Imaging and tracking an electrostatic charge micro-domain by Kelvin force microscopy as evidence of water adsorption on mica surface

Muscovite mica is a widely accepted substrate for scanning probe microscopy (SPM) investigations. However, mica has intrinsic properties that alter samples and obstruct their analysis due to free charges build-up, ionic exchange and water adsorption taking place at the surface. In addition to interfacial phenomena, there is a growing interest in electrostatic charges on insulators as they are crucial in diverse applications. Despite the high demand for studies of this nature, experimental set-ups capable of resolving charge build-up at the micro-scale are still scarce and technically limited. Here, we report the imaging of surface charge dissipation on freshly cleaved mica by Kelvin-probe Force Microscopy (KPFM). A local electrostatic charge micro-domain was generated by friction between an atomic force microscope (AFM) tip and mica, and its decay was tracked by two-dimensional mapping using KPFM. We found time-dependent charge dissipation, which is attributed to the adsorption of water molecules on mica surface.     

有机薄膜电致发光器件载流子注入和传输性质的研究

制备了不同电极、不同厚度、以8-羟基喹啉铝螯合物(Alq3)为发光层的有机薄膜电致发光(TFEL)器件。分析了它们的电流密度-电压关系。不同阳极器件的电流变化很大,而改变阴极时电流密度的变化较小,说明电流以空穴为主。根据不同阴极器件的电致发光效率的比较,说明电子是决定器件电致发光效率的少数载流子。从不同厚度的器件的结果讨论了载流子的传输性质,认为在ITO/Alq3/Al器件中的电流符合陷阱限制的空间电荷电流.     

基于MMPP的802.11网络性能

提出并建立了一个基于马尔可夫调制的泊松过程MMPP(M arkovModu lated Poisson Process)和间歇泊松过程IPP(Interrupted Poisson Process)的系统模型,从新用户的到达和系统中用户发起的新业务两个方面着手,考察了在受系统门限值约束情况下的接入系统的新用户数量和系统内用户发     

聚乙撑二氧噻吩导电聚合物上吗啡的电化学检测

在水相中电沉积制备得到了聚乙撑二氧噻吩（PEDOT）导电聚合物膜,研究了沉积电量、沉积电位等因素对聚合物膜的电化学活性及其在水溶液中检测吗啡的电化学响应的影-向．结果表明．沉积电量为20～40mC,沉积电位为1．2V（相对于Ag／AgCl电极）时所得的聚合物膜对吗啡具有最高的电化学响应．在此基础上,研究了PEDOT膜修饰电极在不同浓度的吗啡水溶液中的电化学检测,发现在0．05～6mmol·L^-1浓度范围内具有很好的线性响应．最低检测限为0．05mmol·L^-1,相关系数达0．995．     

强流相对论性电子束在低压中性气体中传输的研究

本文给出了强流相对论性电子束(IREB)在低压中性气体中传输特性的理论和实验研究结果。660kV,40kA,脉宽100ns的电子束注入充有H_2,N_2的漂移管,稳定的传输气压范围在(0.7-6.7)×10~2Pa间,传输效率可达80％以上;极低气压时(P≈13.3Pa)由于空间电荷效应,束电子被虚阴极阻滞并径向发散,不能有效传输;而较高气压时,束电子除受自身电磁场作用及库仑碰撞散射外,等离子体不稳定性使束流传输效率明显降低。用蒙特·卡洛法及数值解析法对电荷中和、电流中和过程进行了模拟计算并解释了实验结果。     

Thermoluminescence of x-irradiated CaSO4:Dy phosphors and role of Na2SO4 as a charge compensator

The thermoluminescence of x-irradiated CaSO₄: Dy phosphors has been studied for diverse activator concentrations. The concentration-dependence of these phosphors on the increase of glow peak intensities has been found to be remarkable. For higher concentration of dysprosium the concentration quenching effect has been observed. This has been attributed to the resonant transfer of energy from one activator atom to another, bringing the possible migration of energy in a solid, which is likely to get dissipated without luminescence, at the quenching site itself. The effect of irradiation time on the glow peak intensities reveals the initial linearity and a subsequent decrease indicating the possible radiation damage. The role of Na₂SO₄ as a charge compensator has been studied in detail. An attempt has been made to unravel the type of kinetics involved in the process, by calculating the activation energies by different methods. It has been concluded that the type of kinetics involved in the process is bimolecular.     

掺杂型红色有机电致发光显示器件

全色显示是有机电致发光显示(OLED)器件发展的目标,而高性能红色发光器件一直是制约全彩色OLED器件实用化的瓶颈,也是目前有机电致发光显示研究的热点。制作了掺杂DCJTB和不同浓度的rubrene两种荧光染料的红色有机电致发光显示器件,以NPB和Alq₃分别作为空穴传输层和电子传输层,发现器件性能与只掺杂DCJTB的器件相比有明显提高,发光效率提高到2～3倍。通过Frster理论和能带理论分析了器件的能量转移机理,研究发现Frster能量转移不是掺杂器件能量转移的主要形式,载流子俘获机制才是器件效率提高的主要原因;rubrene的引入使得能量能够更有效地从Alq₃转移到DCJTB,从而显著地提高了器件的发光效率和性能。     

ECR-SFC轴向注入系统聚束器效率的研究

为了减少目前SFC轴向注入系统中聚束器杂散电场对束流轴向注入效率的影响, 提高新系统中SFC的束流俘获效率, 参考原始设计, 对目前聚束器的电极结构进行了设计改进. 两种情况下的聚束器杂散场对注入效率影响的计算表明, 改进后0B02的聚束效率较目前有较大提高. 同时计算了束流空间电荷效应对聚束效率的影响, 据此对新SFC轴向注入系统中聚束器的位置进行了重新调整.     

Isospin symmetry violation, meson production and η-nucleus interaction studies

We have studied isospin symmetry violation in nuclear reactions by measuring simultaneously the cross-section of the following two reactionsp +d →³H π⁺ andp +d →³He π⁰. The experiment was perfomed at the cooler synchrotron accelerator COSY, Jülich at several beam energies close to the correspondingη production threshold. We also have ongoing programmes onη-nucleus final-state interaction studies viap+⁶ Li →⁷ Be +η reactions, high resolution search for dibaryonic resonances and lambda-proton final state interaction studies. The experimental details and results obtained so far are presented here     

On the Formation of Nanostructures from Stilbazolium-like Dyes

Nanostructures with well-defined shape and highly monodisperse size were fabricated from model stilbazolium-like dyes with specific molecular structural and conformational characteristics. With the help of absorption and fluorescence optical spectroscopy, the correlated spectroscopy (COSY) and two- dimensional nuclear Overhauser effect spectroscopy (2D NOESY) techniques, along with X-ray diffraction (XRD) measurement, distinctively different aggregation processes of the model molecules are demonstrated. For model dye molecule with linear donor–π system–acceptor (D–π–A) structure, strong D–A pair, and planar conformation, specific intermolecular interaction was identified and special crystal structures as well as spectral properties were observed. For model dye molecules bearing nonlinear D–π–A–π–D structure, weak D–A pair but actual amphiphilic characteristics, a special aggregation process was confirmed and a focused size distribution of the produced nanostructures was obtained.