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排序方式: 共有7309条查询结果,搜索用时 171 毫秒
61.
Masafumi Unno Hiroyuki Murakami Satoshi Kagawa Hideyuki Matsumoto 《Silicon Chemistry》2007,3(3-4):195-198
Two new silanols bearing very bulky silyl groups, (i-Pr3
Si)3SiOH and (t − BuMe2Si)3SiOH were prepared by peracidoxidation of their respective silanes. The X − ray crystallographic analysis revealed that (t − BuMe2Si)3 SiOH forms a dimeric structure with hydrogen bonding, while (i − Pr3 Si)3 SiOH exists as a monomer in the crystal. The effects of the size of the substituents as well as the reactivity of these silanols
are discussed. 相似文献
62.
Excess enthalpies (H
E
) for mixtures of cyclohexanone with propan-1-ol. propan-2-ol, butan-1-ol, butan-2-ol and 2-methyl propan-1-ol at 298.15 K
have been measured over the entire composition range. All mixed endothermically with the maximum values ofH
E
occurring at equimole fraction. Comments about the molecular interactions contributing to the excess enthalpies of a cyclic
ketone + an alcohol are made on the basis of these results. 相似文献
63.
64.
Rabindra N. Roy Lakshmi N. Roy Jason G. Grant Mason P. Cummins Bennett J. Tabor III Sarah J. Richards Curtis A. Himes Bret R. Lively Penny L. Blackwell Ashley N. Simon 《Journal of solution chemistry》2002,31(11):861-872
The values of the second dissociation constant, pK
2, for the dissociation of the NH+ charge center of the zwitterionic buffer compounds 4-(N-morpholino)butanesulfonic acid (MOBS), and N-(2-hydroxyethyl)piperazine-N-4-butanesulfonic acid (HEPBS) have been determined from 5 to 55°C, including, 37°C at intervals of 5°C. The electromotive-force (emf) measurements have been made utilizing hydrogen electrodes and silver–silver chloride electrodes. The value of pK
2 for MOBS was found to be 7.702 ± 0.0005, and 8.284 ± 0.0004 for HEPBS, at 25°C, respectively. The related thermodynamic quantities, G
o, H
o, S
o, and C
p
o for the dissociation processes of MOBS and HEPBS have been derived from the temperature coefficients of pK
2. Both the MOBS and HEPBS buffer materials are useful as primary pH standards for the control of pH 7.3 to 8.6 in the region close to that of physiological fluids. 相似文献
65.
Homo-dinuclear alkynyl complexes with a distinct metal–metal bond constitute a rapidly growing field, where the focus is placed on compounds based on ruthenium, molybdenum, tungsten or rhodium. Interesting characteristics of these complexes include paramagnetism, intense charge-transfer absorptions, tunable bridging ligands, which may not be easily accessible in mononuclear acetylide systems. These complexes have significant potential for use in both molecular electronics and supramolecular chemistry. In this short account, previous work in this area is assessed, and each of the major groups of complexes is discussed in terms of both the synthetic strategies and structural motifs. 相似文献
66.
羟丙基甲基纤维素作为水泥添加剂研究(四) 总被引:2,自引:0,他引:2
以萘磺酸甲醛缩合物为分散剂,水溶性羟丙基甲基纤维素衍生物为粘稠剂,研究了它们的混合物对混凝土材料的分散性与粘稠性及其它性能的影响,并探索了其作用机理。 相似文献
67.
Lingjia Xu Liangliang Zhu Shi Wu Xiaopeng Chen Qiwen Teng 《Central European Journal of Chemistry》2006,4(4):732-742
Supermolecular complexes formed by oligophenyleneethynylene derivatives and isophthalic acid were studied using AM1 method
to obtain binding energy. Electronic spectra and IR spectra of the complexes were calculated by INDO/CIS and AM1 methods based
on AM1 geometries. Results indicated that the dimer could be formed by the monomers via hydrogen bonding because of the negative
binding energy. Binding energy of the complexes was affected by electronegativity and steric effects of the substituents.
The first UV absorptions and IR frequencies of N-H bonds of the complexes were both red-shifted compared with those of the
monomers. The complexes could bind small molecules via hydrogen bonds, resulting in the change in UV absorptions and an increase
in IR frequencies of N-H bonds. 相似文献
68.
JD树脂刻蚀及涂层的XPS研究 总被引:2,自引:0,他引:2
JD光学树脂表面刻蚀过程的XPS研究表明,引进树脂遥COH,C=O,C-SO3H,COOH等基因随刻蚀温度的提高或时间的延长而增加,对其相对含量进行了计算,固化后的耐磨涂层具有SiO2结构,JD板材的最佳刻蚀条件为20℃,20min。 相似文献
69.
J. Baran A. J. Barnes M. K. Marchewka A. Pietraszko H. Ratajczak 《Journal of Molecular Structure》1997,416(1-3):33-42
The crystal structure of bis(betaine)-selenic acid has been determined by X-ray diffraction as orthorhombic, space group Pbca, with a = 11.591(2), b = 22.930(5), c = 12.045(2) Å and Z = 8. The crystal comprises hydrogen selenate ions, HSeO−4, and two distinct betaine molecules, which are held together into a complex by short hydrogen bonds. One of the betaine molecules is present as the zwitterion form (CH3)3N+---CH2---COO− and the second occurs as the protonated form (CH3)3N+---CH2---COOH. Powder FTIR and Raman spectra were measured. An assignment of the observed bands to vibrations of the hydrogen bonds and internal vibrations of the hydrogen selenate ion and the betaine molecules is proposed. 相似文献
70.
Partition coefficients P of the HNCS, HNCO and HN3 hydropseudohalic acids between a number of organic solvents and water were determined. It has been found that log P increases with pKa of the acid and with the basicity of the solvent, but the effect of pKa on P is the smaller the more basic is the solvent. The relationships have been explained in terms of hydrogen bond formation between undissociated acid and solvent molecules. H-bonding between the pseudohalic acids and organic solvents has been confirmed by IR spectra on the example of HN3 in benzene. Association constants for H-bonding between the three acids and water, benzene, dibutyl ether and tri-n-butyl phosphate were determined from partition data. It has been found that H-bonding increases with the strength of the acid, whereas the contribution to partition from non-specific interactions with water and organic solvents depends on the molecular surface area of the acid molecule. 相似文献