LiNi0.8Co0.2O2 / MWNTs复合物超级电容器电极材料的研究

Multiwalled carbon nanotubes (MWNTs) were used as the conductive additive in the electrode materials. The electrochemical properties of supercapacitors based on LiNi_0.8Co_0.2O₂ / MWNTs composite and LiNi_0.8Co_0.2O₂/acetylene black composite and MWNTs in 1.0 mol·L^-1 LiClO₄ / EC+DEC [V(EC)∶V(DEC)=1∶1] electrolyte were investigated by means of constant charge/discharge current tests, respectively. The experimental results show that the LiNi_0.8Co_0.2O₂ / MWNTs composite has better performance than that of others, and the maximum specific capacitance of the supercapacitor can reach 271.6 F·g^-1, while the energy density is up to 339.5 Wh·kg^-1. Furthermore, it is remarkable that the performance of MWNTs is better than that of acetylene black as the conductive additive.     

镓(Ⅲ)-茜素氨羧络合剂在碳糊电极上的阳极吸附伏安法研究及应用

研究了镓(Ⅲ)-茜素氨羧络合剂(ALC)在碳糊电极上的阳极吸附伏安行为,并以此建立了一种高灵敏度、高选择性测定镓的吸附伏安法.在0.12 mol/L HAc-NaAc-0.24 mol/L邻苯二甲酸氢钾底液(pH 4.5)中,-0.10 V (vs.SCE) 富集90 s (或180 s),以250 mV/s扫速线性扫描至0.90 V, Ga3+-ALC在碳糊电极上产生灵敏的与ALC的峰电位相差近230 mV的吸附氧化峰,其二次导数峰电流与镓浓度在5.0×10-10～8.0×10-7 mol/L范围内呈线性关系;富集240 s检出限达3.0×10-10 mol/L(S/N=3).探讨了电极反应机理.该法用于粮食样品中镓的测定,结果满意.     

高温下硅酸锂吸收CO2的研究

以SiO₂和Li₂CO₃为反应原料，采用高温固相法于不同温度下合成了一系列可在高温500~750 ℃之间直接吸收CO₂的硅酸锂(Li₄SiO₄)材料。采用扫描电子显微镜(SEM)、X射线粉末衍射仪(XRD)分别观察和评价了合成材料的表面形貌与结构特征，用热重分析仪(TG)研究了硅酸锂材料吸收CO₂的性能。实验结果表明，在750 ℃下煅烧6 h即可合成出吸收CO₂性能良好的硅酸锂材料，在CO₂气氛下，于700 ℃保持约15 min即可达到吸收平衡，其吸收量约达43%(wt)左右。与文献报道相比，材料的合成条件有所改善，材料吸收CO₂的容量也有较大提高。     

Construction of vicinal quaternary carbon atoms by Ireland ester Claisen rearrangement: total synthesis of (±)-herbertenolide, (±)-herberteneacetal, (±)-herbertene-1,14-diol and (±)-herbertene-1,15-diol

Efficient total syntheses of the herbertane sesquiterpene title compounds have been accomplished employing an Ireland ester Claisen rearrangement and ring-closing metathesis reaction sequence based strategy for the construction of two stereogenic vicinal quaternary carbon atoms on a cyclopentane.     

The Chemistry of Simple Phosphorus-Carbon Compounds

With the aid of selected examples an overview is given of the development trends in phosphoruscarbon chemistry over the past few years. An attempt is made to demonstrate the relationships between various parameters and properties such as constitution, basicity, substitution by functional groups, reaction behavior etc. of the compounds. In the case of basis compounds containing methylphosphorus groups the state of development of industrially interesting processes is also outlined. In addition, the synthesis of a few bifunctional phosphorus-carbon compounds which can be employed as comonomers in the production of polymers is described.     

Carbon film growth on iron substrates by a CVD method

Carbon film coatings have been produced by a hot‐wall chemical vapor deposition (CVD) method under moderate conditions from pyrolysis of a mixture of propane and argon on an Fe(110) substrate at temperatures of 800–900 °C for different deposition times. The effects of temperature and reaction time on the growth of the carbon films were studied. Field‐emission scanning electron microscopy (FESEM), Raman microscopy, Auger electron spectroscopy (AES) and x‐ray diffraction methods have been performed to study the surface morphologies, growth features and microstructures of the carbon film coatings. The FESEM analyses indicated that carbon films on an Fe substrate consisted of flat‐layer and filamentous morphologies. Raman and AES analyses showed that the carbon initially was crystalline but the degree of disorder in the top layer of the carbon film increased with increasing deposition temperature. High‐resolution transmission electron microscopy studies are also in agreement with Raman results. The same trend was observed when the deposition time was increased from 5 to 30 min. Copyright © 2005 John Wiley & Sons, Ltd.     

Catalytic oxidation of CO,hydrocarbons, and ethyl acetate over perovskite-type complex oxides

The catalytic activity of M^IM^IIO₃] perovskite-type complex oxides (M^I = La, Y, Nd, Yb; M^II = Co, Mn, Ni) in the oxidation of CO, propylene, benzene, ethylbenzene,o-xylene, and ethyl acetate was investigated. The Co-containing catalysts were shown to be more active in the oxidation than the Mn-containing catalysts. A relationship between the catalytic and adsorption properties was established.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 602–605, April, 1994.     

A study of methylation of inorganic tin by iodomethane in an aquatic environment with 13C carbon isotope tracer technique

The methylation of tin(II) [Sn(II)] by iodomethane (CH₃I) under environmental conditions has been further demonstrated by a ¹³C carbon isotope tracer method. Methylation products are mainly monomethyltin, and very small amounts of dimethyltin. The reaction of Sn(II) and CH₃I was investigated at pH 2, 4, 6, 8, 10 and salinity (S) 8, 15, 22, 28, 35%; it has been found the reaction was affected by pH and salinity, the tin methylation activity being highest at about pH 6 and S = 28% . The methylation reaction is first-order for both CH₃I and Sn(II), and the rate equation has been obtained as follows: .     

Inorganic—Organic Hybrid 18—Molybdodiphosphate Nanoparticles Bullk—modified Carbon Paste Electrode and Its Electrocatalysis

A kind of inorganic‐organic hybrid 18‐molybdodiphosphate nanoparticles ([(C₄H₉)₄N]₆P₂Mo₁₈Q₆₂·4H₂O) was firstly used as a bulk‐modifier to fabricate a three‐dimensional chemically modified carbon paste electrode (CPE) by direct mixing. The electrochemical behavior of the solid nanoparticles dispersed in the CPE in acidic aqueous solution was characterized by cyclic and square‐wave voltammetry. The hybrid 18‐molybdodiphosphate nanoparticles bulk‐modified CPE (MNP‐CPE) displayed a high electrocatalytic activity towards the reduction of nitrite, bromate and hydrogen peroxide. The remarkable advantages of the MNP‐CPE over the traditional polyoxometalates‐modified electrodes are their excellent reproducibility of surface‐renewal and high stability owing to the insolubility of the hybrid 18‐molybdodiphosphate nanoparticles.     

Study of Factors Affecting the Performance of Voltammetric Copper Sensors Based on Gly‐Gly‐His Modified Glassy Carbon and Gold Electrodes

This paper reports a study of the factors affecting the analytical performance of gold and glassy carbon electrodes modified with the tripeptide Gly‐Gly‐His for the detection of copper ions. Gly‐Gly‐His is attached to a glassy carbon (GC) surface modified with 4‐carboxyphenyl moieties or a gold surface modified with 3‐mercaptopropionic acid by the reaction of the N‐terminal amine group of the peptide with the carboxylic acid groups of the monolayer via carbodiimide activation. X‐ray photoelectron spectroscopy was used to characterize the steps in the biosensor fabrication. It was found that the analytical performance of a sensor prepared with Gly‐Gly‐His on a GC electrode was similar to that on a gold electrode under the same conditions. The performance was greatly enhanced at higher temperature, no added salt during copper accumulation and longer accumulation time within a pH range of 7–9. Interference studies and investigations of stability of the Gly‐Gly‐His sensor are reported. Analysis of natural water samples show that the sensors measure only copper ions that can complex at the sensor surface. Strongly complexed copper in natural water is not measured. Despite greater stability of diazonium salt derived monolayers on carbon surfaces compared with alkanethiols self‐assembled monolayers on gold, the stability of the sensors was essentially the same regardless of the modification procedure.