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101.
Photovoltaic and spectral properties of tetraphenyloporphyrin and metallotetraphenyloporphyrin dyes 总被引:1,自引:0,他引:1
Spectroscopical properties and photocurrent (or photovoltage) of tetraphenyloporphyrins and metallotetraphenyloporphyrins in nematic liquid crystal have been studied. Photoelectric response has been measured in an electrochemical cell made of the semitransparent semiconducting and golden electrodes with porphyrin dyes embedded in liquid crystal. Fluorescence, time-resolved luminescence in microsecond time scale and photoacoustic spectra have also been measured. The competition between radiative, non-radiative processes and charge transfer is discussed. It has been shown that effectivity of porphyrins for photocurrent generation depends on the presence/absence of central metal in the macrocycle of porphyrin skeleton and the kind of metal. The schematic model of the contributions of the dye molecule and semiconducting electrode in the electron transfer process is shown. 相似文献
102.
《Chemphyschem》2004,5(2):175-182
The selectins are Ca2+‐dependent cell adhesion molecules that facilitate the initial attachment of leukocytes to the vascular endothelium by binding to a carbohydrate moiety as exemplified by the tetrasaccharide, sialyl Lewis X (sLeX). An important property of the selectin‐sLeX interaction is its ability to withstand the hydrodynamic force of the blood flow. Herein, we used single‐molecule dynamic force spectroscopy (DFS) to identify the molecular determinants within sLeX that give rise to the dynamic properties of the selectin/sLeX interaction. Our atomic force microscopy (AFM) measurements revealed that the unbinding of the selectin/sLeX complexes involves overcoming at least two activation barriers. The inner barrier, which determines the dynamic response of the complex at high forces, is governed by the interaction between the Fuc residue of sLeX and a Ca2+ ion chelated to the lectin domain of the selectin molecule, whereas the outer activation barrier can be attributed to interactions involving the sialic acid residue of sLeX. Due to their steep inner activation barriers, the selectin‐sLeX complexes are less sensitive to high pulling forces. Hence, besides its contribution to the bond energy, the Ca2+ ion also grants the selectin–sLeX complexes a tensile strength that is crucial for the selectin‐mediated rolling of leukocytes. 相似文献
103.
应用火焰原子吸收光谱(FAAS)法测定了钮扣电池中铅和镉的含量,对测定条件作了较详细的研究。用在线双毛细管标准加入法消除了基体的干扰。按所述方法测定电池样品中铅和镉,测定结果的RSD依次为3.58%和5.87%,铅和镉的浓度水平分别为5.4×10-3%和2.3×10-4%(质量分数),回收率结果为93.0%~100.1%(铅)和95.0%~101.0%(镉)。 相似文献
104.
Haruhisa Kikuchi Yuko Sahashi Asami Haganuma Yoshiteru Oshima 《Tetrahedron letters》2004,45(33):6225-6228
Paecilomycine A (1), B (2), and C (3) were isolated from cultivated fruiting bodies of Paecilomyces tenuipes (Isaria japonica), which is a popular entomopathogenic fungus used in folk medicine and health foods in China, Korea, and Japan. The structures of 1-3 were deduced from their spectroscopic data and their absolute configurations were elucidated by preparing their MPA esters. Compound 1 showed activity in the neurotrophic factor biosynthesis in glial cells. 相似文献
105.
Jingye Li Kohei Sato Saneto Asano Minoru Iida Yoneho Tabata Masakazu Washio 《European Polymer Journal》2005,41(3):547-555
Crosslinked and non-crosslinked polytetrafluoroethylene films (RX-PTFE and V-PTFE films, respectively) were irradiated by γ-ray and then grafted with styrene in liquid phase. Microscope FT-IR spectroscopy, TGA, solid state 13C CP/MAS and high resolution HS/MAS NMR spectroscopy, wide-angle X-ray diffraction (WAXD) study were used to get the structural information of the styrene grafted RX-PTFE and V-PTFE films. From microscope FT-IR spectra of the grafted RX-PTFE films, the “grafting front mechanism” was proved. TGA analysis showed that the grafted films have a small degradation step and two main degradation steps. In the 13C CP/MAS NMR spectra of the non-grafted films, there are no signal due to the absence of the hydrogen atom. While in the spectra of the grafted films, there are signals attributed to the polystyrene grafts. In the 13C HS/MAS NMR spectra of the grafted films, the relative intensity of the peaks attributed to the polystyrene grafts increased while the relative intensity of the peak attributed to PTFE matrix decreased with the increase in the DOG. From WAXD patterns, the intensity of the crystalline peak decrease with the increase in the DOG. The grafted films were sulfonated by chlorosulfonic acid and the results of highest IEC value exceeded 3.0. Those results will be reported in the near future. 相似文献
106.
Ceramic BaCe0.8Ho0.2O3-α with orthorhombic perovskite structure was prepared by conventional solid state reaction, and its conductivity and ionic transport number were measured by ac impedance spectroscopy and gas concentration cell methods in the temperature range of 600-1000 ℃ in wet hydrogen and wet air, respectively. Using the ceramics as solid electrolyte and porous platinum as electrodes, the hydrogen-air fuel cell was constructed, and the cell performance at temperature from 600-1000 ℃ was examined. The results indicate that the specimen was a pure protonic conductor with the protonic transport number of 1 at temperature from 600-900 ℃ in wet hydrogen, a mixed conductor of proton and electron with the protonic transport number of 0.99 at 1000 ℃. The electronic conduction could be neglected in this case, thus the total conductivity in wet hydrogen was approximately regarded as protonic conductivity. In wet air, the specimen was a mixed conductor of proton, oxide ion and electron hole. The protonic transport numbers were 0.01-0.09, and the oxide-ionic transport numbers were 0.27-0.32. The oxide ionic conductivity was increased with the increase of temperature, but the protonic conductivity displayed a maximum at 900 ℃, due to the combined increase in mobility and depletion of the carriers. The fuel cell could work stably. At 1000 ℃, the maximum short-circuit current density and power output density were 346 mA/cm^2 and 80 mW/cm^2, respectively. 相似文献
107.
硝酸镧对大鼠肝脏癌前病变发展的抑制作用及机制的初步探讨 总被引:2,自引:2,他引:2
研究硝酸镧对大鼠肝脏癌前病变的抑制作用及机制. 采用肝癌发生的短期动物模型, 连续用0.2, 10 mg·kg-1的La(NO3)3灌胃2个月后, 观察了不同剂量La(NO3)3对大鼠肝脏形态结构的影响, 免疫组化技术检测肝脏中细胞周期素D1和P16及PCNA的表达, 并做半定量分析. 同时取脾细胞进行淋巴细胞转化率试验. 结果表明, 0.2 mg·kg-1剂量硝酸镧组动物健康状况明显改善, 肝癌前病变程度明显减轻, cyclinD1, PCNA表达下降, P16表达上升, 淋巴细胞转化率升高. 提示低剂量硝酸镧具有一定阻抑肝癌前病变的作用. 相似文献
108.
利用AFM和SNOM对淋巴细胞膜表面超微结构及其光学性质的初步研究 总被引:5,自引:0,他引:5
利用原子力显微镜(Atomic Force Microscopy,AFM)对淋巴细胞表面形貌进行了形态学的初步研究,观察到了其膜表面其他显微技术所不能发现的超微结构.同时也运用扫描近场光学显微镜(Scanning Near field Optical Microscopy,SNOM)对淋巴细胞进行成像,观察了其对光的透射、吸收等光学性质,并对两种成像方法进行了比较.研究发现:淋巴细胞膜表面凹凸不平,分布着大量直径几十到几百纳米不等的小颗粒;淋巴细胞中央部位有自发荧光现象.结果表明,AFM和SNOM可作为进一步探讨淋巴细胞的结构与功能关系的有力工具. 相似文献
109.
110.
While it is well-known that the RSA public-key cryptosystem can be broken if its modulusN can be factored, it is not known whether there are other ways of breaking RSA. This paper presents a public-key scheme which necessarily requires knowledge of the factorization of its modulus in order to be broken. Rabin introduced the first system whose security is equivalent to the difficulty of factoring the modulus. His scheme is based on squaring (cubing) for encryption and extracting square (cube) roots for decryption. This introduces a 14 (19) ambiguity in the decryption. Various schemes which overcome this problem have been introduced for both the quadratic and cubic case. We generalize the ideas of Williams' cubic system to larger prime exponents. The cases of higher prime order introduce a number of problems not encountered in the quadratic and cubic cases, namely the existence of fundamental units in the underlying cyclotomic field, the evaluation of higher power residue symbols, and the increased difficulty of Euclidean division in the field. 相似文献