全文获取类型
收费全文 | 4588篇 |
免费 | 690篇 |
国内免费 | 512篇 |
专业分类
化学 | 1729篇 |
晶体学 | 68篇 |
力学 | 665篇 |
综合类 | 102篇 |
数学 | 1240篇 |
物理学 | 1986篇 |
出版年
2024年 | 8篇 |
2023年 | 44篇 |
2022年 | 91篇 |
2021年 | 78篇 |
2020年 | 126篇 |
2019年 | 99篇 |
2018年 | 104篇 |
2017年 | 172篇 |
2016年 | 186篇 |
2015年 | 145篇 |
2014年 | 211篇 |
2013年 | 402篇 |
2012年 | 279篇 |
2011年 | 312篇 |
2010年 | 236篇 |
2009年 | 298篇 |
2008年 | 261篇 |
2007年 | 301篇 |
2006年 | 272篇 |
2005年 | 210篇 |
2004年 | 216篇 |
2003年 | 219篇 |
2002年 | 187篇 |
2001年 | 156篇 |
2000年 | 152篇 |
1999年 | 146篇 |
1998年 | 135篇 |
1997年 | 88篇 |
1996年 | 90篇 |
1995年 | 81篇 |
1994年 | 83篇 |
1993年 | 57篇 |
1992年 | 52篇 |
1991年 | 46篇 |
1990年 | 40篇 |
1989年 | 27篇 |
1988年 | 26篇 |
1987年 | 22篇 |
1986年 | 14篇 |
1985年 | 22篇 |
1984年 | 16篇 |
1983年 | 7篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 11篇 |
1979年 | 11篇 |
1978年 | 8篇 |
1977年 | 5篇 |
1976年 | 7篇 |
1957年 | 3篇 |
排序方式: 共有5790条查询结果,搜索用时 15 毫秒
61.
62.
摘要利用改进的可视化装置, 研究了10°锥角的台锥型液相色谱柱内的谱带流型与柱参数变化的关系. 将有机玻璃柱管加工成内圆台外方型的一体结构, 选择折射率一致的色谱固定相硅胶和流动相环己烷, 使整个色谱柱成为高度清晰的透明体, 能直接观察柱中彩色样品谱带的动态三维流型. 研究结果表明, 在实验条件范围内, 流动相流速对谱带流型无影响, 填料的形状和性质对塞子状流型有一定程度的影响. 比较了柱长为5cm和等比例放大后柱长为10cm锥型柱内的流型, 发现放大后的锥型柱内仍然保持塞子状流型, 总柱效等比例增加. 表明继续按比例放大成为工业规模色谱柱后仍能保持塞子状流型. 相似文献
63.
Kean H. Khoo K. Rodney Fernando Richard J. Fereday Chee-Yan Chan 《Journal of solution chemistry》1995,24(10):1039-1048
The solubility of thallium(I) chloride has been determined in aqueous solutions of strontium chloride and barium chloride at concentrations up to 1.5 mol kg–1. The data were analyzed using Pitzer's equations without making explicit assumption of association to ion pairs by assuming =3 instead of =2, with the (1) term for TlCl being equivalent to the (2) term for 2-2 electrolytes. Best values of (0) and (1) for TlCl are recommended together with K
s
, the activity solubility product. These were used to fit the present solubility data and derive the Pitzer model mixture parameters relevant to the systems, fTIN and fTINCl (N=Sr, Ba). Mixture parameters for TlCl+MCl+H2O systems are also derived to complete the parameter base. The fit of the experimental data was found to be worse when higher-order terms for asymmetrical mixing were included in the analysis. Activity coefficients for thallium(I) chloride in the mixtures are derived. 相似文献
64.
基于荧光激发光谱和发射光谱对波长呈高斯分布的设定,本文推导出固定波长同步荧光光谱峰峰值位置、相对强度和半峰宽度等3个主要光谱参数的理论计算式。所提出的计算式应用于若干荧光物质光谱参数的计算,并和实测值、文献计算值作了对照。结果表明,和文献计算方法相比,本法与所研究物质的实际光谱参数较为接近,可为固定波长同步荧光光谱参数的理论计算提供一有效方法。 相似文献
65.
甘氨酸与氯化碱金属在水中的焓相互作用参数 总被引:2,自引:0,他引:2
氨基酸在混合溶液中的热力学性质及相互作用的研究不论对溶液化学还是生命科学都是十分重要的.对此国内已有不少的研究h,’1.利用偿效应的方法研究氨基酸与电解质间的相互作用是很有效的卜一句,但大多数的工作都是在低浓度下研究一个氨基酸分子和一个电解质离子对间的相互作用烩.本文测定了甘氨酸在水中和在LICI、NaCI、KCI的水溶液中的溶解偿,计算出甘氨酸与各个公在水中的偿对相互作用参数和三相互作用参数,并由此讨论了甘氨酸与这些盐的对分子相互作用和三分子相互作用.1实验部分试剂:甘氨酸为ARfa,K甲醇一水重结晶.LI… 相似文献
66.
Nebojša Banjac Gordana Ušćumlić Nataša Valentić Dušan Mijin 《Journal of solution chemistry》2007,36(7):869-878
Absorption spectra of eight 3-substituted-5,5-diphenylhydantoins have been recorded in fourteen solvents in the range 200–400 nm.
The effect of solvent dipolarity/polarizability and solvent/solute hydrogen bonding interactions are analyzed by means of
the linear solvation energy relationship (LSER) concept proposed by Kamlet and Taft. The lipophilic activity of the investigated
hydantoins was estimated by the calculation of log 10
P values with the Advanced Chemistry Development Software. The calculated values of log 10
P were correlated with the ratio of the contributions of specific solvent interactions, and, by employing the linear dependence
thus obtained, the pharmacological activity of the studied hydantoin derivatives is discussed. 相似文献
67.
Guo R Liang X Chen J Wu W Zhang Q Martens D Kettrup A 《Journal of chromatography. A》2004,1035(1):31-36
To avoid the limitation of the widely used prediction methods of soil organic carbon partition coefficients (KOC) from hydrophobic parameters, e.g., the n-octanol/water partition coefficients (KOW) and the reversed phase high performance liquid chromatographic (RP-HPLC) retention factors, the soil column liquid chromatographic (SCLC) method was developed for KOC prediction. The real soils were used as the packing materials of RP-HPLC columns, and the correlations between the retention factors of organic compounds on soil columns (ksoil) and KOC measured by batch equilibrium method were studied. Good correlations were achieved between ksoil and KOC for three types of soils with different properties. All the square of the correlation coefficients (R2) of the linear regression between log ksoil and log KOC were higher than 0.89 with standard deviations of less than 0.21. In addition, the prediction of KOC from KOW and the RP-HPLC retention factors on cyanopropyl (CN) stationary phase (kCN) was comparatively evaluated for the three types of soils. The results show that the prediction of KOC from kCN and KOW is only applicable to some specific types of soils. The results obtained in the present study proved that the SCLC method is appropriate for the KOC prediction for different types of soils, however the applicability of using hydrophobic parameters to predict KOC largely depends on the properties of soil concerned. 相似文献
68.
Solubility and Flory Huggins parameters of SBES, poly(styrene-b-butene/ethylene-b-styrene) triblock copolymer, determined by intrinsic viscosity 总被引:2,自引:0,他引:2
Solubility parameter and Flory Huggins interaction parameter of a triblock SBES have been obtained from intrinsic viscosity measurements. The solubility of the block copolymer in all solvents (methyl-cyclohexane, cyclohexane, cyclopentane, toluene and benzene) was found good except in the case of n-hexane. The results obtained are similar to other found in literature for SBR and SBS rubbers, and indicate that cyclohexane and cyclopentane and methylcyclohexane are the most compatible solvents for this kind of polymer. 相似文献
69.
Qing-de Chen Xing-hai Shen 《高分子科学》2005,(6):635-642
In the UV-Vis spectra of pure light-scattering systems, there is an exponential relationship between absorbance and wavelength (A = Kλ^-n). Here, the exponent n is named as flocculation-coagulation parameter. In the present paper, the effects of different additives on the stability of poly(N,N'-methylenebisacrylamide-co-4-vinylpyridine) (poly(Bis-co-4-VP)) microgel dispersion were studied in detail via this parameter. The results showed that the stability of the dispersion mainly comes from the ionization of pyridine groups, making the microgel positively charged on its surface. This was confirmed by the measurement of Zeta potential and the result of conductometric titration. The result of fluorescence analysis indicated that the hydrophobicity in the microgels is enhanced with the increase in total 4-VP unit content. 相似文献
70.
Chemical compounds containing platinum have been employed since 1978 as drugs to beat certain type of tumours. Nevertheless, besides of their exceptional antitumoral properties, these drugs also have important deleterious side effects, such as, nephrotoxicity and ototoxicity.A study of Pt accumulation and a speciation analysis has been performed by ICP-MS in samples from kidney and inner ear in a controlled population of Wistar rats treated with, either, cisplatin, carboplatin or oxaliplatin. The results on Pt accumulation point out to drug structure and not only to Pt content as the responsible for the alteration of organ functionality.Speciation studies in the samples from kidney and inner ear were performed coupling two-dimensional liquid chromatography (2D-LC) to ICP-MS. Size exclusion (SEC) and anion exchange fast protein liquid chromatography (FPLC) was employed for 2D orthogonal separation. After these separations, free drug peaks were not observed in any of the samples.The binding of Pt to biomolecules was demonstrated by SEC and, independently of the drug used, Pt eluted as two main bands with molecular weights of 12 kDa and 25-65 kDa for inner ear samples, and as two different bands with 20 kDa and 50-60 kDa in the samples from kidney. However, the relative band intensity presented important differences for the three drugs. Using the same chromatographic conditions, it was shown that a metallothionein (MT) standard eluted in the same position as some of the cytosolic Pt-biomolecules.High Pt-containing fractions eluting from the SEC column were analysed by anion exchange FPLC after a preconcentration step. Among the different preconcentration methods tested, sample focusing on the head of the FPLC column shows main advantages. In this way, the separation by 2D chromatography of the high molecular Pt-species has been considerably improved. 相似文献