全文获取类型
收费全文 | 1506篇 |
免费 | 420篇 |
国内免费 | 153篇 |
专业分类
化学 | 753篇 |
晶体学 | 25篇 |
力学 | 71篇 |
综合类 | 9篇 |
数学 | 208篇 |
物理学 | 1013篇 |
出版年
2024年 | 4篇 |
2023年 | 21篇 |
2022年 | 64篇 |
2021年 | 63篇 |
2020年 | 68篇 |
2019年 | 38篇 |
2018年 | 51篇 |
2017年 | 73篇 |
2016年 | 66篇 |
2015年 | 64篇 |
2014年 | 105篇 |
2013年 | 122篇 |
2012年 | 106篇 |
2011年 | 127篇 |
2010年 | 105篇 |
2009年 | 109篇 |
2008年 | 109篇 |
2007年 | 130篇 |
2006年 | 104篇 |
2005年 | 83篇 |
2004年 | 65篇 |
2003年 | 67篇 |
2002年 | 51篇 |
2001年 | 42篇 |
2000年 | 43篇 |
1999年 | 29篇 |
1998年 | 25篇 |
1997年 | 32篇 |
1996年 | 15篇 |
1995年 | 14篇 |
1994年 | 8篇 |
1993年 | 10篇 |
1992年 | 16篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 10篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 9篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1973年 | 3篇 |
1959年 | 1篇 |
排序方式: 共有2079条查询结果,搜索用时 203 毫秒
21.
We obtain a necessary and sufficient condition for the decomposition of the spectrum of an arbitrary nonsymmetric potential whose least value is attained at finitely many points. 相似文献
22.
U.Deva Priyakumar 《Tetrahedron letters》2004,45(12):2495-2498
A novel preference for planar tetracoordination was observed over the conventional tetrahedral arrangement in a new series of C5H2, C5H4, C5H41+/2+ and related compounds. The stability of these molecules is assessed with the ring-opening barriers, HOMO-LUMO gap, singlet-triplet energy differences and nucleus independent chemical shift values. 相似文献
23.
Makoto Kato Azusa Tsukigase Hiromitsu Tanaka Arimitsu Usuki Isamu Inai 《Journal of polymer science. Part A, Polymer chemistry》2006,44(3):1182-1188
Isobutylene isoprene rubber (IIR)‐clay nanocomposites have been prepared successfully by melt intercalation with maleic anhydride‐grafted IIR (Ma‐g‐IIR) and organophilic clay. In IIR‐clay nanocomposites, the silicate layers of the clay were exfoliated and dispersed into the monolayer. The nanocomposites exhibited greater gas barrier properties compared with those of Ma‐g‐IIR. When 15 phr clay was added, gas barrier properties were 2.5 times greater than those of Ma‐g‐IIR. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1182–1188, 2006 相似文献
24.
akir Aydoan Mustafa Salam Abdulmecit Türüt 《Journal of Polymer Science.Polymer Physics》2006,44(11):1572-1579
The polypyrrole/p‐InP structure has been fabricated by the electrochemical polymerization of the organic polypyrrole onto the p‐InP substrate. The current–voltage (I–V), capacitance–voltage (C–V), and capacitance–frequency (C–f) characteristics of the PPy/p‐InP structure have been determined at room temperature. The structure showed nonideal I–V behavior with the ideality factor and the barrier height 1.48 and 0.69 eV respectively. C–f measurements of the structure have been carried out using the Schottky capacitance spectroscopy technique and it has been seen that there is a good agreement between the experimental and theoretical values. Also, it has been seen that capacitance almost show a plateau up to a certain value of frequency, after which, the capacitance decreases. The higher values of capacitance at low frequencies were attributed to the excess capacitance resulting from the interface states in equilibrium with the p‐InP that can follow the a.c. signal. The interface state density Nss and relaxation time τ of the structure were determined from C–f characteristics. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1572–1579, 2006 相似文献
25.
应用改进的量子分子动力学模型,在严格挑选初始核考虑弹靶结构效应的基础上,研究了近垒和垒上融合反应40,48Ca+90,96Zr. 研究表明: 4个反应的理论计算截面与实验值很好符合; 丰中子反应40Ca+96Zr的垒下融合截面比其他3个反应有明显增强的现象.为了理解丰中子反应40Ca+96Zr与40Ca+90Zr相比垒下融合截面增强,而Ca+96Zr垒下融合截面没有明显增强的原因, 进一步分析了484个反应的融合位垒,中子转移与融合位垒的关系、中子转移与Q值的关系,结果表明: 正反应Q值会引起核子(特别是中子)转移的增强,从而导致动力学融合位垒的下降和垒下融合截面增强. 相似文献
26.
Ab initio calculations on vinyldifluoroborane yield a -contribution of 23 kJ/mol (5.5 kcal/mol) mainly due to the C=C bond and not to the lone pairs of the fluorine atoms. The rotational barrier was also determined. The force field calculations favour the interpretation of the bond structure derived from the theab initio results. 相似文献
27.
The rectifying junction characteristics of the organic compound pyronine-B film on a p-type Si substrate has been studied. The pyronine-B has been sublimed on the top of p-Si surface. The barrier height and ideality factor values of 0.79±0.04 and 1.13±0.06 eV for this structure have been obtained from the forward bias current-voltage (I-V) characteristics. From the low capacitance-frequency (C-f) characteristics as well as conductance-frequency (G-f) characteristics, the energy distribution of the interface states and their relaxation time have been determined in the energy range of (0.53−Ev)-(0.79−Ev) eV taking into account the forward bias I-V data. The interface state density Nss ranges from 4.93×1010 cm−2 eV−1 in (0.79−Ev) eV to 3.67×1013 cm−2 eV−1 in (0.53−Ev) eV. Furthermore, the relaxation ranges from 3.80×10−3 s in (0.53−Ev) eV to 4.21×10−4 s in (0.79−Ev) eV. It has been seen that the interface state density has an exponential rise with bias from the midgap towards the top of the valence band. The relaxation time shows a slow exponential rise with bias from the top of the valence band towards the midgap. 相似文献
28.
29.
UV absorption spectra of acetyl fluoride-h3 and -d3 (CH3COF and CD3COF) molecules in the region of S1S0 electronic transitions are investigated. The origins (00
0 or 140±
0) of these transitions are observed at 39912 and 39904 cm–1, respectively, and some of the fundamental frequencies of these molecules in the s0 and S1 states are determined. In particular, the systems of torsion and inversion (out-of-plane C=O vibrations) energy levels are studied. The geometric parameters of an acetyl fluoride-h3 molecule in the S1 state are estimated by the theoretical simulation of the rotational contours of the 00
0 (140±
0) band. These data are used to evaluate the potential barriers to internal rotation in the S0 and S1 states, which were found to be 360 and 560 cm–1 for acetyl fluoride-h3 and 380 and 770 cm–1 for acetyl fluoride-d3, respectively, as well as the potential barriers to inversion in the S1 states, which were found to be 2090 and 2370 cm–1 for acetyl fluoride-h3 and acetyl fluoride-d3, respectively.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1957–1964, November, 1994.In conclusion, the authors would like to acknowledge T. S. Kuznetsova for the synthesis and purification of the AF samples.The research presented here was supported in part by the International Science Foundation under grant No. MJ 1000. 相似文献
30.
Beate Hager Bettina Schwarzinger Heinz Falk 《Monatshefte für Chemie / Chemical Monthly》2006,137(2):163-168
Summary. Two model compounds for the green fluorescent protein chromophore were prepared. One of them incorporates the natural 4-hydroxybenzylidene
group of the natural tyrosin derived chromophore, the other one bears a methyl group instead of the hydroxy group. Whereas
the photochemically prepared (E)-diastereomer of the first compound very effectively reverted thermally (room temperature) to the thermodynamically stable
(Z)-diastereomer, the (E)-diastereomer of the second derivative proved to be stable even at elevated temperatures for more than a day. This finding
can be rationalized by constructing the appropriate resonance structures showing that only in the first case an effective
delocalization enables partial single bond character of the benzylidene double bond. From the standpoint of chemical etiology,
only Nature’s choice of the tyrosin derived chromophore of the green fluorescent protein provides an efficient radiationless
thermal relaxation channel for the unwanted photo-diastereomerization product formed after excitation besides the dominating
fluorescence channel of its chromophore. 相似文献