First Cellulose Langmuir‐Blodgett Films towards Photocurrent Generation Systems

Langmuir‐Blodgett films of a cellulose derivative containing porphyrins, porphyrin‐cellulose, were fabricated in order to construct a cellulose‐based molecular photocurrent generation system. On visible light illumination of the LB monolayer film deposited on an ITO electrode, anodic photocurrents were observed with a quantum yield of 1.6% at an applied potential of 0 V versus SCE, and 3.8–4.6% at 0.2–0.3 V versus SCE. These values indicate that the self‐quenching of the photoexcited porphyrins in the cellulose LB film was suppressed, while porphyrin moieties in the LB film had a densely packed structure. This is because the porphyrins are located at a distance of approximately 1.0 nm along the cellulose backbone.

     

在周期性极化铌酸锂波导中的波长转换与光谱分析

实验研究了在准相位匹配LiNbO₃波导中级联的倍频和差频波长转换,通过对转换频谱分析和波形对比分析,讨论了在脉冲泵浦情况下走离效应对光脉冲之间波长转换的影响：由于波导的色散性能,不同波长的光脉冲在波导中传播具有不同的群速度,处在0.8 μm光波段的倍频光脉冲比处在1.55 μm光波段的泵浦光脉冲的传播速度慢,导致了倍频光脉冲与泵浦光脉冲在传播的过程中发生走离;因此倍频脉冲在频域被压缩而在时域被展宽,并遗传给差频过程使得转换脉冲的谱宽变窄、脉宽增加、占空比变大,表明脉冲光泵浦波长转换对信号频谱及波形不是严格透明的转换。实验同时实现了一对多通道的波长转换,表明连续控制光的线宽对转换信号的信噪比有较大的影响。     

Statistical laws of the pressure fluctuations in a hypersonic turbulent boundary layer

The results of measuring the pressure fluctuations on the wall of the nozzle of a hypersonic wind tunnel beneath a developed turbulent boundary layer are presented for the Mach number M_∞ = 7.5. On the basis of a statistical analysis, it is shown that the action of the turbulent flow is dynamically similar to the propagation of a random sequence of wave packets with continuously distributed temporal and spatial scales. Low-frequency disturbances are associated with large-scale structures of long duration that propagate at a mean-statistical velocity similar in value to the outer flow velocity. The continuous generation of weakly-correlated small-scale disturbances ensuring the maintenance and development of turbulence occurs chiefly in the inner region of the boundary layer. Spectral estimates of the power generated by the turbulent flow in the wall region of the boundary layer are presented.     

Entropy analysis for third grade fluid flow with Vogel model viscosity in annular pipe

The steady-state flow of a third grade fluid between concentric circular cylinders is considered and entropy generation due to fluid friction and heat transfer in the annular pipe is examined. Depending upon the fluid viscosity, entropy generation in the flow system varies. The third grade fluid is employed to account for the non-Newtonian effect while Vogel model is accommodated for temperature-dependent viscosity. The analysis is based on perturbation technique. The closed form solutions for velocity, temperature and entropy fields are presented. Entropy generation due to fluid friction and heat transfer in the flow system is formulated. The influence of viscosity parameters A and B on the entropy generation number is investigated. It is found that entropy generation number reduces with increasing viscosity parameter A, which is more pronounced in the region close to the annular pipe inner wall and opposite is true for increasing viscosity parameter B.     

超声波辅助提取-HG-ICP-AES法测定中草药雷公藤中可溶态Sb(Ⅲ)和Sb(Ⅴ)

本文建立了用超声波辅助提取,氢化物发生-电感耦合等离子体原子发射光谱法测定中草药雷公藤中可溶态Sb(Ⅲ)和Sb(Ⅴ)的分析方法。研究了超声波辅助提取的影响因素、锑形态分离的最佳pH值、仪器工作条件对锑氢化物发生的影响及五价锑的还原条件,探讨了共存离子对锑测定的干扰及消除方法。Sb(Ⅲ)和Sb(Ⅴ)的检出限分别为0.3和2.4 μg·L-1, 相对标准偏差分别为3.9%和4.5%,样品加标回收率为93%～105%。     

基于季戊四醇的三代硅碳烷液晶树状物研究

用发散法合成了季戊四醇-四烯丙基醚为核、周边含硝基偶氮苯介晶基元(M-NO₂)端基的新型三代硅碳烷液晶树状物PCSi-3G-NO₂, 并利用元素分析、红外光谱(IR)、核磁共振(NMR)、偏光显微镜(POM)、差示扫描量热法(DSC)和X射线衍射(XRD)进行表征. PCSi-3G-NO₂显示胆甾相和近晶S_E相, 其液晶相行为是K57S_E115I100Ch80S_E53K. 而对应的介晶基元M-NO₂显示向列相, 二者在熔点、清亮点和液晶态温区等方面差别较大.     

MgO海/泡石复合载体负载Cu催化剂催化环己醇脱氢

采用浸渍沉淀法制备了不同比例的MgO/海泡石(Sep)复合载体负载Cu催化剂,并考察了其对环己醇脱氢反应的催化性能。采用N2气物理吸附、X射线衍射(XRD)、红外光谱(IR)、氨气程序升温脱附(NH3-TPD)、程序升温还原(TPR)等测试技术对催化剂进行了表征。结果表明,海泡石的引入有助于催化剂比表面积的增加,但当载体中海泡石的比例太高时,会导致催化剂酸性以及活性组分Cu状态的变化,从而降低催化剂的活性和选择性。当复合载体中海泡石质量分数为40%时,催化剂的活性最高,选择性也较好。     

硫增感AgBrI T颗粒乳剂光电子行为研究

利用微波相敏技术,获得了硫增感AgBrIT颗粒乳剂中自由光电子和束缚光电子时间衰减信号,分析了光电子衰减时间、电子陷阱效应、光电子寿命、有效陷阱深度及束缚电子转移时间与增感时间的关系,获得了最佳的增感时间、衰减时间、电子陷阱效应、光电子寿命、有效陷阱深度和转移时间数值.     

氢化物发生辅助雾化火焰原子吸收法测定人发中的铅

使用氢化物发生辅助雾化的火焰原子吸收法,在K₃Fe(CN)₆-HCl体系中,测定了头发中铅的含量。对酸度、氧化剂及浓度、NaBH₄的浓度及流速对Pb测定的影响分别进行了研究。与传统雾化火焰原子吸收法相比,本方法测铅的灵敏度提高了13.4倍。方法的检出限为2.8 μg·L-1,精密度(RSD)为1.4%。用于测定人发中的Pb,回收率达96%～99%。     

A compact I－V model for lightly-doped-drain MOSFETs

A novel model for lightly-doped-drain (LDD) MOSFETs is proposed, which utilizes the empirical hyperbolic tangent function to describe the I－V characteristics. The model includes the strong inversion and subthreshold mechanism, and shows a good prediction for submicron LDD MOSFET. Moreover, the model requires low computation time consumption and is suitable for design of MOSFETs devices and circuits.