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81.
Lankshear MD Evans NH Bayly SR Beer PD 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(14):3861-3870
We present the rational design and anion-binding properties of the first anion-templated pseudorotaxanes and catenanes in which the "wheel" component is provided by a calix[4]arene macrobicyclic unit. The designs and syntheses of two new calix[4]arene macrobicycles, 2 and 3, are presented, and the abilities of these new species both to bind anions and to undergo anion-dependent pseudorotaxane formation are demonstrated. Furthermore, it is shown that performing ring-closing metathesis reactions on some of these pseudorotaxane assemblies gives novel catenane species 14 and 15, in which the yield of interlocked molecule obtained is critically dependent on the presence of a suitable anion template, namely, chloride. Exchange of the chloride anion in catenane 14 a for hexafluorophosphate gives catenane 14 d, which contains a unique anion-binding domain defined by the permanently interlocked hydrogen-bond-donating calix[4]arene macrobicycle and pyridinium macrocycle fragments. The anion-binding properties of this domain are presented, and shown to differ from non-interlocked components. 相似文献
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Harm-Anton Klok Peter Eibeck Harold Gankema Ren P. Nieuwhof Martin Mller David N. Reinhoudt 《Journal of Polymer Science.Polymer Physics》1998,36(2):383-394
A one-step procedure for the preparation of ion-selective membranes is described. The method employs the thermally induced gel crystallization of ultrahigh molecular weight poly(ethylene) (UHMW-PE) from a dilute xylene solution. After evaporation of the xylene, a microporous UHMW-PE film remains, which can serve as the support for liquid and polymeric ion-selective membranes. The addition of a membrane solvent and suitable receptor molecules to the xylene solution allows a one-step incorporation of these membrane components into the UHMW-PE support. The influence of the preparation conditions of the UHMW-PE support on the rates of the p-tert-butylcalix[4]arene tetraethylester-mediated transport of NaClO4 was studied. Two concepts to improve the life-time of the membranes are introduced. In a first approach, the addition of photocrosslinkable nitril-substituted siloxane copolymers to the membrane phase has been evaluated. The enhanced viscosity of the membrane phase reduces leaching of carrier and solvent molecules from the membrane into the aqueous phases. In a second approach, the solvent is omitted and the membrane-phase merely consists of a benzo-15-crown-5 or calix[4]arene modified siloxane-copolymer, which is substituted to such a degree that ion transport no longer has to take place via diffusion of host–guest complexes but by jumping of the cations from one fixed carrier to a neighboring carrier. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36 : 383–394, 1998 相似文献
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