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991.
L.P. Kaptari B. Kämpfer S.S. Semikh S.M. Dorkin 《The European Physical Journal A - Hadrons and Nuclei》2003,17(1):119-132
The exclusive charge exchange reaction pD↦n(pp) at intermediate and high energies is studied within the Bethe-Salpeter formalism. The final-state interaction in the detected
pp pair at nearly zero excitation energy is described by the 1
S
0 component of the Bethe-Salpeter amplitude. Results of numerical calculations of polarization observables and differential
cross-section persuade that, as in the non-relativistic case, this reaction i) can be utilized as a “relativistic deuteron
polarimeter” and ii) delivers further information about the elementary nucleon-nucleon charge exchange amplitude.
Received: 26 November 2002 / Accepted: 30 January 2003 / Published online: 29 April 2003 相似文献
992.
993.
The process of planar detonation ignition, induced by a constant-velocitypiston or equivalently by a shock reflected from a stationarywall, is investigated using high-resolution one-dimensionalnumerical simulations. The standard one-step model with Arrheniuskinetics, which models thermally sensitive explosives, is employed.Emphasis is on comparing and contrasting the results of thefinite activation temperature simulations with high activationtemperature asymptotic predictions and previous simulations.During the induction phase, it is shown that the asymptoticresults give qualitatively good predictions. However, for parametersrepresentative of gaseous explosives, subsequent to thermalrunaway at the piston and the formation of a reaction wave,the high activation temperature asymptotic theory is qualitativelyincorrect for moderately high activation temperatures. It isshown that the results are very sensitive to the value of theactivation temperature, especially the distance from the pistonat which a secondary shock forms and the degree of unsteadinessin the reaction wave which moves away from the piston. The dependenceof the ignition evolution on the other parameters (initial shockMach number, heat of reaction and polytropic index) is alsoinvestigated. It is shown that qualitative predictions regardingthe dependence of the ignition evolution on each of the parameterscan be elucidated from finite activation temperature homogeneousexplosion calculations together with the high activation temperatureasymptotic shock ignition results. It is found that for sufficientlystrong initiating shocks the ignition evolution is qualitativelydifferent from cases studied previously in that no secondaryshock forms. For a high polytropic index, corresponding to asimple equation of state model for condensed phase explosives,the results are in much better qualitative agreement with theasymptotic theory. 相似文献
994.
Jairo Quijano Jorge David Claudia Snchez Elizabeth Rincon Doris Guerra Luis A. Len Rafael Notario Jos L. Abboud 《Journal of Molecular Structure》2002,580(1-3):201-205
Thermolysis studies of β-hydroxyolefins in gas phase were realized using ab initio MP2 and DFT methods at the 6-31G* levels to explore the possibility of determining a possible concerted process with a six-membered cyclic transition state (TS). Vibrational frequency calculations were carried out in order to confirm the stationary states, including TS structures. IRC calculations have been performed in all cases in order to verify that localized TS structures connect with the corresponding minimum stationary points associated with the reactant and products. With the aim of corroborating the postulated mechanism in the experimental study, we present a theoretical study in order to calculate the rate constants and the activation parameters. The results obtained are in accordance with the experimental conclusions. 相似文献
995.
A study of the free racinoal reaction of vinylcycloprelpane mediated by p-toluenesulfonyl chloride is described. 相似文献
996.
J. Ahrens S. Altieri J. R. M. Annand H. -J. Arends R. Beck A. Braghieri N. d'Hose H. Dutz S. Goertz P. Grabmayr S. Hasegawa E. Heid H. Holvoet L. Van Hoorebeke N. Horikawa T. Iwata O. Jahn P. Jennewein R. Kondratiev J. Krimmer M. Lang B. Lannoy K. Livingston J. C. McGeorge W. Meyer A. Panzeri P. Pedroni T. Pinelli I. Preobrajenski G. Reicherz G. Rosner M. Rost T. Rostomyan D. Ryckbosch M. Schumacher B. Seitz G. Tamas A. Thomas R. van de Vyver Th. Walcher F. Zapadtka 《The European Physical Journal A - Hadrons and Nuclei》2005,26(1):135-140
The G asymmetry of the γp↦Nπ reaction has been measured for the first time for Eγ = 340±14 MeV. This observable, for which very scarce published data exist, plays an important role to disentangle the contributions
of the various nucleon resonances. The experiment, performed at the Mainz microtron MAMI, used a 4π-detector system, a linearly
polarized, tagged photon beam, and a longitudinally polarized proton target. 相似文献
997.
L. Roca C. Hanhart E. Oset U. -G. Meißner 《The European Physical Journal A - Hadrons and Nuclei》2006,27(3):373-380
The Λ(1520)-resonance has been recently studied in a unitarized coupled-channel formalism with πΣ(1385), KΞ(1530), ˉN and πΣ as constituents blocks. We provide a theoretical study of the predictions of this model in physical observables of
the pp → pK+K-p and pp → pK+π0π0Λ reactions. In particular, we show that the ratio between the π0π0Λ and K-p mass distributions can provide valuable information on the ratio of the couplings of the Λ(1520)-resonance to πΣ(1385) and
ˉN than the theory predicts. Calculations are done for energies which are accessible in an experimental facility like COSY at
Jülich or the developing CSR facility at Lanzhou. 相似文献
998.
M. Di Toro V. Baran M. Colonna V. Greco S. Maccarone M. Cabibbo 《The European Physical Journal A - Hadrons and Nuclei》2002,13(1-2):155-161
In the reaction dynamics of intermediate-energy radioactive beams we can probe highly asymmetric nuclear matter in compressed
as well as dilute phases. In this report some predictions are presented, based on analytical results as well as on reaction
simulations. We suggest a series of experiments with RIB aimed to shed light on isospin properties of nuclear interactions
in the medium.
Received: 1 May 2001 / Accepted: 4 December 2001 相似文献
999.
Facile Yb(OTf)3 promoted one-pot synthesis of polyhydroquinoline derivatives through Hantzsch reaction 总被引:1,自引:0,他引:1
Yb(OTf)3 catalyzed efficient Hantzsch reaction via four-component coupling reactions of aldehydes, dimedone, ethyl acetoacetate and ammonium acetate at ambient temperature was described as the preparation of polyhydroquinoline derivatives. The process presented here is operationally simple, environmentally benign and has excellent yield. Furthermore, the catalyst can be recovered conveniently and reused efficiently. 相似文献
1000.
Precise control and knowledge of surface structures are essential inorder to meet the requirements of today's and future materials. One possiblegrowth technique capable of meeting the requirements is atomic layer epitaxy(ALE). ALE is based on sequentially applied saturated gas-solid reactions,which provide the means for adsorption controlled material deposition atatomic layer level. In this paper the potentiality of the use of porousmaterials in a detailed study of adsorption controlled growth is discussed.At the same time the study promotes the application of adsorption controlledmaterials processing for advanced catalysts manufacturing. 相似文献