全文获取类型
收费全文 | 546篇 |
免费 | 51篇 |
国内免费 | 90篇 |
专业分类
化学 | 202篇 |
晶体学 | 11篇 |
力学 | 62篇 |
综合类 | 5篇 |
数学 | 265篇 |
物理学 | 142篇 |
出版年
2024年 | 1篇 |
2023年 | 8篇 |
2022年 | 28篇 |
2021年 | 19篇 |
2020年 | 18篇 |
2019年 | 20篇 |
2018年 | 24篇 |
2017年 | 23篇 |
2016年 | 29篇 |
2015年 | 20篇 |
2014年 | 26篇 |
2013年 | 43篇 |
2012年 | 29篇 |
2011年 | 36篇 |
2010年 | 33篇 |
2009年 | 33篇 |
2008年 | 33篇 |
2007年 | 34篇 |
2006年 | 40篇 |
2005年 | 31篇 |
2004年 | 26篇 |
2003年 | 26篇 |
2002年 | 25篇 |
2001年 | 16篇 |
2000年 | 8篇 |
1999年 | 13篇 |
1998年 | 9篇 |
1997年 | 3篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1989年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1982年 | 1篇 |
1980年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有687条查询结果,搜索用时 15 毫秒
81.
Sn基合金负极材料具有高达990 mAh·g-1的理论比容量,但其也存在因脱嵌锂过程发生巨大的体积变化而导致循环性能较差的问题. 本文以Sn、Fe、石墨为原料利用简易的高能球磨法成功制备了具有核壳结构的FeSn2-C复合物,系统研究了球磨时间、FeSn2相含量对材料物相结构及电化学性能的影响,并分析了电极的失效机理. 研究表明,球磨时间的增加有利于FeSn2金属间化合物相的形成及材料颗粒的细化,进而有利于材料比容量的增加及循环性能的提升;FeSn2相含量的增加能够提高FeSn2-C材料的比容量,但会降低FeSn2-C电极的循环稳定性. 经工艺优化及组分调节,球磨24 h合成的Sn20Fe10C70材料具有最优的电化学性能,材料的比容量在540 mAh·g-1左右,并能稳定循环100次,是一种非常有发展前途的锂离子电池高比容量负极材料. 相似文献
82.
J. Hakl L. Kerekes S. Mészáros K. Vad P. Gurin M. Kis-Varga I. Uzonyi S. Szabó D. L. Beke 《Czechoslovak Journal of Physics》2002,52(2):151-154
Magnetically frozen partially disordered state was observed in nanocrystalline bulk iron prepared by ball-milling of microcrystalline Fe. Role of nanostructure and oxidized fraction is pointed out. Altough we have found a small constituent which is proportional to 1/T in the ZFC curve, the magnetization scaling with T
3/2 at high fields and the hysteretic behavior in FC-ZFC curves signalizes the presence of frozen ferromagnet at low temperatures. 相似文献
83.
Small ball probabilities are estimated for Gaussian processes with stationary increments when the small balls are given by various Hölder norms. As an application we establish results related to Chung's functional law of the iterated logarithm for fractional Brownian motion under Hölder norms. In particular, we identify the points approached slowest in the functional law of the iterated logarithm.Supported in part by NSF Grant DMS-9024961. 相似文献
84.
85.
Jinhai Chen 《Computational Optimization and Applications》2008,40(1):97-118
In this paper, inexact Gauss–Newton methods for nonlinear least squares problems are studied. Under the hypothesis that derivative
satisfies some kinds of weak Lipschitz conditions, the local convergence properties of inexact Gauss–Newton and inexact Gauss–Newton
like methods for nonlinear problems are established with the modified relative residual control. The obtained results can
provide an estimate of convergence ball for inexact Gauss–Newton methods. 相似文献
86.
In this paper, we study the random power series of several complex variables, and give some sufficient conditions for random power series to belong to Qp and Qp,0 spaces by means of their characterizations of Carleson measure. Moreover, we show that such conditions are best possible in some sense. 相似文献
87.
Let be the unit ball in , let be the unit sphere, and let be the admissible area function. In this paper, we show that if , then and there exists a constant such that .
88.
A functional law of the iterated logarithm is obtained for processes given by certain stochastic integrals. This extends earlier results by Shi(12) and Rémillard(10) who established analogues of the classical limit results of Chung(4) for a variety of processes, including Lévys stochastic area process. The functional aspects of our results are motivated by a paper of Wichura(13) on Brownian motion. Proofs depend on small ball probability estimates, and yield the small ball probabilities of the weighted sup-norm for the processes given by these stochastic integrals. 相似文献
89.
The effect of change of shape of a steel ball was revealed as a result of its etching in an aqueous solution of nitric acid under influence of an external magnetic field. The elongation of a ferromagnetic ball was observed along the direction of an external magnetic field while etching took place uniformly in all the directions without magnetic field application. The steel ball etching in a magnetic field is characterized by formation of three cylindrically symmetric regions with different etching rates and surface structures, divided from each other by clear borders (namely, the pole, equator and transition regions are formed). The non-monotone dependences of etching rate, surface structure of a sample and sample shape after etching on an external magnetic field are observed. 相似文献
90.
We present a theory of ultradistributional boundary values for harmonic functions defined on the Euclidean unit ball. We also give a characterization of ultradifferentiable functions and ultradistributions on the sphere in terms of their spherical harmonic expansions. To this end, we obtain explicit estimates for partial derivatives of spherical harmonics, which are of independent interest and refine earlier estimates by Calderón and Zygmund. We apply our results to characterize the support of ultradistributions on the sphere via Abel summability of their spherical harmonic expansions. 相似文献