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71.
72.
Fusion-evaporation cross-sections for the α-induced reactions upon197Au,193Ir,191Ir,185Re,181Ta,121Sb and69Ga nuclei at bombarding energies near the Coulomb barrier have been measured by off-line observation of the γ-rays emitted
in the radioactive decay of the residual nuclei using stacked foil technique. The total fusion cross-section for the systems
have been compared with simple statistical model calculations using the code ALICE/91 as well as with the coupled channel
calculations that include the β2 and ν4 slatic deformations and dynamic couplings of the vibrational/rotational states of the target and the projet tile using the
code CCDEF. 相似文献
73.
一类Narcissistic反应过渡态的优化 总被引:1,自引:0,他引:1
我们对一类narcissistic 反应XCH_2-CH_2Y→[过渡态TS]→YCH_2—CH_2X (1)进行了研究,结果表明其过渡态能在对称性限制下由能量极小化方法较容易地给出. 采用IMSPAK分子轨道从头算程序,在IBM VM/370计算机系统上用STO—3G极小基组以平衡几何构型的能量梯度优化方法,在对称性限制下对反应(1)的几种反应体系的过渡态构型进行了优化,其结果列于表1. 相似文献
74.
采用固相反应合成了四羟基苯基卟啉与与Fe^2+,Co^2+金属离子的配合物,在室温下,将其与分子O2作用,提纯后得到两种固态氧合配合物.通过元素分析、红外光谱(IR)、核磁共振氢谱(^1HNMR)、电导、热分析(TG/DTA)、紫外光谱(UV)等测试手段确定了氧合配合物的组成为[Co·THPP·O2](NO3)2·2H2O、[Fe·THPP·O2]Cl2·2H2O],可知1mol配合物吸收了1molO2,采用失重法测定了氧合配合物中的配位氧,确定1mol金属配合物吸收1molO2形成超氧配合物. 相似文献
75.
Several Pd-catalyzed reactions were explored to further functionalize the bromo-substituted 4-amino-1,2,4,5-tetrahydro-2-benzazepin-3-one scaffold (Aba). We report in this paper suitable reaction conditions for Suzuki, Buchwald-Hartwig, and Heck reactions. The substitution pattern of the starting aminobenzazepinone turned out to be crucial for the success of these transition metal-catalyzed reactions, which often required modifications of standard literature procedures. The Pd-catalyzed methods provide access to novel substitution patterns of the Aba scaffold. 相似文献
76.
Bahattin Gümgüm Nermin Biricik Feyyaz Durap Ismail Özdemir Nevin Gürbüz Wee Han Ang Paul J. Dyson 《应用有机金属化学》2007,21(8):711-715
Palladium(II) complexes with N,N‐bis(diphenylphosphino)aniline ligands catalyse the Heck reaction between styrene and aryl bromides, affording stilbenes in good yield. The structures of two of the complexes used as pre‐catalysts have been determined by single‐crystal X‐ray diffraction. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
77.
78.
《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(1):130-137
We have shown previously that iodosylbenzene–iron(III ) porphyrin intermediates ( 2 ) are generated in the reactions of oxoiron(IV ) porphyrin π‐cation radicals ( 1 ) and iodobenzene (PhI), that 1 and 2 are at equilibrium in the presence of PhI, and that the epoxidation of olefins by 2 affords high yields of epoxide products. In the present work, we report detailed mechanistic studies on the nature of the equilibrium between 1 and 2 in the presence of iodoarenes (ArI), the determination of reactive species responsible for olefin epoxidation when two intermediates (i.e., 1 and 2 ) are present in a reaction solution, and the fast oxygen exchange between 1 and H218O in the presence of ArI. In the first part, we have provided strong evidence that 1 and 2 are indeed at equilibrium and that the equilibrium is controlled by factors such as the electronic nature of iron porphyrins, the electron richness of ArI, and the concentration of ArI. Secondly, we have demonstrated that 1 is the sole active oxidant in olefin epoxidation when 1 and 2 are present concurrently in a reaction solution. Finally, we have shown that the presence of ArI in a reaction solution containing 1 and H218O facilitates the oxygen exchange between the oxo group of 1 and H218O and that the oxygen exchange is markedly influenced by factors such as ArI incubation time, the amounts of ArI and H218O used, and the electronic nature of ArI. The latter results are rationalized by the formation of an undetectable amount of 2 from the reaction of 1 and ArI through equilibrium that leads to a fast oxygen exchange between 2 and H218O. 相似文献
79.
The kinetics of reactions occurring at the gas-exposed surfaces of charged mixed ionic electronic conductors (MIECs) are examined
from theoretical first principles. Analysis based on the classical electrochemical potential-transition state theory model
reveals that the nature of the reactions is electrochemical in general. However, the influence of the surface potential on
the reaction rate is opposite for adsorption and incorporation reactions. Two-dimensional finite volume models of an MIEC
as working electrode in a half-cell configuration are presented. The results for a simple, two-step reduction process show
that the effect of the surface potential on the rate of reactions is minimal for incorporation-limited reactions but more
influential for adsorption-limited reactions.
An erratum to this article is available at . 相似文献
80.
The N-carboethoxy precursor to (±)-tecomanine has been prepared in 11 steps from 2-methyl-1-buten-3-yne. The key step, Pauson-Khand cyclization of a methylated 5-aza-6-nonen-1-yne succeeds, but only in low yield, a consequence of the dialkyl substitution about the azaenyne framework. Nevertheless, the overall sequence to that point is one of the more efficient to be described. 相似文献