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41.
Owing to high-energy density of rechargeable lithium-ion batteries (LIBs), they have been investigated as an efficient electrochemical power sources for various energy applications. High theoretical capacities of tin oxide (SnO2) anodes have led us a path to meet the ever-growing demands in the development of high-performance electrode materials for LIBs. In this paper, a facile approach is described for the synthesis of porous low-dimensional nanoparticles and nanorods of SnO2 for application in LIBs with the help of Tween-80 as a surfactant. The SnO2 samples synthesized at different reaction temperatures produced porous nanoparticles and nanorods with average diameters of ~7–10 nm and ~70–110 nm, respectively. The SnO2 nanoparticle electrodes exhibit a high reversible charge capacity of 641.1 mAh/g at 200 mA/g after 50 cycles, and a capacity of 340 mAh/g even at a high current density of 1000 mA/g during the rate tests, whereas the porous nanorod electrodes delivers only 526.3 mAh/g at 200 mA/g after 50 cycles and 309.4 mAh/g at 1000 mA/g. It is believed that finer sized SnO2 nanoparticles are much more favorable to trap more Li+ ion during electrochemical cycling, resulting in a large irreversible capacity. In contrast, rapid capacity fading was observed for the porous nanorods, which is the result of their pulverization resulting from repeated cycling. 相似文献
42.
通过溶胶-凝胶和高温固相掺杂反应可控合成了形貌均匀、结晶性好的尖晶石型LiMn1.9Al0.1O3.95F0.05正极材料,探究了Al部分取代Mn、F部分取代O后对结构的影响,测试并比较了电极材料的倍率性能和循环充放电性能. 结果表明,尖晶石型LiMn1.9Al0.1O3.95F0.05和LiMn2O4有同样的晶型,但电极较传统的LiMn2O4电极倍率稳定性有显著提高. 在连续混合(如0.1C、0.5C和1C)充放电150次后,LiMn1.9Al0.1O3.95F0.05电极的容量仍能保持90%以上. 相似文献
43.
20单元双压电片变形镜对Zernike像差空间拟合能力的实验研究 总被引:1,自引:1,他引:0
利用20单元双压电片变形镜和13×13阵列哈特曼波前传感器所构成的闭环自适应光学系统,实验测试了双压电片变形镜对3~20项静态Zernike像差的空间校正能力,并将实验结果与仿真计算结果进行了对比.最后分析了哈特曼传感器与双压电片变形镜之间的对准误差对实验结果的影响.研究表明,除了少数几项外,双压电片变形镜对3~20项Zernike像差的拟合误差都小于0.5,各项Zernike仿真和实验结果之差平均小于0.1.计算表明,与严格对准的理想情况相比,双压电片变形镜对3~20项Zernike像差中大多数项的拟合误差都随着失配程度的增加而增大,对准精度对于高阶像差拟合效果的影响尤其严重. 相似文献
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Thyreostatic compounds could be illegally administered to animals in order to obtain a weight gain due to a higher retention of water in the edible tissue and the gastro-intestinal tract. In the European Union their use for animal production is banned since 1981. Recently a highly sensitive method exploiting the determination of thyreostats with 3-iodobenzylbromide prior to purification to determine thyreostats in urine and other matrices was reported. For the first time, the UPLC instrumentation was used to separate the 3-iodobenzyl derivatives of various thyreostats. The deuterated internal standards tapazole-d3 and propylthiouracil-d5 were for the first time used for the quantification of tapazole, thiouracil, methylthiouracil, propylthiouracil, phenylthiouracil and mercaptobenzimidazole. The confirmative quantitative liquid chromatographic tandem mass spectrometric (LC–MS/MS) method was validated according to Commission Decision 2002/657/EC. The decision limit (CCα) and the detection capability (CCβ) were found to be for all compounds below the recommended value of 10 μg kg−1. 相似文献
47.
Over the years, numerous process capability indices (PCIs) have been proposed to the manufacturing industry to provide numerical measures of process performance. Most research efforts have focused on developing and investigating PCIs that assess process capability by precise measurements of output quality. However, real observations of continuous quantities are not precise numbers; in practice, they are more or less imprecise. Since observations of continuous random variables are imprecise the values of related test statistics become imprecise. Therefore, decision rules for statistical tests have to be adapted to this situation. This article presents a set of confidence intervals that produces triangular fuzzy numbers for the estimation of Cpk index using Buckley’s approach with some modification. Additionally, a three-decision testing rule and step-by-step procedure are developed to assess process performance based on fuzzy critical values and fuzzy p-values. This concept is also illustrated with an example for testing process performance. 相似文献
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随着互联网+战略的深入推进,了解不同产业内信息技术能力与产业绩效之间的协调发展情况,对于系统把握我国的信息化发展水平,分类制定有效产业政策具有重要意义。有别于以往采用宏观产业数据,重点评价工业化与信息化融合度,本文主要基于2008~2015年的上市公司的微观数据,采用耦合协调模型,分类测度四大类产业的IT能力与产业绩效的耦合协调度。研究发现:总体上看我国的产业IT能力与产业绩效之间存在中高度耦合关系,但耦合质量不高,耦合协调度处于中低水平,呈现逐渐上升趋势;此外,我国的不同的产业之间的耦合协调度发展趋势存在差异性,本文进一步分析了该差异的存在的原因,并提出政策建议。 相似文献
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认知心理学理论认为,人的知识与能力的获得实际上就是信息的加工过程,也即是学习者在能力习得过程的对已有经验的刺激反应过程.大学实验不仅培养学生的动手能力,它也是孕育创新能力的培养课程.实验能力与思维方式、年龄、智商、性别、知识积累和培养方式等诸多因素相关,思维方式与思维路径绝对创新力,反之,借助于创新性实验教学可以提高学生的创造性思维. 相似文献