防覆冰涂层构建机理及制备

航空、通信、电力和运输设备的覆冰现象给人们的生产、生活带来许多不便,甚至引起重大经济损失,防覆冰涂层主要通过材料表面特殊物理化学性能与微相形貌来实现抗冰目的,这类材料需要兼具防结冰性和疏冰性,从延长结冰时间和降低冰的附着力两方面来减轻甚至消除冰雪积聚,是目前研究的热点。本文从防覆冰机理入手,深入探讨了防结冰性和疏冰性的影响因素,阐述了防覆冰涂层材料的设计与制备方面的最新进展,并对防覆冰涂层目前存在的问题与发展方向进行了分析和展望。     

Preparation and mechanical properties of bacterial cellulose nanocomposites loaded with silica nanoparticles

Bacterial cellulose (BC), which is produced by Gluconacetobacter xylinus (Ga. xylinus) in culture, is made up of a three-dimensional network of ribbon-shaped bundles of cellulose microfibrils. In the current studies, we used two processes to prepare nanocomposites of BC filled with silica particles. In Process I, Ga. xylinus was incubated in medium containing silica sol Snowtex 0 (ST 0, pH 2–4) or Snowtex 20 (ST 20, pH 9.5–10.0). The elastic modulus at 20 °C was improved by keeping the amount of silica in the nanocomposites below 4% when ST 20 was used and below 8.7% when ST 0 was used. This process allowed incorporation of 50% silica in BC. Inclusion of higher amounts of silica reduced the modulus at 20 °C and the strength of the nanocomposites below that of BC. X-ray diffraction measurements revealed that the silica particles disturb the formation of ribbon-shaped fibrils and affect the preferential orientation of the ( ) plane. We also produced BC-silica nanocomposites by Process II, wherein the BC hydrogel was immersed in different concentrations of silica sols, allowing silica particles to diffuse into the BC hydrogel and lodge in the spaces between the ribbon-shaped fibrils. This method increased the modulus at 20°C and the strength compared to the BC matrix, but it was difficult to load the BC with more than 10% silica in this way.     

基于XRD的镀锌钝化膜残余应力试验研究

利用XRD技术测试了镀锌钝化膜结合界面的残余应力，同时通过电解抛光法检测了其厚度方向残余应力的分布规律，分析了残余应力对镀锌钝化膜结合强度的影响. 试验结果表明，镀锌钝化膜的残余应力均表现为压应力，并随着基体表面残余应力的增大而减小；钝化膜在2—10μm厚度方向的残应力为-274.5—-428.3MPa，其应力为梯度分布；镀锌钝化膜与基体的界面结合强度与其残余应力成反比，减小薄膜残余应力，有利于提高镀锌钝化膜与基体的结合强度. 关键词： X射线衍射法(XRD) 镀锌钝化膜 结合强度 残余应力     

降载勾线法在高强钢疲劳断裂试验中的应用

制作高强钢特征试件,在压、弯应力共同作用下进行疲劳断裂试验;结合疲劳辉纹产生机理,采用降载勾线法在试件断面制造出“海滩状花纹”;利用CAD软件描绘断面形貌并测量裂纹长度,用Newman-Raju理论进一步研究表面裂纹扩展的规律,并与试验值比较.结果表明降载勾线法可以解决高强度钢表面裂纹不易测量及断面难以观测到疲劳辉纹的问题;采用Newman-Raju公式模拟压弯组合应力下表面裂纹扩展形貌是合适的,但由此计算的疲劳寿命偏于保守.另外,当压弯应力比值较小时,计算扩展形貌时压应力可以忽略,而计算疲劳寿命时压应力不可忽略.     

类锂等电子系列高位三激发态2p2np4So能量和到1s2pmp4P态的辐射跃迁

利用多组态相互作用方法及Rayleigh-Ritz变分法,计算了类锂离子2p²np⁴S^o(n=2—4)和1s2pmp⁴P(m=2,3)的能量.运用截断变分方法得到能量的改进量.计算了相对论修正、质量极化效应,从而获得了高精度的能量计算值.同时还计算了该系统之间的辐射跃迁波长、振子强度和辐射跃迁率.计算结果与实验符合得很好. 关键词： 三激发态 类锂离子 振子强度 辐射跃迁     

Buffer Standards for pH Measurement of N-(2-Hydroxyethyl)piperazine-N′-2-ethanesulfonic Acid (HEPES) for I=0.16 mol⋅kg−1 from 5 to 55 °C

The values of the second dissociation constant, pK ₂, of N-(2-hydroxyethyl) piperazine-N′-2-ethanesulfonic acid (HEPES) have been reported at twelve temperatures over the temperature range 5 to 55 °C, including 37 °C. This paper reports the results for the pa _H of eight isotonic saline buffer solutions with an I=0.16 mol⋅kg⁻¹ including compositions: (a) HEPES (0.01 mol⋅kg⁻¹) + NaHEPES (0.01 mol⋅kg⁻¹) + NaCl (0.15 mol⋅kg⁻¹); (b) HEPES (0.02 mol⋅kg⁻¹) + NaHEPES (0.02 mol⋅kg⁻¹) + NaCl (0.14 mol⋅kg⁻¹); (c) HEPES (0.03 mol⋅kg⁻¹) + NaHEPES (0.03 mol⋅kg⁻¹) + NaCl (0.13 mol⋅kg⁻¹); (d) HEPES (0.04 mol⋅kg⁻¹) + NaHEPES (0.04 mol⋅kg⁻¹) + NaCl (0.12 mol⋅kg⁻¹); (e) HEPES (0.05 mol⋅kg⁻¹) + NaHEPES (0.05 mol⋅kg⁻¹) + NaCl (0.11 mol⋅kg⁻¹); (f) HEPES (0.06 mol⋅kg⁻¹) + NaHEPES (0.06 mol⋅kg⁻¹) + NaCl (0.10 mol⋅kg⁻¹); (g) HEPES (0.07 mol⋅kg⁻¹) + NaHEPES (0.07 mol⋅kg⁻¹) + NaCl (0.09 mol⋅kg⁻¹); and (h) HEPES (0.08 mol⋅kg⁻¹) + NaHEPES (0.08 mol⋅kg⁻¹) + NaCl (0.08 mol⋅kg⁻¹). Conventional pa _H values, for all eight buffer solutions from 5 to 55 °C, have been calculated. The operational pH values with liquid junction corrections, at 25 and 37 °C have been determined based on the NBS/NIST standard between the physiological phosphate standard and four buffer solutions. These are recommended as pH standards for physiological fluids in the range of pH = 7.3 to 7.5 at I=0.16 mol⋅kg⁻¹.     

固体材料脆性断裂的多尺度时空模型(英文)

通过实例分析了动态断裂过程所固有的典型动态作用,基于断裂孵化时间理论的时空结构方法提出了固体材料断裂的统一解释.此外,还提出了计及尺度效应的广义断裂模型,该模型可以用于预测准脆性非均质材料的多尺度断裂,并证明此模型基于实验室尺度的实验数据可以预测更高尺度(真实尺度)的宏观断裂.     

共面闭合断续节理岩体直剪强度特性研究

介绍了节理面和岩桥各自的抗剪强度机制,引入法向变形协调条件,基于Mohr-Coulomb理论,推导了共面闭合断续节理岩体的直剪强度公式。模型试验发现,剪切破坏面以拉剪复合破坏为主,同时岩块中伴随大量的拉张微裂隙。试样的强度和变形具有明显的阶段性,全应力应变曲线主要经历了线弹性增长、节理面错动、次生裂纹起裂稳态扩展、节理面贯通破坏和残余强度5个阶段。对比发现,理论计算结果与试验值吻合较好。     

ANISOTROPIC STRENGTH CRITERION BASED ON T CRITERION AND THE TRANSFORMATION STRESS METHOD 1)

岩土材料通常呈现出成层水平分布特点, 即可将其视为横观各向同性材料, 横观各向同性对于岩土材料的变形以及强度值都会产生显著的影响. 基于已提出的t强度准则, t强度准则是基于各向同性单元体中存在有效滑移面来构建的, 并根据该空间有效滑移面上主剪应力与主法向应力的比值达到一定阈值为破坏条件. 在空间中存在有效滑移面与物理沉积面, 基于上述两个面在空间的位置关系, 用两面夹角作为表征横观各向同性对剪切强度影响程度的参量, 并假定当该夹角值越大, 则各向异性对强度贡献程度越大, 对应更大的应力比强度值, 反之, 则对应更小的应力比强度值. 基于上述思路并类比将其推广为正交三维各向异性准则, 基于三维各向异性材料的三维沉积面, 提出了三维特征沉积面的概念, 并基于空间滑移面与三维特征沉积面之间的夹角作为度量各向异性程度的变量, 提出了基于两面角作为参量考虑原生各向异性的应力比强度公式, 并利用该应力比强度公式来修正已提出的t强度准则, 最终建立了考虑各向异性影响的t准则公式. 在上述准则基础上, 考虑将各向异性应力空间转换为各向同性应力空间的思路, 在各向异性t准则基础上, 推导得到了基于各向异性强度t准则的变换应力公式, 利用变换应力公式可以将传统的以p, q为变量的各向同性本构模型转变为可考虑各向异性的三维本构模型. 通过对岩土材料的强度以及真三轴条件下的应力应变关系试验数据预测, 验证了所提的各向异性t准则及其变换应力公式的有效性及适用性.     

Improvement of breakdown characteristics of an A1GaN/GaN HEMT with a U-type gate foot for millimeter-wave power application

<正>In this study,the physics-based device simulation tool Silvaco ATLAS is used to characterize the electrical properties of an AlGaN/GaN high electron mobility transistor(HEMT) with a U-type gate foot.The U-gate AlGaN/GaN HEMT mainly features a gradually changed sidewall angle,which effectively mitigates the electric field in the channel, thus obtaining enhanced off-state breakdown characteristics.At the same time,only a small additional gate capacitance and decreased gate resistance ensure excellent RF characteristics for the U-gate device.U-gate AlGaN/GaN HEMTs are feasible through adjusting the etching conditions of an inductively coupled plasma system,without introducing any extra process steps.The simulation results are confirmed by experimental measurements.These features indicate that U-gate AlGaN/GaN HEMTs might be promising candidates for use in miltimeter-wave power applications.