我国活性氧化镁生产工艺研究进展

活性氧化镁是一种高附加值的化工原料,广泛应用于各种化工生产中。重点归纳总结了我国活性氧化镁的生产工艺,内容主要包括固体矿石法和液态镁卤水法,并指出了未来的主要研究方向。     

Antitumor Potential of Annona muricata Linn. An Edible and Medicinal Plant in Mexico: In Vitro,In Vivo,and Toxicological Studies

Annona muricata (Am) is a plant used in traditional Mexican medicine to treat cancer. In this study, ethanol extracts of Am collected in Acapulco and Tecpan from Guerrero state were evaluated orally on Balb/c mice inoculated with 4T1 cells, for cytotoxic activity (CA) on 4T1 cells, in brine shrimp lethality assay (BSLA), and for acute oral toxicity in mice. In addition, ethanol extracts were subjected to high-performance liquid chromatography (HPLC) with diode array detection. Results showed that the extracts collected in December in Acapulco (AcDe) and Tecpan (TeDe) exhibited the most significant antitumor and cytotoxic activity. In the BSLA, the most important effect was observed in the extracts from Acapulco and Tecpan collected in June (AcJu) and August (TeAg), respectively. The samples from Acapulco (AcJu, and AcAg) and Tecpan (TeJu and TeAg) showed the highest toxicity. The analysis of the extracts, AcDe and TeDe, by HPLC revealed that flavonoids, rutin, narcissin, and nicotinflorin were the major components. These findings suggest that extracts from Am collected in Acapulco and Tecpan in the month of December may be an important source to obtain flavonoid glycosides with anticancer potential specifically against breast cancer. This also supports the use of Am to treat cancer in Mexican traditional medicine.     

盐卤硼酸盐化学——Ⅲ.盐卤在动态蒸发条件下硼酸镁的极限溶解度

首先将含硼盐卤日晒蒸发到不同浓度,分别取硫酸镁析出阶段卤水和水氯镁石析出阶段卤水加入芒硝使全部回溶。利用硫酸钠和氯化镁在水溶液中存在交互反应,将芒硝回溶后卤水进行天然蒸发浓缩到硼酸盐开始结晶析出,测得盐卤在动态蒸发过程中硼酸镁的最大极限溶解度为7.36～7.50%MgB₄O₇,室温放置10年后的平衡溶解度为0.94%MgB₄O₇。     

MgO－B2O3－MgCl2－H2O体系与盐酸滴定反应的研究

ＭｇＯ－Ｂ２Ｏ３－ＭｇＣｌ２－Ｈ２Ｏ是含硼盐湖日晒浓缩盐卤的典型体系，它与盐酸反应生成硼酸，是从天然浓缩盐卤中制取硼酸的工艺基础，以量热滴定法和ＰＨ滴定法研究该反应，结果表明，析出硼酸的反应分两步进行；合成盐卤中硼酸盐可用ＭｇＢ２ｎＯ３Ｎ＋１（ｎ＝１，２，３）综合统计形式来表示；天然浓缩盐卤中硼酸盐可以用四硼酸镁的统计形式进行表示。     

高矿化度水体样品中痕量砷形态分析方法研究进展

砷污染物是水体环境中重点优先监测的污染物之一。归纳总结了近年来高矿化度水体系中痕量砷的测定方法研究进展,内容包括样品的处理（稀释、预富集和基体分离）分析,指出了高矿化度水体系中不同形态砷分析的发展方向。     

Li2SO4-Na2SO4-H2O和Li2SO4- K2SO4-H2O溶液的体积性质

本文用高精度数字式振荡管密度计测定了288K至318K温度范围内Li₂SO₄ + Na₂SO₄ + H₂O和 Li₂SO₄ + K₂SO₄ + H₂O三元体系的密度。混合溶液的离子强度范围从0.1到4.5 mol.kg_–1,混合溶液中Na₂SO₄和K₂SO₄的离子强度分数为0.2,0.4,0.6和0.8。用密度实验值拟合得到了不同温度下Pitzer离子相互作用模型混合参数θ_V和 ψ_V,模型的计算值与实验值的偏差在±0.002 g.cm_–3以内。用Pitzer模型计算了不同离子强度下三元体系的混合体积。     

Seepage-Diffusion Model of Brine Migration in Inhomogeneous Aquifers

A new phenomenological mathematical model of the propagation of high- and low-salinity solutions through inhomogeneous aquifers is proposed. The model consists of interrelated equations of two-phase flow and diffusive mass transfer through a porous medium in a region with a traveling boundary. Features of different contamination scenarios of are analyzed with reference to particular examples.     

Saltwater Upconing and Decay Beneath a Well Pumping Above an Interface Zone

Saltwater, or brine, underlies freshwater in many aquifers, with a transition zone separating them. Pumping freshwater by a well located above the transition zone produces upconing of the latter, eventually salinizing the pumped water, forcing shut-off. Following the well’s shut-off, the upconed saltwater mound undergoes decay, tending to return to the pre-pumping regime. The FEAS code is used for the simulation of coupled density-dependent flow and salt transport involved in the upconing–decay process. In this code, the flow equation is solved by the Galerkin finite element method (FEM), while the advective–dispersive salt transport equation is solved in the Eulerian–Lagrangian framework. The code does not suffer from the instability constraint on the Peclet number. The code is used to investigate the transient upconing–decay process in an axially symmetric system and to discover how the process is affected by two major factors: the density difference factor (DDF) and the dispersivities. Simulation results show that under certain conditions, pumping essentially freshwater can be maintained for a certain time period, the length of which depends on the dispersivity values used. A recirculating flow cell may occur in the saltwater layer beneath the pumping well, widening the saltwater mound. The decay process is lengthy; it takes a long time for the upconed saltwater to migrate back to its original shape of a horizontal transition zone prior to pumping. However, the wider transition zone caused by hydrodynamic dispersion can never return to the initial one. This indicates that once a pumping well is abandoned because of high salinity, it can be reused for groundwater utilization only after a long time. It is also shown that the upconing–decay process is very sensitive to DDF, which, in our work, ranges from 0 (for an ideal tracer) to 0.2 (for brine). For a DDF of 0.025 (for seawater), local upconing occurs only for low iso-salinity surfaces, while those of high salt concentration remain stable after a short time. For an ideal tracer, all iso-salinity surfaces rise toward the pumping well, whereas for brine only iso-salinity surfaces of very low salinity upcone towards the pumping well. This may imply that the traditional finding that the sharp interface approximation is practically close to the 0.5 iso-salinity surface may not be true for a high DDF solution.     

Experimental design in the analysis of interferential effects for the determination of Sr in high Ca/Sr ratio brine by inductively coupled plasma atomic emission spectroscopy technique

The ICP-AES technique and experimental design were employed to precisely determine the content of strontium in high Ca/Sr ratio oil field brine of Qaidam basin (Qinghai province, western China). From the statistical analysis using six factor factorial, it was found that Ca²⁺ is the significant interfering element for the recovery of strontium. Accurate strontium content was derived by eliminating the interference contribution according to the influencing model. The experimental results indicate that, under optimal conditions, the ICP-AES method for strontium determination has low LOD and LOQ, and the precision and accuracy are good with the relatively standard deviation below 1% and recovery between 98.0%?～?105.0%.     

Two-phase brine mixtures in the geothermal context and the polymer flood model

Two-phase mixtures of hot brine and steam are important in geothermal reservoirs under exploitation. In a simple model, the flows are described by a parabolic equation for the pressure with a derivative coupling to a pair of wave equations for saturation and salt concentration. We show that the wave speed matrix for the hyperbolic part of the coupled system is formally identical to the corresponding matrix in the polymer flood model for oil recovery. For the class ofstrongly diffusive hot brine models, the identification is more than formal, so that the wave phenomena predicted for the polymer flood model will also be observed in geothermal reservoirs.Roman Symbols A,B coefficient matrices (5) - c(x,t) salt concentration (primary dependent variable) - C(p, s, c, q _t) wave speed matrix (6) - f source term (5) - g acceleration due to gravity (constant) - h _b(p, c) brine specific enthalpy - h _v(p) vapour specific enthalpy - j conservation flux (1) - k absolute permeability (constant) - k _b(s), k_v(s) relative permeabilities of the brine and vapour phases - K conductivity - p(x,t) pressure (primary dependent variable) - q volume flux (Darcy velocity) (3) - s(x,t) brine saturation (primary dependent variable) - t time (primary independent variable) - T=T _sat(p) saturation temperature - u _b(p, c) brine specific internal energy - u _m T rock matrix specific internal energy - u _v(p) vapour specific internal energy - U(x, t) shock velocity - x space (primary independent variable) Greek Symbols porosity (constant) - _b(p, c) brine dynamic viscosity - _v(p) vapour dynamic viscosity - (p, s, c) conservation density (1) - _b(p, c) brine density - _v(p) vapour density Suffixes b brine - m rock matrix - t total - v vapour - S salt - M mass - E energy