全文获取类型
收费全文 | 1726篇 |
免费 | 453篇 |
国内免费 | 280篇 |
专业分类
化学 | 1124篇 |
晶体学 | 32篇 |
力学 | 77篇 |
综合类 | 16篇 |
数学 | 30篇 |
物理学 | 1180篇 |
出版年
2024年 | 5篇 |
2023年 | 30篇 |
2022年 | 47篇 |
2021年 | 59篇 |
2020年 | 78篇 |
2019年 | 44篇 |
2018年 | 61篇 |
2017年 | 92篇 |
2016年 | 77篇 |
2015年 | 111篇 |
2014年 | 133篇 |
2013年 | 144篇 |
2012年 | 109篇 |
2011年 | 125篇 |
2010年 | 79篇 |
2009年 | 97篇 |
2008年 | 117篇 |
2007年 | 120篇 |
2006年 | 118篇 |
2005年 | 69篇 |
2004年 | 75篇 |
2003年 | 67篇 |
2002年 | 75篇 |
2001年 | 69篇 |
2000年 | 60篇 |
1999年 | 57篇 |
1998年 | 50篇 |
1997年 | 39篇 |
1996年 | 36篇 |
1995年 | 27篇 |
1994年 | 22篇 |
1993年 | 23篇 |
1992年 | 26篇 |
1991年 | 18篇 |
1990年 | 16篇 |
1989年 | 11篇 |
1988年 | 9篇 |
1987年 | 11篇 |
1986年 | 13篇 |
1985年 | 3篇 |
1984年 | 9篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 2篇 |
1980年 | 3篇 |
1979年 | 7篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 2篇 |
排序方式: 共有2459条查询结果,搜索用时 203 毫秒
141.
Kyung Moon Jung Kyung Hwan Kim Jung‐Il Jin Min Ju Cho Dong Hoon Choi 《Journal of polymer science. Part A, Polymer chemistry》2008,46(22):7517-7533
New deep‐red light‐emitting phosphorescent dendrimers with hole‐transporting carbazole dendrons were synthesized by reacting tris(2‐benzo[b]thiophen‐2‐yl‐pyridyl) iridium (III) complex with carbazolyl dendrons by DCC‐catalyzed esterification. The resulting first‐, second‐, and third‐generation dendrimers were found to be highly efficient as solution‐processable emitting materials and for use in host‐free electrophosphorescent light‐emitting diodes. We fabricated a host‐free dendrimer EL device with configuration ITO/PEDOT:PSS (40 nm)/dendrimer (55 nm)/BCP (10 nm)/Alq3 (40 nm)/LiF (1 nm)/Al (100 nm) and characterized the device performance. The multilayered devices showed luminance of 561 cd/m2 at 383.4 mA/cm2 (12 V) for 15 , 1302 cd/m2 at 321.3 mA/cm2 (14 V) for 16 , and 422 cd/m2 at 94.4 mA/cm2 (18 V) for 17 . The third‐generation dendrimer, 17 (ηext = 6.12% at 7.5 V), showed the highest external quantum efficiency (EQE) with an increase in the density of the light‐harvesting carbazole dendron. Three dendrimers exhibited considerably pure deep‐red emission with CIE 1931 (Commission International de L'Eclairage) chromaticity coordinates of x = 0.70, y = 0.30. The CIE coordinates remained very stable with the current density. The integration of rigid hole‐transporting dendrons and phosphorescent complexes provides a new route to design highly efficient solution‐processable materials for dendrimer light‐emitting diode (DLED) applications. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 7517–7533, 2008 相似文献
142.
Improving the specularity of magnetic mirrors for atoms 总被引:1,自引:0,他引:1
G. Zabow M. Drndić J.H. Thywissen K.S. Johnson R.M. Westervelt M. Prentiss 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1999,7(3):351-359
An array of anti-parallel current-carrying wires creates an inhomogeneous magnetic field capable of reflecting neutral atoms.
We present analytical and numerical analyses of the magnetic field produced by such an array, and describe methods for reducing
the resulting rms angular deviation from specular reflection to less than 0.1 mrad. Careful choice of cross-sectional wire
profiles is shown to dramatically improve specularity of reflection close to the surface. Additionally, we find that the specularity
depends on whether the number of wires in the mirror is even or odd, and that there exists an optimal turning height above
the surface that maximizes the specularity of reflection from the mirror.
Received 16 November 1998 相似文献
143.
Woo‐Hyung Lee Hoyoul Kong Se‐Young Oh Hong‐Ku Shim In‐Nam Kang 《Journal of polymer science. Part A, Polymer chemistry》2009,47(1):111-120
A series of modified thiophene groups containing PPV‐based semiconducting materials, poly[(2,5‐bis(octyloxy)‐1,4‐phenylenevinylene)‐alt‐(2,2′bithienylenevinylene)] ( PPBT ), poly[(2,5‐bis(octyloxy)‐1,4‐phenylenevinylene)‐alt‐(5,5‐thiostilylenevinylene)] ( PPTVT ), have been synthesized through a Horner coupling reaction. From the FTIR and 1H NMR spectroscopy, the configuration of the vinylene groups in the polymers was all trans (E) geometry. The weight‐average molecular weights (Mw) of PPBT and PPTVT were found to be 11,700 and 11,800, with polydispersity indices of 2.51 and 2.53, respectively. PPBT and PPTVT thin films exhibit UV–visible absorption maxima at 538 and 558 nm, respectively, and the strong absorption shoulder peaks at 578 and 602 nm, respectively. Solution processed field‐effect transistors (FET) fabricated using all the polymers showed p‐type OTFT characteristics. The field‐effect mobility of the PPTVT was obtained up to 2.3 × 10?3 cm2 V?1 s?1, an on/off ratio of 1.0 × 105 with ambient air stability. Studies of the atomic force microscopy (AFM) and X‐ray diffraction (XRD) analysis of the polymer thin films revealed that all the polymers were amorphous structure. The greater planarity and rigidity of PPTVT compared to PPBT results in elongation of conjugation length and better π–π stacking of polymer chains in amorphous region, which leads to improved FET performance. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 111–120, 2009 相似文献
144.
《Laser \u0026amp; Photonics Reviews》2017,11(5)
Mid‐infrared ultrafast lasers have emerged as a promising platform for both science and industry because of their inherent high raw power and eye‐safe spectrum. 2D nanostructures such as graphene have emerged as promising photonic materials for laser mode‐locking to generate ultrashort pulses. However, there are still many unanswered questions about graphene's key advantages to be practical devices, especially over the matured semiconductor saturable absorber mirror (SESAM). In this work, we conducted systematic comparisons on the nonlinear optical properties of graphene and that of a commercial SESAM at 2 μm wavelength. Our results showed that graphene has significant advantages over the commercial SESAM, exhibiting ∼28% less absorptive cross‐section ratio of excited‐state to ground‐state and ∼50 times faster relaxation time. This implies that graphene can be exploited as a better mode‐locker than the current commercial SESAM for high power, high repetition rate and ultrafast mid‐infrared laser sources. 相似文献
145.
Yoav Linzon Boris A. Malomed Michael Zaezjev Roberto Morandotti Maite Volatier Vincent Aimez Richard Ares Shimshon Bar-Ad 《Central European Journal of Physics》2008,6(3):555-562
We study nonlinear interactions between discrete optical solitons that propagate in different regimes of diffraction, and
the nonlinear scattering of dispersive waves by local optical potentials. It is well known in optics that when linear coherent
waves meet, they interfere without interactions. Linear waves also scatter through local optical structures not exchanging
any power with the guided modes of these structures. As a focusing Kerr nonlinearity is present, such linearly-inhibited phenomena
can exist. Our studies are performed in silica and AlGaAs nonlinear waveguides, excited by ultra-short pulses in the near
infrared.
Presented at 9-th International Workshop on Nonlinear Optics Applications, NOA 2007, May 17–20, 2007, Świnoujście, Poland 相似文献
146.
147.
电极过程自由基中间体的ESR研究——取代苯基重氮盐的电解还原 总被引:2,自引:0,他引:2
本文用自由基捕捉剂苯亚甲基叔丁基氮氧化物(PBN)与ESR相结合的方法研究了十种取代苯基重氮盐RC6H4N2+BF4-(R=F,Cl,Br,NO2,OCH3及CH3)在乙腈中电解还原产生的活泼自由基。结果表明:1.RC6H4N2+BF4-电解还原时产生RC6H4自由基,并能被捕捉剂PBN所捕捉,以形成稳定的自由基加合物[RC6H4-PBN]·。2.由[RC6H4-PBN]·ESR谱的超精细裂分常数算出的二面角θβ值大小与处于不同位置的给定取代基R的关系为:θβ(O-R) < θβ(m-R) < θβ(P-R) 相似文献
148.
F.-J. Zhang Z. Xu Y.-G. Lv J.-C. Zhang S. L. Zhao J.-Z. Huang Y. Wang G.-C. Yuan D.-W. Zhao X.-R. Xu 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,52(2):245-248
The organic-inorganic combined structural device (ITO/PVK:Eu/ZnS/Al) is
fabricated based on layered optimization scheme. II–VI semiconductor
material ZnS is acted as an electron function (transporting and
acceleration) layer. The hot electrons which have been accelerated in the
ZnS layer directly impact excitation europium ions through resonant energy
transfer and then recombine with injected holes to form excitons in PVK or
EuTTA2(N-HPA)Phen. Europium (Eu) ions may also be excited by
intramolecular energy transfer from ligands. There are two kinds of
excitation mechanisms: impacted excitation and injected recombination for
the combined structural device. The electroluminescence (EL) intensity of
the combined structural device is strongly improved and reaches up to
381 cd/m2 at 20 V compared with the pure organic structural device. It
may be an effective method to improve the EL intensity of the lanthanide
complex by using electric characteristics of inorganic semiconductor
materials. 相似文献
149.
Wen-Jin Yin Xiao-Long Zeng Bo Wen Qing-Xia Ge Ying Xu Gilberto Teobaldi Li-Min Liu 《Frontiers of Physics》2021,16(3):33501
Heterostructure is an effective approach in modulating the physical and chemical behavior of materials. Here, the first-principles calculations were carried out to explore the structural, electronic, and carrier mobility properties of Janus MoSSe/GaN heterostructures. This heterostructure exhibits a superior high carrier mobility of 281.28 cm2·V−1·s−1 for electron carrier and 3951.2 cm2·V−1·s−1 for hole carrier. Particularly, the magnitude of the carrier mobility can be further tuned by Janus structure and stacking modes of the heterostructure. It is revealed that the equivalent mass and elastic moduli strongly affect the carrier mobility of the heterostructure, while the deformation potential contributes to the different carrier mobility for electron and hole of the heterostructure. These results suggest that the Janus MoSSe/GaN heterostructures have many potential applications for the unique carrier mobility. 相似文献
150.
《中国物理 B》2021,30(5):53702-053702
Micromotion induced by the radio-frequency field contributes greatly to the systematic frequency shifts of optical frequency standards. Although different strategies for mitigating this effect have been proposed, trapping ions optically has the potential to provide a generic solution to the elimination of micromotion. This could be achieved by trapping a single ion in the dipole trap composed of a highpower laser field. Here, we present the setup of the dipole trap composed of a 532 nm laser at a power of 10 W aiming to optically trap a single ~(40)Ca~+ and we observe an AC-Stark shift of the fluorescence spectrum line of ~22 MHz caused by the 532 nm dipole beam. The beam waist of the dipole laser is several microns, which would provide a dipole potential strong enough for all-optical trapping of a single ~(40)Ca~+ ion. 相似文献