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41.
高效亲和色谱法测定2种中药成分与人血清白蛋白的结合率 总被引:1,自引:0,他引:1
采用高效亲和色谱技术(HPAC)对中药成分与人血清白蛋白(HSA)的相互作用进行了研究。首先采用点击化学的方法制备了表面键合有HSA蛋白的硅胶固定相并装填成亲和色谱柱,根据药物在该色谱柱上与空白硅胶柱上的保留时间差计算得到药物与蛋白的结合率。利用该方法测得模型化合物华法令与HSA的结合率与文献中采用超滤法测得的结果基本一致,表明该方法可用于测定药物与HSA的结合率。在此基础上用该方法测定了葛根素和告依春两种中药成分与HSA的相对结合率分别为10.26%和10.20%。同时用超滤的方法测定了葛根素与HSA的结合率为14.25%。结果表明,HPAC可以作为研究药物与蛋白相互作用的一种简便可行的方法,其测定结果与超滤方法一致。 相似文献
42.
L.R.B. Santos A. Larbot C.V. Santilli S.H. Pulcinelli 《Journal of Sol-Gel Science and Technology》1998,13(1-3):805-811
In this work the sol-gel process was used to prepare SnO2 supported membranes with an average pore size of 2.5 nm. The effects of salt concentration (NaCl or CaCl2) and of the pH of the aqueous solutions used on the flux and selectivity through the SnO2 membrane were analyzed by permeation experiments and the results interpreted taking account of the zeta potential values determined from the electrophoretic mobility of the SnO2 powder aqueous dispersion. The results show that the ion flux (Na+, Ca2+ and Cl–) throughout the membrane is determined by the electrostatic repulsion among these species and the surface charge at the tin oxide-solution interface. 相似文献
43.
现有的两类一元理论离心泵叶轮水力设计方法存在试凑性工作量大或盖板形状不为简单曲线的缺陷。本文提出了符合一元理论的离心泵叶轮轴面流道过流断面的一种新的分布规律,并给出了按照此分布规律计算叶轮轴面流道过流面积的计算方法和公式。将其与传统的两类设计方法做了比较。 相似文献
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45.
离心泵叶轮参数对进口回流的影响 总被引:3,自引:0,他引:3
本文对不同叶片进口角、叶片数、不同叶顶间隙的开式和闭式离心叶轮共12种叶轮的进口流场和回流发生情况进行了探针的动态测试和可视化观察.弄清了上述叶轮参数对进口回流初始流量和进口流场的影响. 相似文献
46.
The nonkeratinous proteins of wool can be partly or completely dissolved by controlled enzymatic digestion. A comparison between the keratose content of intact wool and that of wool which has been hydrolysed for 96 h with pronase confirms that specifically all the nonkeratinous components are dissolved out of the wool composite by pronase. The influence of microbial infection can be excluded.The residue of wool after the hydrolysis, i. e., a wool low in nonkeratinous proteins, has a higher internal volume, as measured by mercury porosimetry. The centrifugal swelling test shows that these wool samples also have increased hygroscopy. 相似文献
47.
The permeate fluxes and percent protein transmission were evaluated for steady-state crossflow ultrafiltration of two proteins of different composition: bovine serum albumin (BSA), containing fatty acid, and “fatty-acid-poor” BSA, from which most of the fatty acids had been removed (BSA/FAP). The influences of protein concentration up to 6.5 percent w/v, transmembrane pressure, ionic environment and membrane type (i.e. nominal molecular weight cut-off) were investigated. For both BSA and BSA/FAP, the fluxes and the protein transmission were dependent on the amount of salt present. The higher fatty acid content in the BSA apparently enhanced protein-protein interaction, resulting in a more cohesive and resistant fouling layer; permeate fluxes were lower with BSA/FAP than with BSA at otherwise corresponding operating conditions. A hysteresis behaviour of the flux (J)-transmembrane pressure (TMP) relationship was observed whenever the ultrafiltration unit was operated at a TMP less than some higher value to which the membrane previously had been exposed. 相似文献
48.
49.
本文试验研究了扩压器几何参数对一高速离心风机的噪声的影响。扩压器的几何参数包括叶片数、叶轮与扩压器的径向间隙和倾斜前缘倾角以及它们的耦合作用对风机噪声的影响。试验结果表明:(1)风机A声级噪声随扩压器叶片数增加而下降,但气动性能也随之下降;(2)扩压器前缘半径从R_3/R_2=1.03增加到1.07,在设计点风机A声级噪声降了约3 dB(A),继续增大至1.09则基本不变;(3)适当倾斜扩压器前缘可有效降低风机噪声,在设计点30°倾角扩压器相应的风机A声级噪声下降了约3.6 dB(A);(4)倾斜扩压器前缘与增大径向间隙的降噪效果不能叠加。 相似文献
50.
Summary: Natural and synthetic polymers with heteroatom, such as oxygen, nitrogen, sulfur or phosphorous, potentially can efficiently remove metal ions from aqueous solutions. The ability of synthetic polymers derived from imino diacetic acid, acrylamido glycolic copolymer, and the natural polymer alginic acid to remove metal ions from dilute solution in conjunction with ultrafiltration membranes was studied. The maximum retention capacity was determined and its polymer-metal ion-complexes were studied as possible antibacterial agents. 相似文献