9-Bromomethylacridine a Novel Fluorescent Labeling Reagent of Carboxylic Group for HPLC

Abstract

9-Bromomethylacridine (9-Br · Ma) gave blue fluorescent 9-acridinylmethyl (9-AM) esters by the reaction with carboxylic acids. The reactions were performed simply by mixing the 9-Br · Ma, tetraethylammonium carbonate (TEA C) and carboxylic acids in N,N-dimethylformamide at room temperature. The 9-AM derivatives of fifteen kinds of fatty acids were separated and detected with high performance liquid chromatography. By this method, fatty acids could be determined at levels down to either pmol order by fluorometry or 10 pmol order by UV method. After saponification, those in triacylglycerols were also determined. When four kinds of fatty acids were added to a butter, their recoveries were 92–101%. The coefficient of variation of myristate as a representative was 2.5% (42.8 pmol, n=6).     

Noncommutative differential geometry on the quantum SU(2), I: An algebraic viewpoint

We compute the cyclic homology of the coordinate ring A(SL_q(2)) of the quantum algebraic group SL _q (2). We observe a degeneration of the noncommutative de Rham complex. The results are also verified from the point of view of Connes' noncommutative differential geometry.     

Symmetry of the Barochronous Motions of a Gas

We study the system of nonlinear differential equations which expresses the constancy of the algebraic invariants of the Jacobian matrix for smooth vector fields in three-dimensional space. This system is equivalent to the equations of gas dynamics which describe the barochronous motions of a gas (the pressure and density depend only on the time). We present the results of computation of the admissible local Lie group and construction of the general solution of the system. We mention a few new problems that arise here.     

Designs and Representation of the Symmetric Group

We study (generalized) designs supported by words of given composition. We characterize them in terms of orthogonality relations with Specht modules; we define some zonal functions for the symmetric group and we give a closed formula for them, indexed on ordered pair of semi-standard generalized tableaux: Hahn polynomials are a particular case. We derive an algorithm to test if a set is a design. We use it to search designs in some ternary self-dual codes.     

Equivariant Spectral Triples on the Quantum SU(2) Group

We characterize all equivariant odd spectral triples for the quantum SU(2) group acting on its L ₂-space and having a nontrivial Chern character. It is shown that the dimension of an equivariant spectral triple is at least three, and given any element of the K-homology group of SU_q(2), there is an equivariant odd spectral triple of dimension 3 inducing that element. The method employed to get equivariant spectral triples in the quantum case is then used for classical SU(2), and we prove that for p < 4, there does not exist any equivariant spectral triple with nontrivial K-homology class and dimension p acting on the L ₂-space.The first author would like to acknowledge support from the National Board of Higher Mathematics, India.     

Recovery of Band-Limited Functions on Locally Compact Abelian Groups from Irregular Samples

Using the techniques of approximation and factorization of convolution operators we study the problem of irregular sampling of band-limited functions on a locally compact Abelian group G. The results of this paper relate to earlier work by Feichtinger and Gröchenig in a similar way as Kluvánek's work published in 1969 relates to the classical Shannon Sampling Theorem. Generally speaking we claim that reconstruction is possible as long as there is sufficient high sampling density. Moreover, the iterative reconstruction algorithms apply simultaneously to families of Banach spaces.     

Equivalence Bimodule Between Non-Commutative Tori

The non-commutative torus C ^*(ⁿ,) is realized as the C*-algebra of sections of a locally trivial C*-algebra bundle over S with fibres isomorphic to C ^*n/S, ₁) for a totally skew multiplier ₁ on ⁿ/S. D. Poguntke [9] proved that A is stably isomorphic to C(S) C(^*( Zⁿ/S, ₁) C(S) A M_kl( C) for a simple non-commutative torus A and an integer kl. It is well-known that a stable isomorphism of two separable C*-algebras is equivalent to the existence of equivalence bimodule between them. We construct an A-C(S) A-equivalence bimodule.     

Galois Stability, Integrality and Realization Fields for Representations of Finite Abelian Groups

For a given field F of characteristic 0 we consider a normal extension E/F of finite degree d and finite Abelian subgroups GGL _n (E) of a given exponent t. We assume that G is stable under the natural action of the Galois group of E/F and consider the fields E=F(G) that are obtained via adjoining all matrix coefficients of all matrices gG to F. It is proved that under some reasonable restrictions for n, any E can be realized as F(G), while if all coefficients of matrices in G are algebraic integers, there are only finitely many fields E=F(G) for prescribed integers n and t or prescribed n and d.     

On Central Endomorphisms of a Group with Operators

Let G be a group with a set of operators such that Z(G) is -admissible. Central -automorphisms occur in the Krull-Remak-Schmidt Theorem. We discuss the existence of a central -endomorphism of G that is not an automorphism.2000 Mathematics Subject Classification: 20E36     

All Subvarieties of ℒpq Have Finite Bases of Identities

We consider the varieties of lattice ordered groups with the identity of commutation of the nth powers of elements. We establish that every such l-variety with n=pq, where p and q are distinct prime numbers, has a finite basis of identities.