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21.
Koichi Itoh Takeji Takui 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2004,80(2):29
This review paper deals with an overview of molecule-based magnetism as a rapidly developing interdisciplinary field, topological symmetry rule as the first principle of spin alignment in organic open-shell systems in the ground state, the proposal of organic through-bond 1D and 2D ferro- and superparamagnets and the detection of the first organic high-spin molecule, m-phenylenebis(phenylmethylene) in the quintet ground state (S = 2), followed by extended organic high-spin systems with π-conjugation such as aromatic hydrocarbons having S = 3, 4, 5. The paper also describes a theoretical approach to the understanding of electronic spin structures of organic high-spin molecules by invoking both Heisenberg and Hubbard model Hamiltonians, weakly interacting intramolecular high-spin systems from both experimental and theoretical sides, the spin density distribution of the first organic high-spin molecule in terms of electron- nuclear multiple resonance spectroscopy and the detection and characterization of ionic high-spin hydrocarbons, emphasizing the establishment of high spin chemistry underlying organic molecular magnetism. 相似文献
22.
A general class of Fuller modified maximum likelihood estimators are considered. It is shown that this class possesses finite moments. Asymptotic bias and asymptotic mean squared error are derived using small-σ expansions. A simulation study is carried out to compare different estimators in this class with standard estimators. 相似文献
23.
In order to check whether superconductivity occurs in the acceptor doped fullerenes C60(MF6)2 (M=As, P, Sb) and to study their magnetic and structural properties, we have carried out magnetic, EPR and NMR measurements of these compounds. Temperature dependences of magnetic susceptibility down to 5 K and field dependences of magnetic moment at 5 K show no ‘bulk’ transition in superconducting state. Some reasons of the absence of superconductivity, such as insufficient charge transfer between C60 and intercalated species and inhomogeneity of the compounds under study, are discussed. 相似文献
24.
Ioan Tomescu 《Journal of Graph Theory》2003,43(3):210-222
In the set of graphs of order n and chromatic number k the following partial order relation is defined. One says that a graph G is less than a graph H if ci(G) ≤ ci(H) holds for every i, k ≤ i ≤ n and at least one inequality is strict, where ci(G) denotes the number of i‐color partitions of G. In this paper the first ? n/2 ? levels of the diagram of the partially ordered set of connected 3‐chromatic graphs of order n are described. © 2003 Wiley Periodicals, Inc. J Graph Theory 43: 210–222, 2003 相似文献
25.
The role of the tunneling mechanisms in metal-disordered layer-semiconductor structure under spin injection at the interface is investigated. The non-ideal metal-semiconductor structure as prepared by ionized cluster beam deposition is considered, and it is shown that the depletion region of the semiconductor can be tailored to include a suitably heavily doped region near the interface. The tunneling is described within a simplified model in which the expression for the interface resistance of the metal-disordered layer-semiconductor structure is obtained. It is argued that in the case of ionized cluster beam deposited non-ideal Schottky structure a significant spin injection is achieved. 相似文献
26.
金淦 《Annals of Differential Equations》1998,(4)
1IntroductionStabilityintermsoftwomeasures,thisconceptenableustounifyava-rietyofstabilityconceptsandtoofferageneralandunifiedframeworkforinvestigationofstabilitytheory.AndtheoriginalLiapunovtheoremshavebeenextended,generalizedandweakenedinvariousaspects[3… 相似文献
27.
A new and rather trivial model is suggested with mechanism that implies simultaneous violation of the zeroth and the second
laws of thermodynamics. Mathematically rigorous quantum theory reduces to a trivial application of the Golden rule formula.
It yields exciton on-energy-shell diffusion caused by bath-nonassisted excitation hopping between tails of different exciton
site levels ε1 < ε2 broadened by bath-assisted finite life-time effects. The elastic character of the hopping implies 1 ↔ 2-symmetric transfer
rate W. Thus the net diffusion exciton flow W(P
1 - P
2) and also, as argued, the net energy flow are possible due to different near-to-equilibrium exciton populations P
1 > P
2. As the sites are provided with two different baths, the population imbalance and the flows survive even for slightly different
local bath temperatures T
1 < T
2 < T
1ε2/ε1. Thus spontaneous exciton and also energy flows against temperature step become possible, in contradiction with the Clausius
form of the second law. Violations of both the laws disappear in the high-temperature, i.e. classical limit
Received 16 May 2001 and Received in final form 20 September 2001 相似文献
28.
Wen.-C. Chiang J.G. Lin K.H. Hsu D.S. Hussey D.V. Baxter 《Journal of magnetism and magnetic materials》2006
We investigate Co/Nb multilayers to explore the spontaneous π-phase shift between the superconducting (SC) layers, which is attributed for causing the non-monotonic change of the SC transition temperature (Tc) with the ferromagnetic (FM) layer thickness (tFM) in several FM/SC multilayered systems. The issue of interfacial roughness is also explored by growing Co/Nb multilayers at various sputtering pressures. Transport measurements show a non-monotonic dependence of Tc on tFM, and this dependence is insensitive to the structural variation present in the samples, as measured by X-ray scattering. 相似文献
29.
30.
K. Kolwas 《Applied physics. B, Lasers and optics》1998,66(4):467-470
Received: 27 August 1997/Revised version: 7 November 1997 相似文献