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101.
A bicyclic diphenyldisilane bearing two tetramethylene tethers reacts with lithium to form predominantly the disilanyllithium as a result of Si-CPh bond fission, while the pentamethylene homolog undergoes ordinary Si-Si bond cleavage to afford the expected phenylsilyllithium. The compressed Si-Si bond incorporated in the bicyclic ring system may be kinetically stabilized (compression effect), resulting in the unusual Si-C bond fission. When the reaction is carried out in the presence of chlorotrimethylsilane, a Calas-type reaction takes place on the phenyl rings. This result suggests that electron transfer to the phenyl group is the primary process in these bicyclic disilanes, followed by Si-Si or Si-C bond cleavage to afford the corresponding silyllithium species. 相似文献
102.
Abelló S Medina F Tichit D Pérez-Ramírez J Groen JC Sueiras JE Salagre P Cesteros Y 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(2):728-739
Two different rehydration procedures in the liquid or gas phase have been applied to reconstruct mixed oxides derived from calcined hydrotalcite-like materials to be used as catalysts for aldol condensation reactions. The as-synthesized hydrotalcite, its decomposition product, as well as the reconstructed solids upon rehydration were characterized by XRD, N(2) adsorption, He pycnometry, FTIR, SEM, TEM, (27)Al MAS-NMR and CO(2)-TPD (TPD=temperature-programmed desorption). Compared to the Mg-Al mixed oxide rehydrated in the gas phase (HT-rg), that rehydrated in the liquid phase (HT-rl) exhibits a superior catalytic performance with respect to the aldol condensation of citral with ketones to yield pseudoionones and in the self-aldolization of acetone. The textural properties of HT-rl and HT-rg differ strongly and determine the catalytic behavior. A memory effect led to a higher degree of reconstruction of the lamellar structure when the mixed oxide was rehydrated in the gas phase rather than in the liquid phase, although liquid-phase rehydration under fast stirring produced a surface area that was 26 times greater. This contrasts to typical statements in the literature claiming a higher degree of reconstruction in the presence of large amounts of water in the medium. CO(2)-TPD shows that the number of OH(-) groups and their nature are very similar in HT-rg and HT-rl, and cannot explain the markedly different catalytic behavior. Accordingly, only a small fraction of the available basic sites in the rehydrated samples is active in liquid-phase aldol condensations. Our results support the model in which only basic sites near the edges of the hydrotalcite platelets are partaking in aldol reactions. Based on this, reconstructed materials with small crystallites (produced by exfoliation during mechanical stirring), that is, possessing a high external surface area, are beneficial in the reactions compared to larger crystals with a high degree of intraplatelet porosity. 相似文献
103.
Patrícia M. Dias Dalva L. A. De Faria Vera R. L. Constantino 《Journal of inclusion phenomena and macrocyclic chemistry》2000,38(1-4):251-266
In the present work, the interaction between5,10,15,20-tetrakis(1-methyl-4-pyridyl)-21H,23H-porphine (TMPyP) and its metallated form(CoTMPyP) with three cationic clays was investigatedby X-ray diffraction (XRD), UV-VIS and resonance Ramanspectroscopies. Sodium montmorillonites K10 and KSFand a synthetic fluorohectorite (FHT) containingdifferent macrocycle loadings, were prepared by an ionexchange reaction. In nonsaturated KSF and FHT, theCoTMPyP molecule assumes a flat orientation, relativeto the host layers, giving rise to at least twoabsorption bands in the Soret region (ca. 445 and 465 nm)assigned to adsorbed and intercalated CoTMPyP,respectively. For the delaminated K10 sample, a broadband centered around 456 nm, indicates a majorcontribution from the metalloporphyrin on the clayexternal surfaces. The electronic spectra of FHTsamples containing increasing amounts of CoTMPyPshow bands red shifted even when a small amount ofporphyrin is used, suggesting that the electroniclevels of the macrocycle are more affected by theinteraction with the clay than by the metalloporphyrindistortion inside the galleries. The resonance Ramanspectra obtained for all CoTMPyP samples presentedonly minor shifts in peak positions and band width,with the exception of the FHT saturated sample, wherethe bands are clearly broader when compared to otherloadings, suggesting that porphyrin aggregation isoccurring. In the case of TMPyP, the bands at ca. 430and 468 nm were assigned to nonprotonated andprotonated molecules, respectively. This assignment issupported by resonance Raman spectroscopy, which alsoshowed the 2 mode (ca. 1550 cm-1) to bethe most sensitive peak to protonation. 相似文献
104.
Ammonium acetate was found to catalyze efficiently the selective deprotection of aromatic acetates in the presence of various sensitive functionalities in aqueous methanol under neutral conditions at room temperature to yield the corresponding phenols in excellent yields. The method has been utilized for deprotection of acetates of several naturally occurring bioactive phenolic compounds and for preparation of venkatasin, a natural coumarino-lignan, from the anticancer compound cleomiscosin A. 相似文献
105.
Reinhard Haase Dorit S. Meinhold Berthold Thomas Edwin Weber Gerd Rheinwald 《Structural chemistry》2002,13(5-6):471-477
The crystal structures of inclusion compounds of 3,3-bis(9-hydroxy-9-fluorenyl)-2,2-binaphthyl host (1) and its chloro (2) or bromo (3) derivatives substituted in 2,7-positions of the fluorene units with acetone guests (1A–3A) were determined by X-ray studies as well as by 1H-CRAMPS solid-state NMR. Using this NMR technique allows identification of differently bound guest molecules due to their different chemical shifts caused by the influence of the ring current effects of the host aryl units. 相似文献
106.
Mahrour A. Lacroix M. Nketsa-Tabiri J. Calderon N. Gagnon M. 《Radiation Physics and Chemistry》1998,52(1-6):81-84
This study was undertaken to determine if a combined treatment (marinating in natural plant extracts or vacuum) with irradiation could have a synergetic effect, in order to reduce the dose required for complete elimination of Salmonella on fresh poultry. The effect of these combined treatments on the shelf-life extension was also evaluated. The fresh chicken legs were irradiated at 0, 3 and 5 kGy. The poultry underwent microbial analysis(mesophilic and Salmonella detection). For each treatment, the total microbial count decreased with increase of irradiation dose. The marinating treatment have a synergistic effect with irradiation treatment to reduce the total microbial count and controlling the proliferation during storage at 4°C. Irradiation of fresh chicken pieces with a dose of 3 kGy appears to be able to extend the microbial shelf-life by a factor of 2. When the chicken is marinating and irradiated at 3 kGy or when irradiated at 5 kGy without marinating, the microbial shelf-life is extended by a factor of 7 to 8. No Salmonella was found during all the experiment in the chicken in air and marinated. However, a presence of Salmonella was found in samples irradiated at 5 kGy under vacuum, in unirradiated samples and samples irradiated at 3kGy in air and under vacuum. 相似文献
107.
108.
Concha-Graña E Turnes-Carou MI Muniategui-Lorenzo S López-Mahía P Fernández-Fernández E Prada-Rodríguez D 《Journal of chromatography. A》2004,1047(1):147-155
The scope of this work is the development of a rapid, reliable and sensitive method for the analysis of organochlorine pesticides from soils by pressurized liquid extraction (PLE). The effect of four parameters (temperature, pressure, static time and cell volume) on the extraction efficiency was studied. The great extracting power of the PLE causes the extraction of numerous interfering substances, so a more efficient purification of this extract was necessary. In this work several sorbents have also been assayed to carry out the purification of soil samples: Florisil, silica, alumina, carbon, as well as combinations of them. Finally, the proposed analytical method was validated using a certified reference soil material (CRM804-050) and the results were compared with those obtained by other extraction techniques (Soxhlet and microwave-assisted extraction). 相似文献
109.
Tetramethyldisilane-1,2-diyl bridged Dicyclopentadienyl and Diindenyl Metal Dichlorides of the Group 4 Metals – Crystal Structure of Dicyclopentadienyl and diindenyl metal dichlorides of the type Cp′? SiMe2SiMe2? Cp′MCl2 (Cp′ = C5H4, M = Ti ( 1 ), Zr ( 2 ), Hf ( 3 ); Cp′ = C9H7, M = Zr ( 4 ), Hf ( 5 )) were synthesized and characterized by means of their 1H, 13C, 29Si-n.m.r., MS, and IR spectra. The crystal structure of 2 was determined. 相似文献
110.
Julia E. Barker 《Tetrahedron letters》2005,46(40):6805-6808
Mononuclear (Me3TACN)MnX3 compounds, where X is Cl−, Br−, or N3−, and Me3TACN is 1,4,7-N,N′,N″-trimethyl-1,4,7-triazacyclononane, have been tested for catalyzing both sulfide oxygenation and styrene epoxidation by tert-butyl hydroperoxide (TBHP) and display turnover frequencies (TOF) up to 200 h−1 at room temperature. Sulfoxides or sulfones may be produced selectively by varying reaction conditions. Product distribution from the oxygenation reactions of ethyl phenyl sulfide, 2-chloroethyl phenyl sulfide, and styrene is consistent with a mechanism involving an early single-electron transfer (SET) step. 相似文献