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991.
Investigators have viewed the stress rate in two different ways: the material (body-fixed) point of view and the Eulerian point of view. We discuss the Zaremba–Jaumann rate and Oldroyd’s rate from the material viewpoint and apply them to the material formulation of a theory of plasticity for materials undergoing anisotropic plastic deformation. Significant advantages of the material formulation are that the derivation of equations is straight forward, the distortion of yield surface can be easily accounted for, and the issue of self-consistent elastic equation does not arise. 相似文献
992.
993.
A series of phosphorescent cyclometalated iridium complexes with 2,5‐diphenylpyridine‐based ligands has been synthesized and characterized to investigate the effect of the simple ligand modification on photophysics, thermostability and electrochemistry. The complexes have the general structure (C∧N)2Ir(acac), where C∧N is a monoanionic cyclometalating ligand [e.g. 2,5‐diphenylpyridyl (dppy), 2,5‐di(4‐methoxyphenyl)pyridyl (dmoppy), 2,5‐di(4‐ethoxyphenyl)pyridyl (deoppy) and 2,5‐di(4‐ethylphenyl)pyridyl (deppy)]. The absorption, emission, cyclic voltammetry and thermostability of the complexes were systematically investigated. The (dppy)2Ir(acac) has been characterized using X‐ray crystallography. Calculation on the electronic ground state of (dppy)2Ir(acac) was carried out using B3LYP density functional theory. The highest occupied molecular orbital (HOMO) level is a mixture of Ir and ligand orbitals, while the lowest occupied molecular orbital (LUMO) is predominantly dppy ligand‐based. Electrochemical studies showed the oxidation potentials of (dmoppy)2Ir(acac), (deoppy)2Ir(acac), (deppy)2Ir(acac) were smaller than that of (ppy)2Ir(acac), while the oxidation potential of (dppy)2Ir(acac) was larger relative to (ppy)2Ir(acac). The 10% weight reduction temperatures of these complexes were above that of (ppy)2Ir(acac). All complexes exhibited intense green photoluminescence, which has been attributed to MLCT triplet emission. The maximum emission wavelengths in CH2Cl2 at room temperature were in the range 531–544 nm, which is more red‐shifted than that of (ppy)2Ir(acac). Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
994.
995.
Franck Pastor Malorie Trillat Joseph Pastor Etienne Loute 《Comptes Rendus Mecanique》2006,334(4):213-219
A nonlinear interior point method associated with the kinematic theorem of limit analysis is proposed. Associating these two tools enables one to determine an upper bound of the limit loading of a Gurson material structure from the knowledge of the sole yield criterion. We present the main features of the interior point algorithm and an original method providing a rigorous kinematic bound from a stress formulation of the problem. This method is tested by solving in plane strain the problem of a Gurson infinite bar compressed between rough rigid plates. To cite this article: F. Pastor et al., C. R. Mecanique 334 (2006). 相似文献
996.
Harry H. Hilton 《Journal of Elasticity》2001,63(3):221-251
It is proven that time-independent viscoelastic Poisson ratios (PR) can only exist under separation of variable solutions which severely limits the class of applicable problems to quasi-static ones with incompressible homogeneous materials and non-moving boundaries under separable stress or displacement boundary conditions without any thermal expansions. Therefore, composites which are inherently anisotropic and sandwich structures which are nonhomogeneous and anisotropic are generally precluded from having time-independent PRs. Equal time variations for material properties in all directions are shown to be another simultaneous requirement instead of the incompressibility condition for achieving time-independent PRs. However, such restricted models lead to physically unrealistic bulk moduli responses when compared to experimentally determined relaxation moduli and are not generally achievable in current real materials. Consequently, viscoelastic materials are best characterized in terms of relaxation or creep functions, moduli or compliances rather than combinations of the latter with Poisson's ratios. Additionally, the assumption of constant PRs in problems involving thermal and chemical expansions, such as curing and manufacture of viscoelastic composites, is shown to be unjustified and insupportable. The distinct viscoelastic PR definitions, as found in the literature, are examined and classified into five categories. It is further shown that each is inherently unrelated to the others and all are always time-dependent, unless the above extremely limiting conditions are imposed. An extensive literature review indicates that experimental results overwhelmingly confirm the time dependent nature of viscoelastic PRs as no constant experimentally observed PRs were reported. 相似文献
997.
固体材料激光冷却的实验研究及其最新进展 总被引:1,自引:1,他引:0
近年来,基于反斯托克斯荧光制冷(Anti—Stokes Fluorescent Cooling)的固体材料激光冷却技术得到了快速发展。本文首先简单介绍了固体材料激光冷却的基本原理及其技术;其次,详细介绍了各种固体激光冷却的新材料、新方案和新结果及其最新实验进展;最后,就固体激光冷却技术的应用前景及其未来发展方向等问题进行了简单讨论与展望。 相似文献
998.
999.
根据原子分子反应静力学和群论,确定TiH2,TiD2和TjT2的基电子状态为^3A2.应用基函数6-311G^**和密度泛函理论B3P86方法,全电子计算了氢同位素分子及其钛化物的能量E、定容热容Cv和熵S应用电子振动近似理论,即用单个分子TiH2,TiD2和TjT2中的电子和振动能量和熵近似代表他们处于固态时的能量和熵,计算所得到的金属钛的氢化热力学函数△Hc^0,△S^0,△G^0以及平衡压力与温度的关系,与文献符合很好,这表明电子振动近似理论的可应用性,选用金属钛作为中子靶是很正确的。 相似文献
1000.
A rate dependent crystal plasticity model for the α/β Ti–Al alloy Ti–6Al–4V with duplex microstructure is developed and presented herein. Duplex Ti–6Al–4V is a dual-phase alloy consisting of an hcp structured matrix primary α-phase and secondary lamellar α + β domains that are composed of alternating layers of secondary α laths and bcc structured residual β laths. The model accounts for distinct three-dimensional slip geometry for each phase, anisotropic and length scale dependent slip system strengths, the non-planar dislocation core structure of prismatic screw dislocations in the primary α-phase, and crystallographic texture. The model is implemented in the general purpose finite element code (ABAQUS, 2005. Ver 6.5, Hibbitt, Karlsson, and Sorensen, Inc., Pawtucket, RI) via a UMAT subroutine. 相似文献