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41.
Two greener procedures for flow-injection spectrophotometric determination of nitrite in natural waters were developed and critically compared. Replacement of toxic reagents, waste minimization and treatment were exploited to attend the standards of clean chemistry. The flow system was designed with solenoid micro-pumps in order to minimize reagent consumption and waste generation. The first procedure is based on the Griess diazo-coupling reaction with sulfanilamide and N-(1-naphthyl)ethylenediamine (NED) yielding an azo dye, followed by photodegradation of the low amount of waste generated based on the photo-Fenton reaction. The second procedure is based on the formation of iodine from nitrite and iodide in acid medium in order to avoid the use of toxic reagents. For Griess method, linear response was achieved up to 1.0 mg L− 1, described by the equation A = − 0.007 + 0.460C (mg L− 1), r = 0.999. The detection limit was estimated as 8 μg L− 1 at the 99.7% confidence level and the coefficient of variation was 0.8% (n = 20). The sampling rate was estimated as 108 determinations per hour. The consumption of the most toxic reagent (NED) is reduced 55-fold and 20-fold in comparison to batch method and flow injection with continuous reagent addition, respectively. A colorless residue was obtained by in-line photodegradation with reduction of 87% of the total organic carbon content. The results obtained for natural water samples were in agreement with those achieved by the reference method at the 95% confidence level. For the nitrite–iodide method, linear response was observed up to 2.0 mg L− 1, described by the equation A = − 0.024 + 0.148C (mg L− 1), r = 0.999. The detection limit was estimated as 25 μg L− 1 at the 99.7% confidence level and the coefficient of variation was 0.6% (n = 20). The sampling rate was estimated as 44 determinations per hour. Despite avoiding the use of toxic reagents, the nitrite–iodide method presented worst performance in terms of selectivity and sensitivity. 相似文献
42.
集化学家与化学教育家于一身的一代化学大师李比希--纪念李比希诞辰200周年 总被引:1,自引:0,他引:1
在德国著名化学家李比希诞辰200周年之际,对这位集化学家与化学教育家于一身的一代化学大师对科学和科学教育以及人类社会作出的贡献进行了评述。 相似文献
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Summary The novel theoretical scheme IMOMM, integrating ab initio and molecular mechanics contributions in a single geometry optimization process, is applied to the structural determination of different [OsO4(NR3)] (NR3 = bulky chiral alkaloid derivative) species closely related to active catalysts for the asymmetric dihydroxylation of olefins. Computed values compare in a satisfactory way with available X-ray data, the relationship between the Os-N distance and the nature of the NR3, ligand being properly reproduced. The computational scheme allows the separate quantification of electronic and steric effects, as well as the identification of the specific steric repulsions responsible for the difference. 相似文献
46.
Highly ordered mesoporous bioactive glasses with superior in vitro bone-forming bioactivities 总被引:3,自引:0,他引:3
47.
用量子化学从头算方法 ,在RHF/STO - 3G水平上 ,对 2_三氰基乙烯基蒽 (2_TCVA)分子进行了理论计算 ,优化得到了它的平衡几何构型 ,并计算了它的谐振动频率 .结果表明 :2_TCVA存在两种旋转异构体 :2_TCVA(1)和 2_TCVA(2 ) ,2_TCVA(2 )的总能量比 2_TCVA(1)的略高 .在PM3/CIS水平上计算了它们的电子光谱 ,得到了由基态到各激发态的垂直跃迁能和相应的振子强度 .研究表明 :2_TCVA(1)和 2_TCVA(2 )的强度最大的吸收波长分别为 2 4 9.72nm和 2 89.4 1nm ,2_TCVA(2 )的强度最大的吸收波长比 2_TCVA(1)的要长 .计算结果与实验结果符合得较好 相似文献
48.
Poschalko A Lancelot N Marin J Larras V Limal D Elbayed K Raya J Piotto M Briand JP Guichard G Bianco A 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(18):4532-4537
A novel resin called DEUSS (perdeuterated poly(oxyethylene)-based solid support) has been prepared by anionic polymerization of deuterated [D4]ethylene oxide, followed by cross-linking with deuterated epichlorohydrin. DEUSS can be suspended in a wide range of solvents including organic and aqueous solutions, in which it displays a high swelling capacity. As measured by proton HRMAS of the swollen polymer, the signal intensity of the oxyethylene protons is reduced by a factor of 110 relative to the corresponding nondeuterated poly(oxyethylene)poly(oxypropylene) (POEPOP) resin, thus facilitating detailed HRMAS NMR studies of covalently linked molecules. This 1H NMR invisible matrix was used for the solid-phase synthesis of peptides, oligoureas, and a series of amides as well as their characterization by HRMAS NMR spectroscopy. On-bead NMR spectra of high quality and with resolution comparable to that of liquid samples were obtained and readily interpreted. The complete absence of the parasite resin signals will be of great advantage, for example, for the optimization of multistep solid-phase stereoselective reactions, and for the conformational study of resin-bound molecules in a large variety of solvents. 相似文献
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S. Dirè P. Egger M. L. Di Vona M. Trombetta S. Licoccia 《Journal of Sol-Gel Science and Technology》2004,32(1-3):57-61
The preparation of nanostructured organic-inorganic materials by assembling of nanobuilding blocks allows controlling the extent of phase interaction, which in its turn governs structure-properties relationships. We present here the synthesis of siloxane-based nanobuilding blocks prepared by reacting diphenylsilanediol with vinyltriethoxysilane and triethoxysilane. The reaction products were obtained by non-hydrolytic condensation between silanediol and ethoxide groups in inert atmosphere, in the presence of pyridine, triethylamine or butyl lithium. Different synthetic conditions were examined by means of ATR-FTIR and NMR spectroscopies, showing the formation of siloxane bonds. In the case of triethoxysilane the reaction carried out in the presence of pyridine leads to Si–H bond preservation in the final product. Air stable products with improved Si–O–Si hydrolytic stability can be obtained by removal of the base after the reaction completion. The condensation products can be described as a mixture of siloxane rings involving difunctional and trifunctional silicon units. 相似文献