust grain-associated acoustic modes. As usual, the modified ion acoustic mode (also known as dust ion-acoustic (DIA) wave) dynamics associated with parent ion inertia is excitable for both nanoscale-and micronscale-sized dust grains. It is found that the so-called (ion) acoustic mode (also known as dust-acoustic (DA) wave) associated with nanoscale dust grain inertia is indeed resonantly excitable through the active role of weak but finite parent ion inertia. It is interestingly conjectured that the same excitation physics, as in the case of normal plasma sound mode, operates through the active inertial role of plasma thermal species. Details of the nonlinear acoustic mode analyses of current interest in transonic domains of such impure plasmas in hydrodynamic flow are presented.      

离子注入SiO_2玻璃的光吸收研究

本文用卢瑟福背散射和光吸收技术研究了高剂量Ag离子注入SiO_2玻璃以及退火后的状况.吸收光谱测量表明,注入的Ag离子聚集形成了胶态粒子,其等离子共振峰的极大值在400nm处.运用米(Mie)理论和德拜(Doyle)方法,根据测得的等离子共振峰的光宽度,估算出Ag胶态粒子的半径约为18(?).