Mg／Mgl．8La0．2Ni纳米复合材料的吸放氢性能研究

应用高能球磨法制备Mg-x％Mg1.8La0.2Ni（x=10、20和30）纳米复合储氢材料．X射线衍射（XRD）、透射电镜（TEM）和选区电子衍射（SAED）测试表明，该复合材料具有纳米晶和非晶态混合结构的性质，吸氢温度降低，较好的吸放氢动力学性能，在423K，2．5MPa氢压的条件下，50s内即可达到最大吸氢量．     

多复变中正规权Zygmund空间上的几个性质

本文讨论了多复变中单位球上正规权Zygmund空间Z_μ(B)的一些性质.首先给出了Z_μ(B)函数的一种积分表示,接着证明了Z_μ(B)是正规权Bergman空间A_v~1(B)的对偶空间,其对偶对按如下形式给出:■,其中v(p)=(1-ρ~2)~(β+1)μ~(-1)(ρ)(0≤ρ<1)并且β>max{0,b-1}.最后作为积分表示和对偶的一个应用,作者给出了Z_μ(B)中每个函数的一个原子分解.     

锂离子电池高比容量FeSn2-C复合负极材料的合成与性能

Sn基合金负极材料具有高达990 mAh·g^-1的理论比容量,但其也存在因脱嵌锂过程发生巨大的体积变化而导致循环性能较差的问题. 本文以Sn、Fe、石墨为原料利用简易的高能球磨法成功制备了具有核壳结构的FeSn₂-C复合物,系统研究了球磨时间、FeSn₂相含量对材料物相结构及电化学性能的影响,并分析了电极的失效机理. 研究表明,球磨时间的增加有利于FeSn₂金属间化合物相的形成及材料颗粒的细化,进而有利于材料比容量的增加及循环性能的提升;FeSn₂相含量的增加能够提高FeSn₂-C材料的比容量,但会降低FeSn₂-C电极的循环稳定性. 经工艺优化及组分调节,球磨24 h合成的Sn₂₀Fe₁₀C₇₀材料具有最优的电化学性能,材料的比容量在540 mAh·g^-1左右,并能稳定循环100次,是一种非常有发展前途的锂离子电池高比容量负极材料.     

Disordered Magnetic Phase in Partially Oxidized Bulk Nanocrystalline Iron

Magnetically frozen partially disordered state was observed in nanocrystalline bulk iron prepared by ball-milling of microcrystalline Fe. Role of nanostructure and oxidized fraction is pointed out. Altough we have found a small constituent which is proportional to 1/T in the ZFC curve, the magnetization scaling with T ^3/2 at high fields and the hysteretic behavior in FC-ZFC curves signalizes the presence of frozen ferromagnet at low temperatures.     

Hybrid Comminution with High‐Pressure Roller and Stirred Bead Milling

This paper presents the experimental results on the wet grinding of a moist calcium carbonate material in a hybrid comminution system, which consists of a high pressure roller mill (HPRM) and a subsequent stirred bead mill. The results show that the pre‐treatment of the material with the HPRM could result in energy saving and efficient size reduction during the subsequent wet ultra‐fine grinding in the stirred bead mill. It was found that the level of fineness of the ground product is dramatically influenced by the number of repeat passes of pre‐grinding in the HRPM. The formation of micro‐cracks in the particles under compressive loads was discussed in order to elucidate the role of the HRPM as a pre‐grinder in the hybrid comminution system. The simulated breakage behaviors of various irregular shaped particles indicate that the tortuous micro‐crack propagation paths and the crack branching behavior are related to the heterogeneity of the particle and the stress distributions.     

Small ball probabilities for Gaussian processes with stationary increments under Hölder norms

Small ball probabilities are estimated for Gaussian processes with stationary increments when the small balls are given by various Hölder norms. As an application we establish results related to Chung's functional law of the iterated logarithm for fractional Brownian motion under Hölder norms. In particular, we identify the points approached slowest in the functional law of the iterated logarithm.Supported in part by NSF Grant DMS-9024961.     

压力下Ti60Si40纳米晶的固相反应

 利用球磨方法制备出Ti₆₀Si₄₀纳米晶混合物，研究了该混合物在不同静压力下固态反应，利用X射线衍射和电子显微镜分别研究了样品中的相组成。实验结果表明，球磨过程中生成的微量新的亚稳相可以在适当的压力和温度条件下长大，但其长大速率却随压力的增加而减小。在常压下进行相同温度和时间的热处理，则只有纳米晶的长大而没有固相反应发生。     

The convergence analysis of inexact Gauss–Newton methods for nonlinear problems

In this paper, inexact Gauss–Newton methods for nonlinear least squares problems are studied. Under the hypothesis that derivative satisfies some kinds of weak Lipschitz conditions, the local convergence properties of inexact Gauss–Newton and inexact Gauss–Newton like methods for nonlinear problems are established with the modified relative residual control. The obtained results can provide an estimate of convergence ball for inexact Gauss–Newton methods.     

Randomization of Q_p spaces on the unit ball of C~n

In this paper, we study the random power series of several complex variables, and give some sufficient conditions for random power series to belong to Qp and Qp,0 spaces by means of their characterizations of Carleson measure. Moreover, we show that such conditions are best possible in some sense.     

Boundedness of admissible area function on nonisotropic Lipschitz space

Let be the unit ball in , let be the unit sphere, and let be the admissible area function. In this paper, we show that if , then and there exists a constant such that .