Use of a displacement model for solvent sorption to study non-specific selectivity in reversed-phase liquid chromatography

Summary A thermodynamic equation is derived for the non-specific selectivity of alkyl bonded phases as a function of the mobile phase composition using a displacement mechanism to model the sorption of solvents into the bonded phase. The equation is used to calculate the thermodynamic parameters which characterize the incremental behavior of a hydrophobic group in ethyl alkanoate and methyl perfluoroalkanoate ester solutes chromatographed with water-methanol and water-acetonitrile mobile phases on both octyl and octadecyl bonded phases.     

合肥光源注入系统建造与调试

介绍了HLS(合肥光源)储存环注入系统建造与调试情况. 重点讨论了各种公差、公差判断及抑制措施, 经过改进与及仔细调整, 得到了平均累积速率2—6mA/s的日常运行水平, 最高累积流强400mA, 该系统已经稳定使用近两年, 在光源的运行中起到了重要作用.     

核磁共振磁体超导接头工艺研究进展

高度稳定的磁场对于核磁共振（NMR）波谱仪至关重要.为了保持磁场的稳定性,高质量的超导接头必不可少.它在过去几十年中,受到NMR超导磁体研究人员的广泛关注.本文从五个部分介绍了超导接头技术的研究进展：第一部分简要介绍了NMR超导磁体和超导接头的发展;第二部分概述了低温超导体材料之间超导接头的研究进展;第三部分介绍了高温超导体材料之间的接头;第四部分讨论了有关超导接头电阻的测量技术;最后,提出了对超导接头技术研究的展望.     

弱界面异质球形夹杂本征应变问题的解析解

本文研究了具有线弹簧弱界面的异质球形夹杂的本征应变问题，所采用的线弹簧界面模型既能界面的切线方向滑动，又能考虑界面的法线方向张开，根据叠加原理、原问题的弹性场可分成三部分；二部分由真实均匀本征应变所引起，另一部分由等效的非均匀本征应变所引起，后一部分则由虚拟的Ｓｏｍｉｇｌｉａｎａ位错场所产生。本文求得了等效非均匀本征应变和虚拟位错场的Ｂｕｒｇｅｒ矢量的解析表达式，进而确定的问题的弹性场。     

大黄酸键合硅胶固定相的简便制备及色谱性能评价

以大黄酸为原料,γ-氨丙基三乙氧基硅烷(KH-550)为偶联剂,简便制备了一种新型羧基键合硅胶固定相(RBSP),并用红外光谱、热重分析及元素分析对其结构进行表征.考察了流动相中甲醇含量对键合固定相色谱性能的影响,并以含酸性、中性和碱性化合物的混合物为溶质,评价了RBSP的色谱性能.以甲醇-水为流动相,用C18柱作参比,研究了该键合硅胶作为HPLC固定相对两种大豆异黄酮化合物和几种生物碱基的分离,并对其色谱分离机理进行了初步探讨.实验结果表明,该固定相(RBSP)具有较好的反相色谱性能,同时由于键合相中含有酚羟基及酰胺基团,能为多种溶质提供作用位点,对极性化合物的分离具有明显优势,且分离速度快,可有效用于极性化合物的分离分析.     

Characterization of calixarene‐bonded stationary phases

Calixarene‐bonded stationary phases received growing interest in HPLC as stationary phases with special retention characteristics and selectivity. The commercially available unsubstituted and p‐tert‐butyl‐substituted Caltrex^® columns have been intensively studied and characterized in our workgroup. They can be used as reversed phases, yet they support additional interactions. Especially, their steric, polar and ionic properties differ from conventional alkyl‐bonded phases. However, also the hydrophobic interaction shows differences since adsorption and partition interactions on or in a bonded layer of calixarenes are not similar to those of alkyl‐bonded layers. The relative strength of the hydrophobic properties of the stationary phases has been found depending on the methanol concentration of the mobile phase. Generally, the dependencies of their interaction strengths on mobile‐phase conditions, e.g. the change of the intensity of the hydrogen‐bonding abilities with decreasing methanol content, are not similar from phase to phase either. This probably gives calixarene‐bonded stationary phases enhanced suitability for analyses at extreme compositions of the mobile phase. An overview about the synthesis, retention and selectivity properties of Caltrex^® columns is given here.     

超导磁体等效材料参数的有限元预测

HT—7U超导托卡马克装置中纵场超导磁体是由多种材料组成的且具有周期性分布的大型复杂的重要结构，对其宏观等效材料参数的准确掌握在其结构设计阶段是十分重要的。本文着重介绍了利用小参数展开的渐近均匀化方法对其进行等效处理的过程，并采用有限元方法预测出其等效弹性模量与热膨胀系数等，这些都为纵场磁体结构的力学计算与传热分析提供了必要的参数。     

迫流冷却二极NbTi超导磁体的研究

首先介绍了导体的测试结果;其次,为评估迫流冷却的二极NbTi超导磁体正常工况下对液氦产生的低温热负荷,基于surf152表面效应单元对线圈盒进行了辐射传热分析;此外,为减小通过线圈盒支撑的传导热负荷并且提高其机械强度,依据线圈盒支撑杆的设计尺寸,提出使用玻璃纤维经过三维编织的各向异性复合材料-G10制作线圈盒支撑杆,从...