Ca2+掺杂铌酸锶钡晶体的光折射变化特性研究

基于Ca²⁺掺杂铌酸锶钡晶体的透射特性,探讨了Ca²⁺在晶体中的电子行为机制，分析了Ca²⁺掺杂而引起的光致折射率变化特性.采用Michelson干涉装置测得了样品折射率随时间变化的特性曲线.实验结果分析表明，适当的Ca²⁺掺杂可以有效改善铌酸锶钡晶体的光折射特性. 关键词： 2+')" href="#">Ca²⁺ 铌酸锶钡 透射率 光折变     

Association of riboflavin,caffeine, and sodium salicylate in aqueous solution

We have used UV and visible spectrophotometry to study self-association of aromatic riboflavin molecules (RFN, vitamin B₂, 7,8-dimethyl-10-N-(1′-D-ribityl)isoalloxazine) in aqueous solution (pH 6.86) at T = 298 K, using a dimer model. We have determined the equilibrium dimerization constant for riboflavin, K_dB = 125 ± 40 M⁻¹. We have studied heteroassociation in the system of molecules of 7,8-dimethyl-10-ribitylisoalloxazine with 1,3,7-trimethylxanthine (caffeine) and sodium salicylate (NAS) in aqueous solution (pH 6.86; T = 298 K). We have determined the heteroassociation constants for RFN-NAS and RFN-caffeine molecules in the absence and in the presence of urea in solutions using a modified Benesi-Hildebrand equation: 25 ± 4, 17 ± 3, and 74 ± 11, 53 ± 7 M⁻¹ respectively. We have determined the dimerization constants for NAS (2.7 ± 0.5 M⁻¹) and caffeine (17.0 ± 1.5 M⁻¹). We conclude that heteroassociation of the aromatic molecules leads to a lower effective riboflavin concentration in solution, and the presence of urea in mixed solutions leads to an decrease in the complexation constants for the RFN-NAS and RFN-caffeine systems. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 2, pp. 188–194, March–April, 2007.     

Functionalization of the active chain ends of poly(vinyl chloride) obtained by single‐electron‐transfer/degenerative‐chain‐transfer mediated living radical polymerization: Synthesis of telechelic α,ω‐di(hydroxy)poly(vinyl chloride)

The chloroiodomethyl chain ends of poly(vinyl chloride) (PVC) obtained by the single‐electron‐transfer/degenerative‐chain‐transfer mediated living radical polymerization of vinyl chloride initiated with iodoform were quantitatively functionalized by the reaction with 2‐allyloxyethanol (CH₂?CHCH₂OCH₂CH₂OH). This reaction was performed in dimethyl sulfoxide at 70 °C and was catalyzed by sodium dithionite/sodium bicarbonate. The resulting product is the first example of telechelic PVC [α,ω‐di(hydroxy)PVC]. A possible mechanism for this reaction was suggested. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1255–1260, 2005     

Ultrafast single‐electron‐transfer/degenerative‐chain‐transfer mediated living radical polymerization of acrylates initiated with iodoform in water at room temperature and catalyzed by sodium dithionite

Sodium dithionite in the presence of NaHCO₃ in water acts as a single‐electron‐transfer agent and facilitates the single‐electron‐transfer/degenerative‐chain‐transfer mediated living radical polymerization (SET–DTLRP) of acrylates initiated with iodoform at room temperature. The resulting α,ω‐di(iodo)polyacrylates can be used as macroinitiators for the SET–DTLRP of other acrylates. Ultrahigh‐molar‐mass poly(tert‐butyl acrylate) can be synthesized via the SET–DTLRP of tert‐butyl acrylate and has a very low weight‐average molecular weight/number‐average molecular weight ratio of 1.15. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 2178–2184, 2005     

合成试剂及反应XI X一硝酸铈铵催化下溴酸钠对酰肼的氧化裂解

在硝酸铈铵催化下,酰肼可被溴酸钠氧化成羧酸。本方法具有试剂价廉、反应迅速、操作简便、产率较高的特点。     

Solute-Solvent interactions in water-rich mixtures. II. Ionic conductances in water-dimethylsulfoxide mixtures at 25°C

Conductances of sodium bromide, iodide, and perchlorate, potassium chloride, and tetraphenylboride (BPh ₄ ^– ) as well as triisoamyl-n-butylammonium iodide (i-Am₃BuNI) have been measured in aqueous mixtures containing up to 20 mole percent dimethylsulfoxide (DMSO) at 25°C. Experimental data were analyzed by the 1965 Fuoss-Onsager-Skinner (FOS) equation. Single-ion limiting equivalent conductances were calculated by assuming that ₀ (i–Am ₃ BuN ⁺=₀ (BPh ₄ ^– ). The variations of the limiting ionic Walden products are discussed on the basis of acid-base type interactions for cations, and on the basis of structural effects for anions.     

The interaction between sodium carboxymethylcellulose and water

A differential scanning calorimeter has been used to study the nonfreezing of water in a series of solutions of sodium carboxymethylcellulose. In particular, the effects of molecular weight, degree of substitution, and particle size have been investigated. The results show that large amounts of water are associated with all the samples of sodium carboxymethylcellulose, suggesting a multilayer arrangement of water molecules about the solute. A change in degree of substitution has some effect on the hydration, but it appears less significant than a change in molecular weight.     

Ion-pair assisted recovery of matrix-assisted laser desorption/ionization mass spectral signals from SDS-containing peptide-protein mixtures

We have developed a simple and effective means of using alkylammonium ion-pairing agents, such as cetyltetramethylammonium bromide, to recover matrix assisted laser desorption/ionization mass spectrometric (MALDI-MS) signals from sodium dodecyl sulfate (SDS)-containing protein and peptide samples. A two-layer method of matrix preparation, with a bottom matrix layer of ion-pairing agents and a top matrix layer of SDS protein samples, is essential for reproducible MALDI mass spectra with good recovery. Both buffer ions and ion-pairing agents have profound effects on signal recovery and can be rapidly and systematically optimized. This practical technique, termed ion-pair assisted recovery (IPAR), is compatible with major SDS-based biotechniques and can be easily incorporated into high-throughput proteomic analysis.     

An EPMA Study on KNbO3 and NaNbO3 Single Crystals – Potential Reference Materials for Quantitative Microanalysis

Single crystals of KNbO₃ and NaNbO₃ were selected from the limited number of suitable alkali compounds that are available and evaluated as possible reference materials for the electron-probe microanalysis (EPMA) of alkaline niobates with a composition described by the general formula K_1–XNa_XNbO₃. The EPMA study verified that KNbO₃ and NaNbO₃ single crystals are stable under the electron beam and compositionally homogeneous. A quantitative microanalysis confirmed the composition of pure KNbO₃, while the NaNbO₃ crystal contained 0.3 mass fraction % of Ca. A significant improvement in the accuracy of the quantitative EPMA of polycrystalline potassium–sodium niobates was achieved using these single crystals as standards. The crystals can also be useful as reference materials for the analysis of sodium and potassium in other materials.