全文获取类型
收费全文 | 9655篇 |
免费 | 1195篇 |
国内免费 | 1073篇 |
专业分类
化学 | 7585篇 |
晶体学 | 281篇 |
力学 | 287篇 |
综合类 | 108篇 |
数学 | 1015篇 |
物理学 | 2647篇 |
出版年
2024年 | 19篇 |
2023年 | 131篇 |
2022年 | 439篇 |
2021年 | 390篇 |
2020年 | 483篇 |
2019年 | 381篇 |
2018年 | 316篇 |
2017年 | 332篇 |
2016年 | 476篇 |
2015年 | 426篇 |
2014年 | 412篇 |
2013年 | 784篇 |
2012年 | 479篇 |
2011年 | 557篇 |
2010年 | 462篇 |
2009年 | 496篇 |
2008年 | 526篇 |
2007年 | 669篇 |
2006年 | 677篇 |
2005年 | 529篇 |
2004年 | 461篇 |
2003年 | 354篇 |
2002年 | 293篇 |
2001年 | 231篇 |
2000年 | 220篇 |
1999年 | 205篇 |
1998年 | 156篇 |
1997年 | 169篇 |
1996年 | 145篇 |
1995年 | 106篇 |
1994年 | 102篇 |
1993年 | 77篇 |
1992年 | 86篇 |
1991年 | 50篇 |
1990年 | 45篇 |
1989年 | 38篇 |
1988年 | 34篇 |
1987年 | 31篇 |
1986年 | 29篇 |
1985年 | 22篇 |
1984年 | 16篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 9篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1978年 | 6篇 |
1977年 | 9篇 |
1976年 | 6篇 |
1974年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
101.
《Magnetic resonance in chemistry : MRC》2003,41(8):626-628
15N isotopic enrichment was necessary for the unequivocal assignment of the 1H NMR lines to the protons in the NH–OH fragment of benzohydroxamic acid, BHXA, C6H5CONHOH, in dry dimethyl sulfoxide solutions. The assignment [δ(NH) = 11.21, δ(OH) = 9.01, 1J(15N,1H) = 102.2 Hz, 2J(15N,1H) <1.5 Hz], which is opposite to that used by other authors, confirms the assignment extended to BHXA by Brown and co‐workers from the spectra of acetohydroxamic acid. The enrichment allowed also assignment of the 29Si lines in the spectra of disilylated benzohydroxamic acid, (Z)‐tert‐butyldimethylsilyl N‐tert‐butyldimethylsilyloxybenzoimidate (2) and (Z)‐tert‐butyldiphenylsilyl N‐tert‐butyldiphenylsilyloxybenzoimidate (3), and confirmed structure of the monosilylated products, N‐tert‐butyldiphenylsilyloxybenzamide (4) and N‐tert‐butyldiphenylsilyloxy benzoimidic acid (5). Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
102.
Archana Devi 《European Polymer Journal》2007,43(6):2422-2432
Cardanol-based novolac-type phenolic resins were synthesized with different mole ratios of cardanol-to-formaldehyde, viz., 1:0.6, 1:0.7, and 1:0.8. These novolac resins were epoxidized with molar excess of epichlorohydrin at 120 °C in basic medium. The epoxidized novolac resins were, separately, blended with different weight ratios of carboxyl-terminated polybutadiene liquid rubber ranging between 0-25 wt% with an interval of 5 wt%. All the blends were cured at 150 °C with 40 wt% polyamide. The formation of various products during the curing of blend samples has been studied by Fourier-transform infra-red spectroscopic analysis. The tensile strength and elongation-at-break of the cured samples increased up to 15 wt% in the blend and decreased thereafter. This blend sample was also found to be most thermally stable system. The blend morphology, studied by scanning electron microscopy analysis, was finally correlated with the structural and property changes in the blends. 相似文献
103.
104.
N. A. Anikin A. S. Mendkovich M. B. Kuzminskiy A. M. Andreev 《Russian Chemical Bulletin》2008,57(2):428-430
A new fast computational method for mass calculations of docking complexes by the AM1/PM3 semiempirical methods is proposed.
The computation time is shortened by at least an order of magnitude compared to alternative schemes of quantum chemical calculations.
The root-mean-square deviation of the AM1 calculated energies of formation of complexes from the results obtained by conventional
diagonalization procedure is at most 0.4 kcal mol−1.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 418–420, February, 2008. 相似文献
105.
R. W. Home 《Physics in Perspective (PIP)》2005,7(4):473-490
I survey highlights of the practice of physics and allied sciences in Melbourne,Australia, from the 1850s, soon after Europeans
first settled in the area, to the present. I note recognizable sites of past and current physical-science activity that may
be visited, as well as exhibits of historic items of physics apparatus. I trace the role of physics, in the course of a century
and a half, in the evolution of a pioneering settlement into a large city embedded in a modern industrial economy. 相似文献
106.
王梅珍 《宁波大学学报(理工版)》2004,17(1):116-120
介绍了国外计算机图形学界对织物变形形态的研究现状.按建模原理分为几何方法。物理方法及综合方法. 相似文献
107.
U.Deva Priyakumar 《Tetrahedron letters》2004,45(12):2495-2498
A novel preference for planar tetracoordination was observed over the conventional tetrahedral arrangement in a new series of C5H2, C5H4, C5H41+/2+ and related compounds. The stability of these molecules is assessed with the ring-opening barriers, HOMO-LUMO gap, singlet-triplet energy differences and nucleus independent chemical shift values. 相似文献
108.
关于非线性多目标规划问题非劣解解法的探讨 总被引:3,自引:0,他引:3
非线性多目标规划是一类复杂的规划问题,由于其往往没有最优解,因此求其非劣解具有重要的意义。本首先探讨了无约束条件下非线性多目标规划的解法,然后提出了有约束条件下非线性多目标规划的一种解法。所述方法具有一定的普遍意义。 相似文献
109.
Summary The potential of liquid chromatography-mass spectrometry (LC-MS) has been studied for the simultaneous determination of sixteen carbamate and organophosphorus pesticides in honeybees using a traditional sample preparation protocol based on acetone extraction and dichloromethane partitioning. The performances of both atmospheric pressure chemical ionization (APCI) and electrospray (ES) interfaces were compared. APCI offered better sensitivity and specificity for a higher range of pesticides. Limits of quantification were from 0.01 to 0.17 mg kg–1, at which recoveries obtained were between 64 and 93%, except for pirimicarb that was at 13%, with relative standard deviations ranging from 7 to 20%. Fenitrothion, fenoxycarb, methiocarb and phoxim were found in bees from Valencian Community beehives at concentrations between 0.03 and 3.75 mg kg–1. 相似文献
110.
Pierre Gaspard 《Journal of statistical physics》2004,117(3-4):599-615
A concept of time-reversed entropy per unit time is introduced in analogy with the entropy per unit time by Shannon, Kolmogorov, and Sinai. This time-reversed entropy per unit time characterizes the dynamical randomness of a stochastic process backward in time, while the standard entropy per unit time characterizes the dynamical randomness forward in time. The difference between the time-reversed and standard entropies per unit time is shown to give the entropy production of Markovian processes in nonequilibrium steady states. 相似文献