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51.
Iron-Cobalt-Silica nanocomposites were prepared in form of aerogels. X-ray diffraction, transmission electron microscopy and N2 physisorption at 77 K were used to investigate the structure, size and dispersion of the nanocrystals and the porous structure in the aerogels and in the final composites. The variation of the supercritical drying conditions gives rise to differences in the morphological features of the aerogels. These differences influence the size of the cobalt oxide nanoparticles in the aerogels. On the other hand, after the reduction treatment the average size of the alloy nanoparticles is the same in all the aerogel nanocomposites. The effect of reduction temperature on alloy formation and particle size is also discussed. 相似文献
52.
Double percolation effect on the electrical conductivity of conductive particles filled polymer blends 总被引:11,自引:0,他引:11
M. Sumita K. Sakata Y. Hayakawa S. Asai K. Miyasaka M. Tanemura 《Colloid and polymer science》1992,270(2):134-139
Electrical conductivity of carbon black (CB) filled polymer blends which are incompatible with each other was studied as a function of the polymer's blend ratio. Transmission electron microscope (TEM) analysis shows that CB distributes unevenly in each component of a polymer blend. TEM photographs of phase structure of solvent extracted HDPE/PMMA blend and solvent extraction experiments of PMMA/PP blend detect the blend ratio at which the structural continuity of filler rich phase is formed. The electrical conductivity of polymer blends is found to be determined by two factors. One is the concentration of CB in the filler rich phase and the other is the structural continuity of this phase. This double percolation affects the conductivity of conductive particle filled polymer blends. 相似文献
53.
Jeong Hwan Kim Ji Hoon Ko Byeong-Soo Bae 《Journal of Sol-Gel Science and Technology》2007,41(3):249-255
Multi-scale hybrid nanocomposites containing both ∼15 nm silica colloids and ∼2 nm oligosiloxanes in a methacryl polymer matrix
were newly designed and fabricated. Colloidal silica sols were dispersed in methacryl oligosiloxanes nano-hybrid resins synthesized
by sol-gel reaction of methacryloxypropylmethoxysilane and diphenylsilanediol. On the basis of TEM and SANS analyses, it was
confirmed that the silica colloids were compatibly dispersed and different sizes of colloidal silica and oligosiloxanes co-exist
in the solutions. Multi-scale hybrid nanocomposites fabricated by UV and thermal curing with incorporation of silica colloids
in the nano-hybrid materials show enhanced mechanical and thermal characteristics. 相似文献
54.
UV curable epoxy acrylates were reinforced with two different organically modified montmorillonites (MMTs) and an unmodified MMT. Conversion and rate of polymerization was monitored by real time infrared spectroscopy (RTIR) and photo-DSC. Microstructures were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and optical clarity. Optical clarity of the films containing clay was quite good as only a slight decrease was observed. Physical properties of the reinforced films were examined by differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), hardness and tensile testing. Enhancements in glass transition temperature (Tg), thermal stability and mechanical properties were observed. The films reinforced with the unmodified MMT exhibit the most significant enhancements in properties. 相似文献
55.
56.
I. Kiricsi 《Journal of Thermal Analysis and Calorimetry》2005,79(3):567-572
Summary In this study we report the synthesis and thermal characterization of multiwall carbon nanotubes containing zeolite based nanocomposites. Three different zeolites (LTA, FAU and MFI) were used in this study and it was observed that the morphologies of the synthesized nanocomposites were significantly different. For FAU zeolite nanocrystals with a few nm in diameter were nucleated on the nanotubes covering their surface, however, for LTA and MFI zeolites bulky crystals with nanotubes crossing them were observed by transmission electron microscopy. One of the most important results of our study was the generation of secondary mesoporosity in the zeolites after removing the carbon nanotubes. 相似文献
57.
交联助剂对PPC/NBR弹性体结构和性能的影响 总被引:2,自引:1,他引:2
研究了马来酸酐(MA)及异氰脲酸三烯丙酯(TAIC)对聚丙撑碳酸酯/丁腈橡胶共混弹性体结构和性能的影响,发出加入MA或TAIC能有效地改善交联网络;加入适量MA能显著改善共混弹性体热氧老化稳定性;加入TAIC使共混弹性体具有优良的高弹特性和力学性能。 相似文献
58.
59.
等离子体引发原位聚合制备凹凸棒土/聚苯乙烯纳米复合物 总被引:7,自引:0,他引:7
用阳离子表面活性剂处理凹凸棒土(Attapulgite),通过超声分散的方法将其均匀分散到苯乙烯单体中,并采用等离子体引发的方法制备出凹凸棒土/聚苯乙烯纳米复合物。通过透射电子显微镜(TEM)和X-射线衍射(XRD)观察了凹凸棒土及其纳米复合物的微观结构。对复合物的GPC测试表明,采用等离子体引发聚合反应可以显著提高树脂的分子量。XRD结果表明聚苯乙烯不是嵌入到凹凸棒土的层间,而是通过离子吸附接枝在凹凸棒土的棒状晶束上。 相似文献
60.