全文获取类型
收费全文 | 941篇 |
免费 | 147篇 |
国内免费 | 15篇 |
专业分类
化学 | 1093篇 |
晶体学 | 1篇 |
物理学 | 9篇 |
出版年
2024年 | 1篇 |
2023年 | 7篇 |
2022年 | 23篇 |
2021年 | 27篇 |
2020年 | 33篇 |
2019年 | 32篇 |
2018年 | 16篇 |
2017年 | 14篇 |
2016年 | 39篇 |
2015年 | 53篇 |
2014年 | 51篇 |
2013年 | 57篇 |
2012年 | 45篇 |
2011年 | 46篇 |
2010年 | 34篇 |
2009年 | 48篇 |
2008年 | 49篇 |
2007年 | 41篇 |
2006年 | 52篇 |
2005年 | 54篇 |
2004年 | 49篇 |
2003年 | 64篇 |
2002年 | 191篇 |
2001年 | 14篇 |
2000年 | 8篇 |
1999年 | 3篇 |
1997年 | 16篇 |
1996年 | 8篇 |
1995年 | 12篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有1103条查询结果,搜索用时 109 毫秒
71.
Five-coordinate phenylsilicates are formed from the reaction of trimethoxy(phenyl)silane with monosaccharides in methanol in the presence of a stoichiometric amount of base. Five complexes have been isolated and characterized with two ketoses and three aldopentoses. The silicon central atom in [K([18]crown-6)][PhSi(beta-D-Fruf 2,3H-2)2].MeOH (1, Fru=fructose) is part of two chelate rings, with the ligands being beta-D-fructofuranose-O2,O3 dianions. The beta-furanose isomer is best suited for silicon ligation because it exhibits a torsion angle close to 0 degrees for the most acidic diol function, thus assuring a flat chelate ring. The same structural principles are also found in [K([18]crown-6)][PhSi(beta-D-Araf1,2H-2)2].2 MeOH (2, Ara=arabinose), [K([18]crown-6)][PhSi(alpha-D-Ribf1,2H-2)2] (3, Rib=ribose), [K([18]crown-6)][PhSi(alpha-D-Xylf1,2H-2)2]. acetone (4, Xyl=xylose), and [K([18]crown-6)][PhSi(alpha-D-Rulf2,3H-2)2] (5, Rul=ribulose). 相似文献
72.
A new efficient system for transporting saccharides through a liquid membrane has been constructed. The transport rates of saccharides were accelerated greatly by the cyclodextrin dimer 2; by contrast, the corresponding cyclodextrin monomer 1 was not effective at mediating saccharide transport. The transport rate of D-ribose through a chloroform liquid membrane was 17 times faster when the cyclodextrin dimer 2 was used as the transporter than when the cyclodextrin monomer 1 was used. Similarly the transport rate of methyl D-galactopyranoside was 16 times faster by 2 than by 1. 相似文献
73.
74.
75.
76.
77.
Daniela M. Fidalgo Adriana A. Kolender Oscar Varela 《Journal of polymer science. Part A, Polymer chemistry》2013,51(2):463-470
Novel linear carbohydrate‐derived [m,n]‐polyurethanes are successfully prepared using D ‐mannitol as renewable and low cost starting material. The key comonomer, 1,6‐di‐O‐phenylcarbonyl‐2,3,4,5‐tetra‐O‐methyl‐D ‐mannitol is polymerized with a diamine synthesized from D ‐mannitol or with alkylenediamines. These polymerization reactions afford, respectively, a [6,6]‐polyurethane entirely based on a carbohydrate derivative or [m,n]‐polyurethanes constituted by a poly‐O‐methyl substituted unit alternating with a polymethylene chain. All these polymers are stereoregular, as result of the C2 axis of symmetry of mannitol. The optically active polyurethanes are characterized by standard methods (FTIR, RMN, GPC, TGA, and DSC). Thus, GPC analysis reveals weight‐average molecular weights between 18,000 and 25,000 Da. Thermal studies (DSC) indicate that the polymers obtained are amorphous materials with Tg values dependent on the structure and chain length of the diamine constituent. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
78.
Ahmed Al‐Harrasi Dr. Fabian Pfrengle Dipl.‐Chem. Vladimir Prisyazhnyuk Dr. Shahla Yekta Dr. Peter Koóš Dr. Hans‐Ulrich Reissig Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(43):11632-11641
1,3‐Dioxolanyl‐substituted 1,2‐oxazines, such as syn‐ 1 and anti‐ 1 , rearrange under Lewis acidic conditions to provide bicyclic products 2 – 5 . Subsequent reductive transformations afforded enantiopure 3‐aminopyran derivatives such as 7 and 9 or their protected diastereomers 16 and 18 , which can be regarded as carbohydrate mimetics. An alternative sequence of transformations including selective oxidation of the primary hydroxyl groups in 21 and 24 led to two protected β‐amino acid derivatives with carbohydrate‐like backbone (sugar amino acids). Treatment of bicyclic ester 23 with samarium diiodide cleaved the N? O bond and furnished the unusual β‐lactam 27 in excellent yield. Alternatively, γ‐amino acid derivative 29 was efficiently prepared in a few steps. Fairly simple transformations gave azides 32 and 35 or alkyne 30 which are suitable substrates for the construction of oligosaccharide mimetics such as 34 by copper iodide catalyzed cycloadditions. With this report we demonstrate that enantiopure rearrangement products 2 – 5 are protected precursors of a variety of polyfunctionalized pyran derivatives with great potential for chemical biology. 相似文献
79.