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91.
Zhijun Yi Tingyu LiuQiren Zhang Yuanyuan Sun 《Journal of Electron Spectroscopy and Related Phenomena》2006
The electronic structures of PbWO4 crystals containing F type color centers with the lattice structure optimized are studied within the framework of the fully relativistic self-consistent Direc–Slater theory, using a numerically discrete variational (DV-Xα) method. The calculated results show that F and F+ centers have donor energy level in forbidden band. Their optical transition energy are 1.84 eV, 2.21 eV, respectively, which corresponds to the 680 nm, 550 nm absorption bands. It predicts that the 680 nm, 550 nm absorption bands originate form the F and F+ centers in PbWO4 crystals. 相似文献
92.
Jin Hu Gang Liu Jixiu Zhang Lingchao Kong Weidong Fei 《Applied Surface Science》2006,253(5):2792-2795
The microstructure of a laser treated Al18B4O33w/2024Al composite has been investigated using transmission electron microscope (TEM), low-angle (glancing angle) X-ray diffraction (XRD) techniques. Various surface microstructures were observed in the laser treated composite. The Al18B4O33 whisker on the surface of the composite was decomposed during laser surface melting, various decomposition products were studied in the laser treated composite. Eutectic phases and the precipitation in the matrix of the composite with laser-treated were observed. The main phases detected in the molten zone were aluminum and decomposition products Al2O3. The effect of laser treatment on the hardness of the composite was also examined. A surface hardness of 400 Hv was noted. 相似文献
93.
94.
Hongrui Zhang Mingju Chao Mingyi Gao Liwen Zhang Jianquan Yao 《Optics & Laser Technology》2003,35(6):573-449
A fiber-coupled diode-single-end-pumped Nd:YVO4 laser with an Nd:YVO4 crystal of 0.3 at% doping concentration and 3×3×10 mm3 dimensions was reported. 14.850 W of continuous-wave output power in an M2 factor of 1.12 was obtained under pump power of 27.365 W, with an optical conversion efficiency of 60.49%, and a slope efficiency of 64.5%. 相似文献
95.
96.
O. N. Lyubenko I. G. Ermolenko L. D. Patsenker Krasovitskii I. N. Tur 《Chemistry of Heterocyclic Compounds》2003,39(4):511-519
The behavior of dimethylamino-substituted 7H-benzo[de]pyrazolo[5,1-a]isoquinoline-7-ones, synthesized for the first time, under conditions of the Vilsmeier-Haack reaction. It has been shown that, on heating with POCl3 and DMF, they are converted by electrophilic substitution at the position ortho to the dimethylamino group, followed by cyclization of the iminium adduct to a quinazolinium salt. When an acetyl group is present, the Arnold reaction, leading to the formation of a chloroaryl, accompanies the heterocyclization. The rates and proportion of the reaction products depend on the position of the dimethyl groups relative to the pyrazole ring. 相似文献
97.
To find an effective extraction and removal method for palladium(II), which is one of the main fission products from an acidic nuclear spent fuel solution, the extraction behavior of palladium(II) from a nitric acid medium by an acidic chelating extractant, 1-phenyl-3-methyl-4-trifluoroacetylpyrazolone-5-one (HPMTP) and a tertiary amine of high molecular weight, tri-n-octylamine (TOA), has been studied by spectrophotometry. A noticeable antagonistic extraction effect was observed in the extraction system under the given conditions. To understand this phenomenon, a preliminary investigation was performed to explain the mechanism of this reaction. According to the theory of corresponding solutions (TCS), the association reaction between HPMTP and TOA is proposed in the organic phase. An associated species, HPMTP·TOA, formed through hydrogen bonding in a chloroform medium might be the main reason why an antagonistic extraction effect occurred. The association constant between HPMTP and TOA was calculated to be 2.86±0.05. 相似文献
98.
继续作者最近的研究,用所谓的Hankel向量方法建立S[a,b]函数类中带边界插值数据的Nevanlinna-Pick插值问题与[a,b]上的某种带约束条件的Hausdorff矩量问题之间解集之间明确的一一对应关系.通过N[a,b]函数类与S[a,b]函数类之间的联系,从而由BNP(N[a,b])问题的可解性准则和解的参数化描述获得BNP(S[a,b)问题的可解性准则和解的参数化表示. 相似文献
99.
Giorgio AbbiatiAntonio Arcadi Egle BeccalliElisabetta Rossi 《Tetrahedron letters》2003,44(28):5331-5334
Intramolecular cyclization of 2-acyl-1-propargyl-1H-indoles in the presence of ammonia provides an easy entry to pyrazino[1,2-a]indole nucleus. 相似文献
100.
HAOJie LIXing 《声学学报:英文版》2003,22(1):77-85
In a syllable-based speaker-independent Chinese continuous speech recognition system based on classical Hidden Markov Model(HMM),a Bayesian approach of keyword confidence estimation is studied,which utilizes both acoustic layer scores and syllable-based statistical language model(LM) score.The Maximum a posteriori(MAP) confidence measure is proposed,and the forward-backward algorithm calculating the MAP confidence scores is deduced.The performance of the MAP confidence measure is evaluated in keyword spotting application and the experiment results show that the MAP confidence scores provide high discriminability for keyword candidates.Furthermore,the MAP confidence measure can be applied to various speech recognition applications. 相似文献